Citation: Xinzhe HUANG, Lihui XU, Yue YANG, Liming WANG, Zhangyong LIU, Zhongjian WANG. Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212 shu

Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr

Xinzhe HUANG ¹ ,
Lihui XU ^{1, 2,,} ,
Yue YANG ³ ,
Liming WANG ¹ ,
Zhangyong LIU ¹ ,
Zhongjian WANG ⁴

1.
School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
2.
National Innovation Center of Advanced Dyeing & Finishing Technology, Taian, Shandong 271000, China
3.
Shanghai Aurora Vocational College, Shanghai 201900, China
4.
Lishui Heli New Material Co., Lishui, Zhejiang 323000, China

Corresponding author: Lihui XU, xulh0915@163.com
Received Date: 4 June 2024
Revised Date: 14 September 2024

Figures(8)

BiSbO₄/BiOBr composites were synthesized using a two-step hydrothermal method and thoroughly characterized in their microscopic morphology, physical phase structure, chemical composition, optical properties, and photocatalytic performance. The study revealed that nanorod-structured BiSbO₄ was successfully deposited onto the surface of flaky BiOBr, forming a heterojunction that not only extended the photoresponsive range of the catalyst but also improved the separation efficiency of photogenerated electron-hole pairs. The photocatalytic activity under simulated visible light exceeded that of individual BiSbO₄ and BiOBr. With a BiSbO₄ mass fraction of 6%, the composite exhibited optimal photocatalytic degradation of methylene blue (MB), achieving a degradation rate of 91.3% after 120 min of irradiation. Furthermore, the degradation rate remained at 77.4% after four cycles.
- BiSbO₄/BiOBr,
- preparation,
- photocatalytic degradation,
- heterojunction structure
1. [1]
  HELMA S V, POLLITTB A, BARNETTA M A, CURRANA M A, CRAIGA Z R. Differentiating environmental concern in the context of psychological adaption to climate change[J]. Glob. Environ. Change-Human Policy Dimens., 2018,48:158-167. doi: 10.1016/j.gloenvcha.2017.11.012
2. [2]
  SHARMA N, BHARDWAJ N K, SINGH R B P. Environmental issues of pulp bleaching and prospects of peracetic acid pulp bleaching: A review[J]. J. Clean. Prod., 2020,256120338. doi: 10.1016/j.jclepro.2020.120338
3. [3]
  LONG C C, JIANG Z X, SHANGGUAN J F, QING T P, ZHANG P, FENG B. Applications of carbon dots in environmental pollution control: A review[J]. Chem. Eng. J., 2021,406126848. doi: 10.1016/j.cej.2020.126848
4. [4]
  SHARMA K, DUTTA V, SHARMA S, RAIZADA P, HOSSEINI-BANDEGHARAEI A, THAKUR P, SINGH P. Recent advances in enhanced photocatalytic activity of bismuth oxyhalides for efficient photocatalysis of organic pollutants in water: A review[J]. J. Ind. Eng. Chem., 2019,78:1-20. doi: 10.1016/j.jiec.2019.06.022
5. [5]
  LIU Y L, HE J Y, QI Y, WANG Y W, LONG F, WANG M. Preparation of flower-like BiOBr/Bi₂WO₆ Z-scheme heterojunction through an ion exchange process with enhanced photocatalytic activity[J]. Mat. Sci. Semicon. Process, 2022,137106195. doi: 10.1016/j.mssp.2021.106195
6. [6]
  SHARMA V K, FENG M B. Water depollution using metal-organic frameworks-catalyzed advanced oxidation processes: A review[J]. J. Hazard. Mater., 2019,372:3-16. doi: 10.1016/j.jhazmat.2017.09.043
7. [7]
  YANG Y, ZHAO Y X, WANG Y L, YANG S J. Study on the adsorption performance of nickel doped MIL-53(Fe) for methylene blue[J]. Industrial Water Treatment, 2023,23(11):154-160.
8. [8]
  YANG Y, ZHANG Y L, HU H, YANG S J. Research on preparation and absorption properties of H₃PMo₁₂O₄₀/MOF-808 composite[J]. Chemical Research and Application, 2023,35(4):862-869. doi: 10.3969/j.issn.1004-1656.2023.04.017
9. [9]
  NATARAJAN S, BAJAJ H C, TAYADE R J. Recent advances based on the synergetic effect of adsorption for removal of dyes from waste water using photocatalytic process[J]. J. Environ. Sci., 2018,65:201-222. doi: 10.1016/j.jes.2017.03.011
10. [10]
  SIVULA K, LE FORMAL F, GRÄTZEL M. Solar water splitting: Progress using hematite (α-Fe₂O₃) photoelectrodes[J]. ChemSusChem, 2011,4(4):432-449. doi: 10.1002/cssc.201000416
11. [11]
  CAO D P, WANG J, ZHANG J B, LIU S S, XU F T, SONG X, XU X, BAO X M, GAO Z Q. Mechanism investigation of the postnecking treatment to WO₃ photoelectrodes[J]. ACS Appl. Energy Mater., 2018,1(9):4670-4677. doi: 10.1021/acsaem.8b00805
12. [12]
  ERRANDONEA D, MUÑOZ A, RODRÍGUEZ-HERNÁNDEZ P, GOMIS O, ACHARY S N, POPESCU C, PATWE S J, TYAGI A K. High-pressure crystal structure, lattice vibrations, and band structure of BiSbO 4[J]. Inorg. Chem., 2016,55(10):4958-4969. doi: 10.1021/acs.inorgchem.6b00503
13. [13]
  LIU M, LV L, DU X M, LANG J Y, SU Y G, ZHAO Y X, WANG X J. Photo-synergistic promoted in situ generation of Bi⁰-BiSbO₄ nano-structures as an efficient catalyst for nitrobenzene reduction[J]. RSC Adv., 2015,5:103013-103018. doi: 10.1039/C5RA20004K
14. [14]
  ZHOU P W, ZHANG L P, DAI Y M, WU W, MAO Z P. Construction of a metallic silver nanoparticle-decorated bismuth oxybromide-based composite material as a readily recyclable photocatalyst[J]. J. Clean. Prod., 2019,246119007.
15. [15]
  NING R S, YAN Z S, LU Z Y, WANG Q K, WU Z L, DAI W X, FAN G D, FU X Z. Photocatalytic membrane for in situ enhanced removal of semivolatile organic compounds in membrane distillation under visible light[J]. Sep. Purif. Technol., 2022,292121068. doi: 10.1016/j.seppur.2022.121068
16. [16]
  ZUO W L, YU Y D, HUANG H. Making waves: Microbe-photocata-lyst hybrids may provide new opportunities for treating heavy metal polluted wastewater[J]. Water Res., 2021,195116984. doi: 10.1016/j.watres.2021.116984
17. [17]
  EGORYSHEVA A V, BERSENEVA A A, KUVSHINOVA T B, GAITKO O M. Synthesis of nanocrystalline BiSbO₄[J]. Russ. J. Inorg. Chem., 2017,62(9):1155-1161. doi: 10.1134/S0036023617090042
18. [18]
  LI J, LIU X, GUO L, TUO S, YANG Y. Novel 0D/2D Ag⁰/BiSbO₄ nanosheets with remarkably enhanced photocatalytic activity under simulated sunlight: Strong interfacial interaction, DFT calculation and degradation mechanism study[J]. Mater. Lett., 2023,338134049. doi: 10.1016/j.matlet.2023.134049
19. [19]
  EL-BAHY S M, ARSHAD J, MUNIR S, CHAUDHARY K, ALHASHMIALAMEER D, EDDY D R, WARSI M F, SHAHID M. Improved photocatalytic performance of a new silver doped BiSbO₄ photocatalyst[J]. Ceram. Int., 2022,48(16):23914-23920. doi: 10.1016/j.ceramint.2022.05.062
20. [20]
  AJMAL A, EL SAYED M E, WARSI M F, MURSHED M N, SAMIR A, EL-BAHY Z M, MUNIR S. Synthesis, characterization and photo-catalytic activity study of aluminium doped BiSbO₄ microflakes[J]. Ceram. Int., 2023,49(7):10976-10985. doi: 10.1016/j.ceramint.2022.11.292
21. [21]
  LI J, WANG J, ZHANG G K, LI Y, WANG K. Enhanced molecular molecular oxygen activation of Ni²⁺-doped BiO_2-x nanosheets under UV, visible and near-infrared irradiation: Mechanism and DFT study[J]. Appl. Catal. B-Environ., 2018,234:167-177. doi: 10.1016/j.apcatb.2018.04.016
22. [22]
  ZHAN L J. Preparation and photocatalytic performance of bismuth halide oxide (BiOX) composite materials[D]. Changchun: Jilin Jianzhu University, 2023: 12-20
23. [23]
  WANG Y M. Preparation and performance study of biobr based photocatalytic materials[D]. Lanzhou: Lanzhou University of Technology, 2023: 9-13
24. [24]
  WANG Z W, CHEN M, HUANG D L, ZENG G M, XU P, ZHOU C Y, LAI C, WANG H, CHENG M, WANG W J. Multiply structural optimized strategies for bismuth oxyhalide photocatalysis and their environmental application[J]. Chem. Eng. J., 2019,374:1025-1045. doi: 10.1016/j.cej.2019.06.018
25. [25]
  YE Y, ZANG Z G, ZHOU T W, DONG F, LU S R, TANG X S, WEI W, ZHANG Y B. Theoretical and experimental investigation of highly photocatalytic performance of CuInZnS nanoporous structure for removing the NO gas[J]. J. Catal., 2018,357:100-107. doi: 10.1016/j.jcat.2017.11.002
26. [26]
  WANG Z Z, WANG K, LI Y, JIANG L S, ZHANG G K. Novel BiSbO₄/BiOBr nanoarchitecture with enhanced visible-light driven photocatalytic performance: Oxygen-induced pathway of activation and mechanism unveiling[J]. Appl. Surf. Sci., 2019,498143850. doi: 10.1016/j.apsusc.2019.143850
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and visible light responsive photocatalytic properties of BiSbO4/BiOBr

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通讯作者: 陈斌, bchen63@163.com

Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr