Citation: Tieping CAO, Yuejun LI, Dawei SUN. Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366 shu

Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction

1.
College of Chemistry and Materials Engineering, Hainan Vocational University of Science and Technology, Haikou 570100, China
2.
College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China

Corresponding author: Yuejun LI, bc640628@163.com
Received Date: 12 October 2024
Revised Date: 6 March 2025

Figures(9)

A novel Bi/Bi₂S₃/TiO₂ composite fibers photocatalytic materials were constructed by in-situ hydrothermal method using TiO₂ nanofibers prepared by electrospinning technology serve as the matrix, bismuth nitrate as the bismuth source and ethylene glycol as the reducing agent. The morphology, structure, and optoelectronic properties of the composite fibers material were analyzed by powder X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscope, ultraviolet-visible absorption spectroscopy, photocurrent response, electrochemical impedance spectroscopy, and fluorescence emission spectroscopy. The photocatalytic CO₂ reduction performance of Bi/Bi₂S₃/TiO₂ composite fibers under a gas-solid reaction system was investigated. The results show that metal Bi nanoparticles and scaly Bi₂S₃ are orderly constructed on the surface of TiO₂ nanofibers. The surface plasmon resonance (SPR) effect of metal Bi has a synergistic effect with the Bi₂S₃/TiO₂ S-scheme heterojunction, which enables the efficient spatial separation and transfer of photogenerated carriers and effectively enhances the photocatalytic activity of Bi/Bi₂S₃/TiO₂. In-depth research found that the S-scheme heterojunction possesses a unique mechanism of carrier movement, resulting in a robust redox capacity and strong driving force. The main products of the photocatalytic CO₂ reduction were CH₄ and CH₃OH, with yields of 4.21 and 9.86 μmol·h^-1·g^-1, respectively, about three times that of Bi₂S₃/TiO₂.
- surface plasmon resonance,
- S-scheme heterojunction,
- photocatalytic CO₂ reduction
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沈阳化工大学材料科学与工程学院沈阳 110142

Surface plasmon resonance effect enhanced photocatalytic CO2 reduction performance of S-scheme Bi2S3/TiO2 heterojunction

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Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction