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Citation: Zelong LIANG, Shijia QIN, Pengfei GUO, Hang XU, Bin ZHAO. Synthesis and electrocatalytic CO2 reduction performance of metal-organic framework catalysts loaded with silver particles[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409 shu

Synthesis and electrocatalytic CO2 reduction performance of metal-organic framework catalysts loaded with silver particles

  • Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China

Figures(5)

  • A 2D metal-organic framework (Zn-MOF, {[Zn(btz)2]·DMF·CH3OH}n, Hbtz=benzotriazole, DMF=N, N- dimethylformamide) was synthesized, exhibiting high stability in solvents, acid-base, and thermal conditions. The stable structure and uncoordinated nitrogen atoms enable Zn-MOF to effectively enrich silver ions, which can be converted into silver nanoparticles anchored on the MOF (Ag@Zn-MOF) through heat treatment. The silver nanoparticle loading (mass fraction) of the Ag@Zn-MOF composite reached 1.84%. The Zn-MOF framework remained stable after pyrolytic reduction. Electrocatalytic CO2 reduction performance tests demonstrated that, compared to Zn-MOF, the Faraday efficiency of Ag@Zn-MOF for CO production increased from 59.6% to 92.1%, with a current density of 30.3 mA·cm-2 at -1.34 V (vs RHE), highlighting its superior electrocatalytic performance.
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