Citation: Zhuo WANG, Xiaotong LI, Zhipeng HU, Junqiao PAN. Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223 shu

Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties

Guangzhou Greater Bay Technology Co., Ltd., Guangzhou 510000, China

Corresponding author: Zhuo WANG, wangzhuo@gbtrnd.com Xiaotong LI, lixiaotong@gbtrnd.com
Received Date: 13 June 2024
Revised Date: 17 October 2024

Figures(7)

Bi nanoparticles were decorated on three-dimensional porous carbon (3DPC) to prepare Bi/3DPC composite, in which the 3DPC acts as a carbon framework to buffer the volume expansion of the material during discharging and charging and to enhance the electrical conductivity of the material. Besides, the micropores and mesopores of 3DPC can increase the specific surface area of the material and provide active sites for the adsorption of sodium ions. Constructing nanoscale bismuth particles cushions the structural destruction during charge and discharge processes. The impedance decreased after 50 cycles at 0.5 A·g^-1, which indicates good long-term cycle stability of Bi/ 3DPC composite. And the charge storage mechanism of the materials was explored by performing cycle voltammetry tests at different scan rates, where capacitance behavior predominated. Meanwhile, Bi nanoparticles and the 3DPC take advantage of the synergistic effect, showing longterm cycle stability in sodium ion batteries. When placed under the current density of 5 A·g^-1, Bi/3DPC maintained a capacity of 268.52 mAh·g^-1 after 1 000 cycles.
- three-dimensional porous carbon,
- bismuth,
- sodium-ion battery,
- anode material
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