Citation: Yongzhi LI, Han ZHANG, Gangding WANG, Yanwei SUI, Lei HOU, Yaoyu WANG. A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307 shu

A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution

Yongzhi LI ^1,, ,
Han ZHANG ¹ ,
Gangding WANG ² ,
Yanwei SUI ¹ ,
Lei HOU ^2,, ,
Yaoyu WANG ²

1.
School of Materials and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China

Corresponding author: Yongzhi LI, Lyz2021@cumt.edu.cn Lei HOU, lhou2009@nwu.edu.cn
Received Date: 20 August 2024
Revised Date: 14 November 2024

Figures(6)

Herein, a two dimensional europium based metal organic framework [Eu(dtztp)_0.5(H₂dtztp)_0.5(DMF)₃] · 0.113H₂O (Eu -MOF) was obtained through self assembly of 2, 5 bis(2H tetrazol 5 yl) terephthalic acid ligand (H₄dtztp) with Eu³⁺ under solvent thermal conditions, where DMF is N, N-dimethylformamide. The spatial structure, phase purity, and thermal stability of Eu-MOF were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis. Meanwhile, the solid-state fluorescence and antibiotic detection functions of Eu-MOF were also investigated. The results show that Eu-MOF crystallizes in triclinic system, \begin{document}$P \overline{1}$\end{document} space group with cell parameters: a=1.018(7) nm, b=1.103(8) nm, c=1.252(9) nm, α=115.963(2)°, β=92.604(2)°, γ=96.556(2)°. Eu-MOF displayed obvious red luminescence under ultraviolet light at 365 nm, as well as showed highly selective detection for nitrofurantoin (NFT) and nitrofurazone (NFZ) in aqueous solution with detection limits of 3.88 and 5.44 μmol·L^-1, respectively. The fluorescence detection mechanism of Eu-MOF for NFT and NFZ was revealed by the combination of experiment and theoretical calculation.
- antibiotic,
- metal-organic framework,
- crystal structure,
- fluorescence sensing
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