Citation: Hailang JIA, Pengcheng JI, Hongcheng LI. Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398 shu

Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution

School of Chemistry and Chemical Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China

Corresponding author: Hailang JIA, jiahailang85@126.com
Received Date: 3 November 2024
Revised Date: 26 June 2025

Figures(7)

We used ZIF-8 as a sacrificial template and utilized its inherent polyhedral spatial structure to suppress the stacking and aggregation behavior of nanoparticle catalysts. At the same time, we further introduced transition metal nickel (Ni) element to doping ruthenium dioxide (RuO₂) to optimize the electronic structure of the material and improve the intrinsic activity of active sites. As a result, the high-performance oxygen evolution electrocatalyst (Ni-RuO₂) with a particle size of 8-10 nm was prepared. The results indicated that Ni-RuO₂ had excellent oxygen evolution reaction (OER) catalytic performance, surpassing commercial RuO₂. When Ni-RuO₂ was used as the anode for overall water splitting testing, only a decomposition voltage of 1.476 V was required at a current density of 10 mA·cm^-2.
- oxygen evolution reaction,
- nickel doping,
- ruthenium dioxide,
- sacrificial template
1. [1]
  GEWIRTH A A, VARNELL J A, DIASCRO A M. Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems[J]. Chem. Rev., 2018,118:2313-2339.
2. [2]
  ZHAO Z Q, CHEN H, ZHANG W Y, YI S, CHEN H L, SU Z, NIU B, ZHANG Y Y, LONG D H. Defect engineering in carbon materials for electrochemical energy storage and catalytic conversion[J]. Mater. Adv., 2023,4:835-867.
3. [3]
  IQBAL M F, IDREES M, IMRAN M, RAZAQ A, ZHU G M, ZHANG J, MUHAMMAD Z, ZHANG M. Enhancement of the characteristics and HER activity of molybdenum carbide nanosheets for hydrogen evolution reaction[J]. Sustain. Energ. Fuels, 2024,8:2299-2308.
4. [4]
  WU F, JIAO Y H, GE J L, ZHU Y Y, FENG C, WU Z, LV C P. Rapid synthesis of sea urchin-like Ni(OH)₂@Ni(Fe)OOH electrocatalysts for the oxygen evolution reaction[J]. New J. Chem., 2024,48:16380-16386.
5. [5]
  WANG Q, YE M Z, HE G Y, CHEN H Q. Sulfur vacancies modified CuCo₂S₄ popcorn-like nanoballs loaded reduced graphene oxide as bifunctional electrocatalysts for electrochemical water splitting[J]. J. Alloy. Compd., 2024,1009176948.
6. [6]
  LUAN X Y, GUO L F, LI H D, XIAO W P, XU G R, CHEN D H, LI C X, DU Y M, WU Z X, WANG L. Ultrafast quasi-solid-state microwave construction of spongy cobalt-molybdenum phosphide for hydrogen production over wide pH range[J]. Small, 2024,202404830.
7. [7]
  PAN J T, ZHENG D W, XU G Y, GUO T, DING Y G, LIU D. Ion exchange engineering of S, Cu co-doped cobalt phosphide toward efficient electrochemical hydrogen evolution[J]. Fuel, 2024,378132954.
8. [8]
  LIN C C, ZHANG Q, HAN P, WANG X Y, ZUO X Q, YANG Q, CHEN D M, LI G. Regulation of electrons between Ru and VN for high performance HER of low-level Ru doping in vanadium-nitrogen doped carbon catalysts[J]. Surf. Interfaces, 2024,51104544.
9. [9]
  TENG Y, JI P C, JIA H L. FeNi-LDH coated with orange-peel carbon aerogel for oxygen evolution reaction[J]. ChemSusChem, 2024,18e202401276.
10. [10]
  LI Y Q, CHEN J Y, WANG Z A, CHEN S R. 3D hierarchical carbon-supported ultrafine Ru nanoparticles for pH universal hydrogen evolution reactions[J]. ACS Appl. Nano Mater., 2024,77555.
11. [11]
  LI N, MAO L J, FU Y T, WANG H R, SHEN Y C, ZHOU X M, LI Q P, QIAN J J. Ru-anchoring Co-MOF-derived porous Ru-Co₃O₄ nanomaterials for enhanced oxygen evolution activity and structural stability[J]. Inorg. Chem. Front., 2024,11:8139-8145.
12. [12]
  AN B, LI X Q, LIN Y, SHANG F F, HE H J, CAI H R, ZENG X X, WANG W T, YANG S C, WANG B. Strontium doping RuO₂ electrocatalyst with abundant oxygen vacancies for boosting OER performance[J]. Inorg. Chem. Front., 2024,11:8935-8944.
13. [13]
  YI H, ZHANG X, AI Z, SONG S X, AN Q. Hollow nanowire constructed by NiCo doped RuO₂ nanoparticles for robust hydrogen evolution at high-current-density[J]. ChemSusChem, 2022,15e202201532.
14. [14]
  XU F F, LIU X, ZHANG L L, GUO M X, LI M Z, DING X, ZHANG L X. Revealing and optimizing the dialectical relationship between NOR and OER: Cation vacancy engineering enables RuO₂ with unanticipated high electrochemical nitrogen oxidation performance[J]. Adv. Energy Mater., 2023,132300615.
15. [15]
  HUANG J, HU B, MENG J, MENG T, LIU W, GUAN Y, JIN L, ZHANG X. Highly efficient sustainable strategies toward carbon-neutral energy production[J]. Energy Environ. Sci., 2024,17:1007-1045.
16. [16]
  KWON I S, DEBELA T T, KWAK I H, PARK Y C, SEO J, SHIM J Y, YOO S J, KIM J G, PARK J, KANG H S. Ruthenium nanoparticles on cobalt-doped 1T' phase MoS₂ nanosheets for overall water splitting[J]. Small, 2020,162000081.
17. [17]
  HAO Y R, XUE H, SUN J, GUO N K, SONG T S, SUN J W, WANG Q. Tuning the electronic structure of CoP embedded in N-doped porous carbon nanocubes via Ru doping for efficient hydrogen evolution[J]. ACS Appl. Mater. Interfaces, 2021,13:56035-56044.
18. [18]
  WANG H S, ABRUÑA H D. Comparative study of Ru-transition metal alloys and oxides as oxygen evolution reaction electrocatalysts in alkaline media[J]. ACS Appl. Energ. Mater., 2022,5:11241-11253.
19. [19]
  CHOU C H, YEH C H, CHEN P L, LIN K H, WU C Y, YAN Z C, HSIAO P H, CHEN C Y. Reducing hole-injection hurdles of OER electrocatalysts derived from Ru-doped FeNi metal-organic frameworks anchored with FeOOH[J]. J. Mater. Chem. A, 2024,12:29526-29537.
20. [20]
  WANG M T, JIAN J, WANG Z, XUE X X, NIE P, CHANG L M. Self-supporting Ru³⁺ doped copper phosphate with Pt/C-like hydrogen evolution reaction activity[J]. J. Mater. Chem. C, 2024,12:17128-17134.
21. [21]
  ESCALERA-LÓPEZ D, CZIOSKA S, GEPPERT J, BOUBNOV A, RÖSE P, SARAÇI E, KREWER U, GRUNWALDT J D, CHEREVKO S. Phase- and surface composition-dependent electrochemical stability of Ir-Ru nanoparticles during oxygen evolution reaction[J]. ACS Catal., 2021,11:9300-9316.
22. [22]
  DING J Y, PENG Z M, WANG Z W, ZENG C H, FENG Y H, YANG M S, HU G Z, LUO J, LIU X J. Phosphorus-tungsten dual-doping boosts acidic overall seawater splitting performance over RuO_x nanocrystals[J]. J. Mater. Chem. A, 2024,12:28023-28031.
23. [23]
  TAO Z H, LV N, ZHAO H Y, LUO X, LI Z L, YU J, CHEN L, LIU X P, MU S C. Dual active site-mediated Ir single-atom-doped RuO₂ catalysts for highly efficient and stable water splitting[J]. Chem. Sci., 2024,15:16796-16803.
24. [24]
  JI P C, TENG Y, LI H C, GUAN M Y, JIA H L. Honeycomb-like hollow carbon loaded with ruthenium nanoparticles as high-performance HER electrocatalysts[J]. Sustain. Energ. Fuels, 2024,8:82-89.
25. [25]
  REN Y M, XU Y X. Three-dimensional graphene/metal-organic framework composites for electrochemical energy storage and conversion[J]. Chem. Commun., 2023,59:6475-6494.
26. [26]
  WU Z Y, CHEN F Y, LI B Y, YU S W, FINFROCK Y Z, MEIRA D M, YAN Q Q, ZHU P, CHEN M X, SONG T W, YIN Z Y, LIANG H W, ZHANG S, WANG G F, WANG H T. Non-iridium-based electrocatalyst for durable acidic oxygen evolution reaction in proton exchange membrane water electrolysis[J]. Nat. Mater., 2023,22:100-108.
27. [27]
  KE J, JI Y J, LIU D, CHEN J X, WANG Y, LI Y Y, HU Z W, HUANG W H, SHAO Q, LU J M. Optimizing acidic oxygen evolution with manganese-doped ruthenium dioxide assembly[J]. ACS Appl. Mater. Interfaces, 2025,17:13-21.
28. [28]
  ZHOU Y N, YU N, LV Q X, LIU B, DONG B, CHAI Y M. Surface evolution of Zn doped-RuO₂ under different etching methods towards acidic oxygen evolution[J]. J. Mater. Chem. A, 2022,10:16193-16203.
29. [29]
  HOU J G, SUN Y Q, WU Y Z, CAO S Y, SUN L C. Promoting active sites in core-shell nanowire array as Mott-Schottky electrocatalysts for efficient and stable overall water splitting[J]. Adv. Funct. Mater., 2018,281704447.
30. [30]
  KIRTI , NANDHA N, SINGH P S, SRIVASTAVA D N. Improved OER performance on the carbon composite electrode through tailored wettability[J]. ACS Appl. Energy Mater., 2021,4:9618-9626.
31. [31]
  SUN Y X, CAI Q G, WANG Z, LI Z C, ZHOU Q Y, LI X, ZHAO D Y, LU J F, TIAN S Q, LI Y, WANG S F. Two-dimensional SnS mediates NiFe-LDH-layered electrocatalyst toward boosting OER activity for water splitting[J]. ACS Appl. Mater. Interfaces., 2024,16:23054-23060.
32. [32]
  WEI J M, LOU J L, HU W B, SONG X K, WANG H F, YANG Y, ZHANG Y Q, JIANG Z R, MEI B B, WANG L B, YANG T H, WANG Q, LI X P. Superstructured carbon with enhanced kinetics for zinc-air battery and self-powered overall water splitting[J]. Small, 2023,202308956.
33. [33]
  LI W M, LIU R, YU G T, CHEN X J, YAN S, REN S Y, CHEN J J, CHEN W, WANG C, LU X F. Rationally construction of Mn-doped RuO₂ nanofibers for high-activity and stable alkaline ampere-level current density overall water splitting[J]. Small, 2024,202307164.
34. [34]
  ZHAO C F, WANG J, GAO Y, ZHANG J, HUANG C Y, SHI Q H, MU S C, XIAO Q F, HUO S J, XIA Z H, ZHANG J J, LU X G, ZHAO Y F. d-orbital manipulated Ru nanoclusters for high-efficiency overall water splitting at industrial-level current densities[J]. Adv. Funct. Mater., 2024,342307917.
35. [35]
  JIANG R, DA Y M, ZHANG J F, WU H, FAN B B, LI J H, WANG J J, DENG Y D, HAN X P, HU W B. Non-equilibrium synthesis of stacking faults-abundant Ru nanoparticles towards electrocatalytic water splitting[J]. Appl. Catal. B-Environ., 2022,316121682.
36. [36]
  YU Q Q, YU W Q, WANG Y J, HE J T, CHEN Y K, YUAN H F, LIU R Y, WANG J J, LIU S Y, YU J Y, LIU H, ZHOU W J. Hydroxyapatite-derived heterogeneous Ru-Ru₂P electrocatalyst and environmentally-friendly membrane electrode toward efficient alkaline electrolyzer[J]. Small, 2023,192208045.
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