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Citation: Qilin YU, Yifei XU, Pengjun ZHANG, Shuwei HAO, Chongqiang ZHU, Chunhui YANG. Effect of regulating K+/Na+ ratio on the structure and optical properties of double perovskite Cs2NaBiCl6: Mn2+[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418 shu

Effect of regulating K+/Na+ ratio on the structure and optical properties of double perovskite Cs2NaBiCl6: Mn2+

  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

  • Corresponding author: Chongqiang ZHU, zcq90@hit.edu.cn
  • Received Date: 28 November 2024
    Revised Date: 8 May 2025

Figures(9)

  • A series of Cs2NaBiCl6: Mn2+and Cs2Na1-xKxBiCl6: Mn2+ phosphors were synthesized using a solvothermal method. Crystal structures and optical properties were systematically studied through theoretical calculations and experimental measurements. The results showed that in the Cs2NaBiCl6: Mn2+ system, localized excitation absorption near ultraviolet light centered on the [BiCl6]3- octahedron was observed. With the increase of Mn2+ doping concentration, energy transfer from [BiCl6]3- to Mn2+ promoted electronic transitions between the d orbitals of Mn2+ and produced orange-yellow luminescence. After further introducing K+, the photoluminescence (PL) intensity and color purity of Cs2NaBiCl6: Mn2+ were enhanced. It was confirmed that the introduction of K+ effectively tuned the density of states composition of Cs2NaBiCl6: Mn2+ and promoted the 1S0→3P1, 2 electron transition of [BiCl6]3-, thus enhancing the PL intensity of Cs2NaBiCl6: Mn2+, and the color purity was calculated to be 93.58% using CIE software. The final results suggested that Cs2Na1-xKxBiCl6: Mn2+ had strong orange-yellow luminescent properties.
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