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Citation: Ziliang KANG, Jiamin ZHANG, Hong AN, Xiaohua LIU, Yang CHEN, Jinping LI, Libo LI. Preparation and water adsorption properties of CaCl2@MOF-808 in-situ composite moulded particles[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282 shu

Preparation and water adsorption properties of CaCl2@MOF-808 in-situ composite moulded particles

  • Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

  • Corresponding author: Yang CHEN, chenyangtyut@163.com
  • Received Date: 25 July 2024
    Revised Date: 9 October 2024

Figures(10)

  • The combination of hygroscopic salt with metal-organic framework (MOF) material and in-situ modified moulding method can be used to rapidly prepare hygroscopic salt-loaded CaCl2@MOF-808 composite moulded particles. Based on the high porosity and high specific surface area of MOF-808, CaCl2 could be dispersed in the pore channels of MOF-808, and water molecules were adsorbed under the joint action of the rich pore environment and the hygroscopic salt, which enhances the water harvesting ability of the molded particles under low pressure. Characterization techniques such as X-ray powder diffraction, scanning electron microscopy, N2 adsorption-desorption, and water adsorption tests were used to observe the physical phase and properties of the formed particles. The test results showed that the mechanical strength of CaCl2@MOF-808 molded adsorbent reached 25 N, which meets the compressive level of the application. At a temperature of 25 ℃ and a relative humidity (RH) of 30%, the maximum value of its water adsorption rate was 0.43 g·g-1, which was five times higher than that of the original MOF-808.
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