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Citation: Yuan ZHU, Xiaoda ZHANG, Shasha WANG, Peng WEI, Tao YI. Conditionally restricted fluorescent probe for Fe3+ and Cu2+ based on the naphthalimide structure[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232 shu

Conditionally restricted fluorescent probe for Fe3+ and Cu2+ based on the naphthalimide structure

  • College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China

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  • To address the lack of systematic studies on heavy metal fluorescent probes in typical buffer solutions, this study developed a Fe3+ and Cu2+ fluorescent probe, DHU-NP-4, based on a naphthalimide fluorophore. Comparative analysis of the probe's performance in various buffer systems revealed that buffers with high organic content are unsuitable for evaluating such probes. Furthermore, the pH of the solvent system was found to significantly influence the probe's behavior. Under highly acidic conditions (pH≥2), DHU-NP-4 exhibited exceptional specificity for Fe3+, while in alkaline conditions, it demonstrated high specificity for Cu2+. Leveraging these properties, the probe enabled the quantitative detection of Fe3+ and Cu2+ in solution.
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