Citation: Xiumei LI, Linlin LI, Bo LIU, Yaru PAN. Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273 shu

Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers

Xiumei LI ¹ ,
Linlin LI ^1,, ,
Bo LIU ^2,, ,
Yaru PAN ¹

1.
Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China
2.
Faculty of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: Linlin LI, 403666495@qq.com Bo LIU, 112363305@qq.com
Received Date: 19 July 2024
Revised Date: 25 September 2024

Figures(9)

Two new transition-metal coordination polymers, {[Cd(oba)(L)₂]·H₂O}_n (1) and [Cd(4-nph)(L)₂]_n (2) (H₂oba=4, 4′-oxydibenzoic acid, 4-H₂nph=4-nitrophthalic acid, L=2, 2′-biimidazole), were successfully synthesized under hydrothermal conditions and characterized structurally by IR spectroscopy, elemental analyses, single-crystal X-ray diffraction, powder X-ray diffraction, and thermogravimetric analysis. The results of single-crystal X-ray diffraction show that complex 1 presents a 1D zigzag chain structure and further extends to a 2D network through N—H…O hydrogen bonds and π-π stacking interactions. Meanwhile, complex 2 has a zero-dimensional structure and also extends to form a 2D network through N—H…O hydrogen bonds and π-π stacking interactions. In addition, both 1 and 2 exhibited luminescent properties in the solid state. Furthermore, quantum chemical calculations were carried out on the "molecular fragments" extracted from the crystal structures of 1 and 2 using the PBE0/LANL2DZ method constructed by the Gaussian16 program. The calculated values signify a significant covalent interaction between the coordination atoms and the Cd(Ⅱ) ions.
- coordination polymer,
- cadmium(Ⅱ) complex,
- crystal structure,
- quantum-chemical calculations
1. [1]
  ZHANG L W, ZHANG Y, CUI Y F, YU M, DONG W K. Heterobimetallic [Ni^ⅡLn^Ⅲ] (Ln=Sm and Tb) N₂O₄-donor coordination polymers: Syntheses, crystal structures and fluorescence properties[J]. Inorg. Chim. Acta, 2020, 506: 119534 doi: 10.1016/j.ica.2020.119534
2. [2]
  WANG Y, JIANG Y L, LIU Q Y, TAN Y X, WEI J J, ZHANG J. A series of three-dimensional lanthanide(Ⅲ) coordination polymers of 2, 5-dihydroxy-1, 4-benzenedicarboxylic acid based on dinuclear lanthanide units[J]. CrystEngComm, 2011, 13(15): 4981-4987 doi: 10.1039/c1ce05069a
3. [3]
  LI X M, HUANG Y J, LIU B, PAN Y R. Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers[J]. Chinese J. Inorg. Chem., 2024, 40(10): 2031-2039 doi: 10.11862/CJIC.20240109
4. [4]
  WANG S, HUANG R Q, LI W, LV Y J, HAN G C, WEI R Z, LIU Z. Synthesis, structure and properties of two complexes based on N and S heterocyclic dicarboxylic acid ligands[J]. Mol. Cryst. Liq. Cryst., 2022, 746(1): 110-119 doi: 10.1080/15421406.2022.2081044
5. [5]
  LI X L, YANG Z Q, ZHU J P. Preparation of LiNi_1/3Co_1/3Mn_1/3O₂ using NiCoMn-MOF as precursor[J]. J. Electron. Mater., 2021, 50(11): 6114-6120 doi: 10.1007/s11664-021-09140-y
6. [6]
  YANG T T, GUO B S, DU W Y, ASLAM M K, TAO M L, ZHONG W, CHEN Y M, BAO S J. ZHANG X, XU M W. Design and construction of sodium polysulfides defense system for room-temperature Na-S battery[J]. Adv. Sci., 2019, 6(23): 1901557 doi: 10.1002/advs.201901557
7. [7]
  LI S L, WANG B Q, LIU G C, LI X H, SUN C, ZHANG Z, WANG X L. Achieving ultra-trace analysis and multi-light driven photodegradation toward phenolic derivatives via a bifunctional catalyst derived from a Cu(Ⅰ)-complex-modified polyoxometalate[J]. Inorg. Chem. Front., 2024, 11(5): 1561-1572 doi: 10.1039/D3QI02513F
8. [8]
  WANG H L, WANG X, LI M M, FENG J D. Two new Zn(Ⅱ) coordination polymers incorporating 2-(2, 6-dichlorophenyl)-1H-imidazo[4, 5-f][1, 10]phenanthroline: Synthesis and structure[J]. Main Group Met. Chem., 2024, 47: 20230033 doi: 10.1515/mgmc-2023-0033
9. [9]
  GAO Q, XU J, BU X H. Recent advances about metal-organic frameworks in the removal of pollutants from wastewater[J]. Coord. Chem. Rev., 2019, 378: 17-31 doi: 10.1016/j.ccr.2018.03.015
10. [10]
  LIANG C X, LIU Z, LIANG Q Q, HAN G C, HAN J X, ZHANG S F, FENG X Z. Synthesis of 2-aminofluorene bis-Schiff base and corrosion inhibition performance for carbon steel in HCl[J]. J. Mol. Liq., 2019, 277: 330-340 doi: 10.1016/j.molliq.2018.12.095
11. [11]
  WEI W C, LIU Z, WEI R Z, LIANG C X, FENG X Z, Han G C. Synthesis, crystal structure and anticorrosion performance of Zn(Ⅱ) and Ni(Ⅱ) complexes[J]. J. Mol. Struct., 2021, 1228: 129452 doi: 10.1016/j.molstruc.2020.129452
12. [12]
  WEI R Z, LIU Z, WEI W C, LIANG C X, HAN G C, ZHAN L. Synthesis, crystal structure and characterization of two cobalt(Ⅱ) complexes based on pyridine carboxylic acid ligands[J]. Z. Anorg. Allg. Chem., 2022, 648(9): e202000418 doi: 10.1002/zaac.202000418
13. [13]
  ZHAN P Y, FENG W Z, LI X M, LIU B. A new pyridine-3, 4-dicarboxylic acid bridged zinc(Ⅱ) coordination complex: Crystal structure, quantum chemistry, and luminescence property[J]. Chin. J. Struct. Chem., 2021, 40(8): 1039-1046
14. [14]
  HAMIDI Z, MOSAVIAN S Y, SABBAGHI N, ZARCHI M A K, NOROOZIFAR M. Cross-linked poly(N-alkyl-4-vinylpyridinium) iodides as new eco-friendly inhibitors for corrosion study of St-37 steel in 1 M H₂SO₄[J]. Iran. Polym. J., 2020, 29(3): 225-239 doi: 10.1007/s13726-020-00787-8
15. [15]
  LUN H J, LI Y M, ZHANG X D, YANG J H, XIAO C Y, XU Y Q, LI J R. Different dimensional coordination polymers with 4, 4′-oxybis(benzoate): Syntheses, structures and properties[J]. J. Solid State Chem., 2014, 215: 277-283 doi: 10.1016/j.jssc.2014.04.016
16. [16]
  LI G F, QI X F, LI X M, JI J Y, NIU Y L, WANG Q W. Synthesis, crystal structure and theoretical calculations of a zinc(Ⅱ) coordination polymer assembled by 4, 4′-oxydibenzoic acid and 1, 3-bis(imidazol-1-ylmethyl)-benzene ligands[J]. J. Inorg. Organomet Polym., 2015, 25: 576-582 doi: 10.1007/s10904-014-0145-6
17. [17]
  LI X M, WANG Z T, VALTCHEV V, FANG Q R, PAN Y R. Syntheses, crystal structures and theoretical calculations of two nickel, zinc coordination polymers with 4-nitrophthalic acid and bis(imidazol) ligands[J]. J. Inorg. Organomet. Polym., 2020, 30: 477-485 doi: 10.1007/s10904-019-01206-z
18. [18]
  LI X M, PAN Y R, LIU B, ZHOU S. Syntheses, crystal structures and theoretical calculations of two cadmium(Ⅱ) complexes assembled by bis(imidazol) ligands[J]. Chinese J. Inorg. Chem., 2019, 35(7): 1275-1282
19. [19]
  LÜ Y, LI X M, HUANG Y J, LIU B, ZHOU S. Synthesis, structure and properties of zinc/cadmium complexes based on succinic acid ligands[J]. Chinese J. Inorg. Chem., 2022, 38(12): 2511-2520 doi: 10.11862/CJIC.2022.246
20. [20]
  YANG L, WANG F, AUPHEDEOUS D Y, FENG C L. Achiral isomers controlled circularly polarized luminescence in supramolecular hydrogels[J]. Nanoscale, 2019, 11(30): 14210-14215 doi: 10.1039/C9NR05033G
21. [21]
  WANG X, MU B, LIN H Y, LIU G C. Three new two-dimensional metal-organic coordination polymers derived from bis(pyridinecarboxamide)-1, 4-benzene ligands and 1, 3-benzenedicarboxylate: Syntheses and electrochemical property[J]. J. Organomet. Chem., 2011, 696(11/12): 2313-2321
22. [22]
  DOLENSKY B, KONVALINKA R, JAKUBEK M, KRAL V. Identification of intramolecular hydrogen bonds as the origin of malfunctioning of multitopic receptors[J]. J. Mol. Struct., 2013, 1035: 124-128 doi: 10.1016/j.molstruc.2012.09.040
23. [23]
  MOHAMED G G, EL-GAMEL N E A. Synthesis, investigation and spectroscopic characterization of piroxicam ternary complexes of Fe(Ⅱ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) with glycine and DL-phenylalanine[J]. Spectroc. Acta Pt. A‒Molec. Biomolec. Spectr., 2004, 60: 3141-3154 doi: 10.1016/j.saa.2004.01.035
24. [24]
  DONG M M, HE L L, FAN Y J, ZANG S Q, HOU H W, MAK T C W. Seven copper coordination polymers based on 5-iodo-isophthalic acid: Halogen-related bonding and N-donor auxiliary ligands modulating effect[J]. Cryst. Growth Des., 2013, 13(8): 3353-3364 doi: 10.1021/cg400033s
25. [25]
  SHI Z Q, LI Y Z, GUO Z J, ZHENG H G. Six new 2D or 3D metal- organic frameworks based on bithiophene-containing ligand and dicarboxylates: Syntheses, structures, and properties[J]. Cryst. Growth Des., 2013, 13(7): 3078-3086 doi: 10.1021/cg400490y
26. [26]
  GLASSON C R K, MEEHAN G V. MOTTI C A, CLEGG J K, TRUNER P, JENSEN P, LINDOY L F. New nickel(Ⅱ) and iron(Ⅱ) helicates and tetrahedra derived from expanded quaterpyridines[J]. Dalton Trans., 2011, 40: 10481-10490 doi: 10.1039/c1dt10667h
27. [27]
  PANDEY S, DAS P P, SINGH A K, MUKHERJEE R. Cobalt(Ⅱ), nickel(Ⅱ) and copper(Ⅱ) complexes of a hexadentate pyridine amide ligand: Effect of donor atom (ether vs. thioether) on coordination geometry, spin-state of cobalt and M^Ⅲ-M^Ⅱ redox potential[J]. Dalton Trans., 2011, 40: 10758-10768 doi: 10.1039/c1dt10661a
28. [28]
  MUKHOPADHYAY U, BERNAL I. Self-assembled hexameric water clusters stabilized by a cyano-bridged trimetallic complex[J]. Cryst. Growth Des., 2005, 5(5): 1687-1689 doi: 10.1021/cg0501940
29. [29]
  LI G L, LIU G Z, HUANG L L, LI L, ZHANG X. Ancillary ligand-mediated syntheses, structures and fluorescence of three Zn/Cd(Ⅱ) coordination polymers based on nitrobenzene dicarboxylate[J]. J. Inorg. Organomet. Polym., 2014, 24(3): 617-623 doi: 10.1007/s10904-014-0024-1
30. [30]
  REED A E, CURTISS L A, WEINHOLD F. Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint[J]. Chem. Rev., 1988, 88(6): 899-926 doi: 10.1021/cr00088a005
31. [31]
  CHEN Q, HU Y Y, NI L, YAO J, WANG L, JIANG Y H, ZHANG W L. Synthesis, crystal structures and fluorescent property of a 3D manganese(Ⅱ) coordination polymer with 2, 2′-bipyridine-4, 4′-dicarboxylic acid and 2-methyldipyrido [3, 2-f∶2′, 3′-h]quinoxaline[J]. Chinese J. Inorg. Chem., 2014, 30(6): 1481-1488
32. [32]
  GUO C H, LI H N, LI J, JIA J F, WU H S. Theoretical study on structure and property of iron carbonyl derivatives Fe(CO)_5-x(PR₃)_x[J]. Chinese J. Inorg. Chem., 2017, 33(7): 1187-1195
33. [33]
  LEE C T, YANG W T, PARR R G. Development of the colle-salvetti correlation-energy formula into a functional of the electron density[J]. Phys. Rev. B, 1988, 37(2): 785 doi: 10.1103/PhysRevB.37.785
34. [34]
  DUNNING T H, HAY P J. Gaussian basis sets for molecular calculations[C]//Schaefer H F. Methods of electronic structure theory. New York: Plenum Press, 1977: 1-28
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
3. [3]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
4. [4]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
5. [5]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
6. [6]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
7. [7]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
8. [8]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
9. [9]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
10. [10]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
11. [11]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
12. [12]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
13. [13]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
14. [14]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
15. [15]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
16. [16]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
17. [17]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
18. [18]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
19. [19]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
20. [20]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(170)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142