Citation: Jie WU, Zhihong LUO, Xiaoli CHEN, Fangfang XIONG, Li CHEN, Biao ZHANG, Bin SHI, Quansheng OUYANG, Jiaojing SHAO. Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400 shu

Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2.
State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Supply Co., Ltd., Zunyi, Guizhou 563003, China
3.
School of Materials Science and Engineering, Shanxi Institute of Science and Technology, Jincheng, Shanxi 048011, China

Corresponding author: Jiaojing SHAO, shaojiao_jing@163.com
Received Date: 7 November 2024
Revised Date: 16 March 2025

Figures(8)

LiNi_0.5Mn_1.5O₄ (LNMO) was prepared by a high-temperature solid phase method, and then AlPO₄ (AP) was coated on the polyhedral LNMO surface by the wet chemical method. The experimental results showed that the LNMO-1%AP|Li cell prepared with a 1% mass ratio of AlPO₄ and LNMO had better electrochemical performance; after 450 cycles at 1C, its discharge specific capacity maintained 108.78 mAh·g^-1, while that of the LNMO|Li cell was only 86.04 mAh·g^-1. Especially at the high rates of 5C and 10C, the electrochemical properties of the former were far superior to the latter. This was attributed to the fact that the AP coating made the surface of LNMO in con- tact with the electrolyte more stable, effectively promoted the Li⁺ transport, and reduced the polarization voltage of the electrode.
- LiNi_0.5Mn_1.5O₄,
- high voltage lithium-ion batteries,
- high-temperature solid-phase method,
- aluminum phosphate,
1. [1]
  CHEN Z J, LI Z H, PENG Y X, WANG T, ZHONG H B, HU C Y, ZHAO R R. Crystalline geometry engineering towards high-energy spinel cathode for lithium-ion batteries[J]. J. Alloy. Compd., 2022,919165798. doi: 10.1016/j.jallcom.2022.165798
2. [2]
  LIU J J, YUAN M L, LI Z, XIE S, WANG T X, YAN J Q, PENG J. Improving the electrochemical performance of single crystal LiNi_0.5Mn_1.5O₄ cathode materials by Y-Ti doping and unannealing pro-cess[J]. Ceram. Int., 2022,48(24):36490-36499. doi: 10.1016/j.ceramint.2022.08.209
3. [3]
  ZHOU M X, ZHOU W H, LONG X, ZHU S K, XU P, OUYANG Q S, SHI B, SHAO J J. A 2D montmorillonite-carbon nanotube intercon-nected porous network that prevents polysulfide shuttling[J]. New Carbon Mater., 2023,38(6):1070-1079. doi: 10.1016/S1872-5805(23)60783-8
4. [4]
  DUAN J D, LIU Y L, TANG X, LI J, GUO J Q, ZENG M, WANG L G. Improve electrochemical performance of spinel LiNi_0.5Mn_1.5O₄ via sur-face modified by Li_1.2Ni_0.2Mn_0.6O₂ layered materials[J]. J. Mater. Sci.-Mater. Electron., 2020,31(5):4336-4344. doi: 10.1007/s10854-020-02991-x
5. [5]
  FU T J, LU D, YAO Z Q, LI Y J, LUO C Y, YANG T Y, LIU S K, CHEN Y F, GUO Q P, ZHENG C M, SUN W W. Advances in modifi-cation methods and the prospects of high-voltage spinel LiNi_0.5Mn_1.5O₄-A review[J]. J. Mater. Chem. A, 2023,11(26):13889-13915. doi: 10.1039/D3TA01777J
6. [6]
  HAN Y, JIANG Y S, YU F D, DENG L, KE W, ZHANG S J, QUE L F, WU B, DING F, ZHAO L, WANG Z B. Addressing Mn dissolution in high-voltage LiNi_0.5Mn_1.5O₄ cathodes via interface phase modulation[J]. Adv. Funct. Mater., 2022,32(41)2207285. doi: 10.1002/adfm.202207285
7. [7]
  MOU J R, DENG Y L, HE L H, ZHENG Q J, JIANG N, LIN D M. Critical roles of semi-conductive LaFeO 3 coating in enhancing cycling stability and rate capability of 5 Ⅴ LiNi_0.5Mn_1.5O₄ cathode materials[J]. Electrochim. Acta, 2018,260:101-111. doi: 10.1016/j.electacta.2017.11.059
8. [8]
  JIAO C M, WNG L, ZUO Y X, NI P, LIANG G C. Solid-state synthe-sis of spherical hierarchical LiNi_0.5Mn_1.5O₄ through an improved calci-nation method and its cyclic performance for 5 Ⅴ lithium ion batteries[J]. Solid State Ion., 2015,277:50-56. doi: 10.1016/j.ssi.2015.04.007
9. [9]
  CHANG L J, CAO S Y, LUO S H, LI K, BI X L, WEI A L, LIU J N. Effect of different calcination temperatures on the high-temperature properties of AlPO₄-coated modified spinel LiNi_0.5Mn_1.5O₄ material[J]. Energy Technol., 2021,9(11)2100637. doi: 10.1002/ente.202100637
10. [10]
  HALLOT M, CAJA-MUNOZ B, LEVIEL C, LEBEDEV O I, RETOUX R, AVILA J, ROUSSEL P, ASENSIO M C, LETHIEN C. Atomic layer deposition of a nanometer-thick Li₃PO₄ protective layer on LiNi_0.5Mn_1.5O₄ films: Dream or reality for long-term cycling?[J]. ACS Appl. Mater. Interfaces, 2021,13(13):15761-15773. doi: 10.1021/acsami.0c21961
11. [11]
  HE J R, MELINTE G, DARMA M S D, HUA W B, DAS C, SCHOKEL A, ETTER M, HANSEN A L, MEREACRE L, GECKLE U, BERGFELDT T, SUN Z P, KNAPP M, EHRENBERG H, MAIBACH J. Surface structure evolution and its impact on the elec-trochemical performances of aqueous-processed high-voltage spinel LiNi_0.5Mn_1.5O₄ cathodes in lithium-ion batteries[J]. Adv. Funct. Mater., 2022,32(46)2207937. doi: 10.1002/adfm.202207937
12. [12]
  LIANG W B, WANG P, DING H, WANG B, LI S Y. Granularity control enables high stability and elevated-temperature properties of micron-sized single-crystal LiNi_0.5Mn_1.5O₄ cathodes at high voltage[J]. J. Materiomics, 2021,7(5):1049-1060. doi: 10.1016/j.jmat.2021.02.003
13. [13]
  QURESHI Z A, TARIQ H A, HAFIZ H M, SHAKOOR R A, ALQARADAWI S, KAHRAMAN R. Influence of graphene wrapped-cerium oxide coating on spherical LiNi_0.5Mn_1.5O₄ particles as cath-ode in high-voltage lithium-ion batteries[J]. J. Alloy. Compd., 2022,920165989. doi: 10.1016/j.jallcom.2022.165989
14. [14]
  LIU J J, YUAN M L, LI Z, WANG L H, YAN J Q, PENG J, OU S W, XU J Y. Enhancing structure and cycling stability of single crystal LiNi_0.5Mn_1.5O₄ cathode via multifunctional MXene surface modifica-tion[J]. J. Energy Storage, 2024,76109785. doi: 10.1016/j.est.2023.109785
15. [15]
  CHANG Q, WANG F, ZUO Z C, HE F, ZHAO Y, WANG F Y, LI Y L. High voltage-stabilized graphdiyne cathode interface[J]. Small, 2021,17(38)2102066. doi: 10.1002/smll.202102066
16. [16]
  SANDARUWAN R D L, CONG L N, MA L P, MA S C, WANG H Y. Tackling the interfacial issues of spinel LiNi_0.5Mn_1.5O₄ by room-tem-perature spontaneous dediazonation reaction[J]. ACS Appl. Mater. Interfaces, 2021,13(11):13264-13272. doi: 10.1021/acsami.1c00204
17. [17]
  LV S S, LI M Y, LUO X Y, CHENG J P, LI Z C. High-voltage LiNi_0.5Mn_1.5O₄ thin film cathodes stabilized by LiPON solid electro-lyte coating to enhance cyclic stability and rate capability[J]. J. Alloy. Compd., 2020,815151636. doi: 10.1016/j.jallcom.2019.07.348
18. [18]
  YI T F, LI Y M, Li X Y, PAN J J, ZHANG Q Y, ZHU Y R. Enhanced electrochemical property of FePO₄-coated LiNi_0.5Mn_1.5O₄ as cathode materials for Li-ion battery[J]. Sci. Bull., 2017,62(14):1004-1010. doi: 10.1016/j.scib.2017.07.003
19. [19]
  ZHU Y R, YI T F, ZHU R S, ZHOU A N. Increased cycling stability of Li ₄Ti₅O₁₂-coated LiNi_0.5Mn_1.5O₄ as cathode material for lithium-ion batteries[J]. Ceram. Int., 2013,39(3):3087-3094. doi: 10.1016/j.ceramint.2012.09.088
20. [20]
  ZENG H N, HE J, FANG D Y, LIANG Y H, ZHAO R R, CAI Y P, LU D S. Nano-sized AlPO 4 coating layer on graphite powder to improve the electrochemical properties of high-voltage graphite/LiNi_0.5Mn_1.5O₄ Li-ion cells[J]. Energy Technol., 2019,7(9)1801078. doi: 10.1002/ente.201801078
21. [21]
  WU Q, YIN Y F, SUN S W, ZHANG X P, WAN N, BAI Y. Novel AlF 3 surface modified spinel LiNi_0.5Mn_1.5O₄ for lithium-ion batteries: Performance characterization and mechanism exploration[J]. Electro-chim. Acta, 2015,158:73-80. doi: 10.1016/j.electacta.2015.01.145
22. [22]
  HWANG T, LEE J K, MUN J, CHOI W. Surface-modified carbon nanotube coating on high-voltage LiNi_0.5Mn_1.5O₄ cathodes for lithium ion batteries[J]. J. Power Sources, 2016,322:40-48. doi: 10.1016/j.jpowsour.2016.04.118
23. [23]
  GAO C, LIU H P, BI S F, FAN S S, MENG X H, LI Q Y, LUO C X. Insight into the effect of graphene coating on cycling stability of LiNi_0.5Mn_1.5O₄: Integration of structure-stability and surface-stability[J]. J. Materiomics, 2020,6(4):712-722. doi: 10.1016/j.jmat.2020.05.010
24. [24]
  GAO C, LIU H P, BI S F, FAN S S, LIU Q, LI H L, CAO L X, LUO C X. Insight into the high-temperature cycling stability of a micro-nanostructured LiNi_0.5Mn_1.5O₄/graphene composite cathode for high-voltage lithium-ion batteries[J]. J. Phys. Chem. C, 2020,124(35):18847-18858. doi: 10.1021/acs.jpcc.0c02933
25. [25]
  QURESHI Z A, TARIQ H A, SHAKOOR R A, KAHRAMAN R, AQARADAWI S. Impact of coatings on the electrochemical perfor-mance of LiNi_0.5Mn_1.5O₄ cathode materials: A focused review[J]. Ceram. Int., 2022,48(6):7374-7392. doi: 10.1016/j.ceramint.2021.12.118
26. [26]
  WEI A J, LI W, CHANG Q, BAI X, HE R, ZHANG L H, LIU Z F, WANG Y J. Effect of Mg²⁺/F-co-doping on electrochemical perfor-mance of LiNi_0.5Mn_1.5O₄ for 5 Ⅴ lithium-ion batteries[J]. Electro-chim. Acta, 2019,323134692. doi: 10.1016/j.electacta.2019.134692
27. [27]
  SUN P, MA Y, ZHAI T Y, LI H Q. High performance LiNi_0.5Mn_1.5O₄ cathode by Al-coating and Al³⁺-doping through a physical vapor deposition method[J]. Electrochim. Acta, 2016,191:237-246. doi: 10.1016/j.electacta.2016.01.087
28. [28]
  YI T F, XIE Y, YE M F, JIANG L J, ZHU R S, ZHU Y R. Recent developments in the doping of LiNi_0.5Mn_1.5O₄ cathode material for 5 Ⅴ lithium-ion batteries[J]. Ionics, 2011,17(5):383-389. doi: 10.1007/s11581-011-0550-6
29. [29]
  PARK S B, EOM W S, CHO W I, JANG H. Electrochemical proper-ties of LiNi_0.5Mn_1.5O₄ cathode after Cr doping[J]. J. Power Sources, 2006,159(1):679-684. doi: 10.1016/j.jpowsour.2005.10.099
30. [30]
  WANG H L, XIA H, LAI M O, LU L. Enhancements of rate capabili-ty and cyclic performance of spinel LiNi_0.5Mn_1.5O₄ by trace Ru-doping[J]. Electrochem. Commun., 2009,11(7):1539-1542. doi: 10.1016/j.elecom.2009.05.054
31. [31]
  ZONG B, DENG Z Y, YAN S H, LANG Y Q, GONG J J, GUO J L, WANG L, LIANG G C. Effects of Si doping on structural and electro-chemical performance of LiNi_0.5Mn_1.5O₄ cathode materials for lithium-ion batteries[J]. Powder Technol., 2020,364:725-737. doi: 10.1016/j.powtec.2020.02.033
32. [32]
  YI T F, HAN X, CHEN B, ZHU Y R, XIE Y. Porous sphere-like LiNi_0.5Mn_1.5O₄-CeO₂ composite with high cycling stability as cathode material for lithium-ion battery[J]. J. Alloy. Compd., 2017,703:103-113. doi: 10.1016/j.jallcom.2017.01.342
33. [33]
  ONEY G, OLCHOWKA J, DEMORTIERE A, WEILL F, CROGUENNEC L. Molten salt synthesis of multifaceted pure-phase spinel LiNi_0.5Mn_1.5O₄ platelets[J]. ACS Appl. Energy Mater., 2023,6(15):8189-8196. doi: 10.1021/acsaem.3c01328
34. [34]
  DENG S X, WANG B Q, YUAN Y F, LI X, SUN Q, DOYLE-DAVIS K, BANIS M N, LIANG J N, ZHAO Y, LI J J, LI R Y, SHAM T K, SHAHBAZIAN-YASSAR R, WANG H, CAI M, LU J, SUN X L. Manipulation of an ionic and electronic conductive interface for highly-stable high-voltage cathodes[J]. Nano Energy, 2019,65103988. doi: 10.1016/j.nanoen.2019.103988
35. [35]
  WEI L Y, TAO J M, YANG Y M, FAN X Y, RAN X X, LI J X, LIN Y B, HUANG Z G. Surface sulfidization of spinel LiNi_0.5Mn_1.5O₄ cathode material for enhanced electrochemical performance in lithium-ion batteries[J]. Chem. Eng. J., 2020,384123268. doi: 10.1016/j.cej.2019.123268
36. [36]
  ZHANG L Q, WANG H, WANG X, WEN J F, REN Y R. Improved electrochemical performance of high voltage spinel LiNi_0.5Mn_1.5O₄ achieved by a dual electronic and ionic surface modification strategy[J]. Solid State Ion., 2022,387116062. doi: 10.1016/j.ssi.2022.116062
37. [37]
  TSAI Y D, SHIH J Y, LI Y J J, HUNG T F, HSU L F, RAMARAJ S K, JOSE R, KARUPPIAH C, YANG C C. Effect of single-walled car-bon nanotube sub-carbon additives and graphene oxide coating for enhancing the 5 Ⅴ LiNi_0.5Mn_1.5O₄ cathode material performance in lithium-ion batteries[J]. ACS Sustain. Chem. Eng., 2022,10(50):16709-16724. doi: 10.1021/acssuschemeng.2c04808
38. [38]
  LI L, ZHAO R, XU T H, WANG D D, PAN D, ZHANG K, YU C Y, LU X, HE G J, BAI Y. Stabilizing a high-voltage LiNi_0.5Mn_1.5O₄ cath-ode towards all solid state batteries: A Li-Al-Ti-P-O solid electrolyte nano-shell with a host material[J]. Nanoscale, 2019,11(18):8967-8977. doi: 10.1039/C9NR01655D
39. [39]
  ZHU R N, ZHANG S J, GUO Q X, ZHOU Y, LI J T, WANG P F, GONG Z L. More than just a protection layer: Inducing chemical interaction between Li ₃BO₃ and LiNi_0.5Mn_1.5O₄ to achieve stable high-rate cycling cathode materials[J]. Electrochim. Acta, 2020,342136074. doi: 10.1016/j.electacta.2020.136074
40. [40]
  TARIQ H A, ABRAHAM J J, QUDDUS A A, ALQARADAWI S, KAHRAMAN R, SHAKOOR R A. Graphene wrapped Y₂O₃ coated LiNi_0.5Mn_1.5O₄ quasi-spheres as novel cathode materials for lithium-ion batteries[J]. J. Mater. Res. Technol., 2021,14:1377-1389. doi: 10.1016/j.jmrt.2021.07.038
41. [41]
  DENG S X, XIAO B W, WANG B Q, LI X, KALIYAPPAN K, ZHAO Y, LUSHINGTON A, LI R Y, SHAM T K, WANG H, SUN X L. New insight into atomic-scale engineering of electrode surface for long-life and safe high voltage lithium ion cathodes[J]. Nano Energy, 2017,38:19-27. doi: 10.1016/j.nanoen.2017.05.007
42. [42]
  MO M Y, HUI K S, HONG X T, GUO J S, YE C C, LI A J, HU N Q, HUANG Z Z, JIANG J H, LIANG J Z, CHEN H Y. Improved cycling and rate performance of Sm-doped LiNi_0.5Mn_1.5O₄ cathode materials for 5 Ⅴ lithium ion batteries[J]. Appl. Surf. Sci., 2014,290:412-418. doi: 10.1016/j.apsusc.2013.11.094
43. [43]
  TANG X N, XIA S, LEI J, YANG X F, LUO Q Y, LIU J N, XUE A. Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion bat-teries[J]. Chinese. J. Inorg. Chem., 2024,40(9):1671-1678.
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Critical roles of AlPO4 coating in enhancing cycling stability and rate capability of high voltage LiNi0.5Mn1.5O4 cathode materials

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Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials