Citation: Bing WEI, Jianfan ZHANG, Zhe CHEN. Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201 shu

Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction

1.
College of Resources and Environmental Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China
2.
College of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China

Corresponding author: Zhe CHEN, chenz@jlict.edu.cn
Received Date: 30 May 2024
Revised Date: 14 January 2025

Figures(11)

Electrocatalytic carbon dioxide reduction technology can effectively convert CO₂ into valuable chemicals to reduce CO₂ emissions, providing a solution for CO₂ management and helping China to achieve the carbon emission target of"carbon peak and carbon neutrality". Currently, the commonly used monometallic nanocatalysts have the shortcomings of a single catalytic site and difficult regulation of the adsorption energy between products and intermediates, and face problems such as poor catalyst selectivity, activity, and stability. In contrast, bimetallic nanocatalysts have been widely studied due to the existence of two atomic coordinations, which can adjust the electronic structure of the catalyst, finely regulate the binding energy of the intermediates, and bring abundant and flexible active sites. This paper reviews the latest research progress of bimetallic nanocatalysts, mainly focusing on the fine regulation of bimetallic nanocatalysts, such as doping control, heterogeneous structure control, alloying control, and geometric structure control, and the catalytic mechanism of bimetal nanocatalysts such as synergistic effect, stress effect, and electronic effect. Moreover, the current shortcomings and future research of bimetallic nanocatalysts are discussed.
- electrocatalytic reduction CO₂,
- bimetallic nanocatalyst,
- catalyst,
- electrochemistry,
- nanomaterial
1. [1]
  HE F, TONG S, LUO Z Y, DING H R, CHENG Z Y, LI C X, QI Z F. Accelerating net-zero carbon emissions by electrochemical reduction of carbon dioxide[J]. J. Energy Chem., 2023,79:398-409. doi: 10.1016/j.jechem.2023.01.020
2. [2]
  ZHANG X L, GUO S X, GANDIONCO K A, BOND A M, ZHANG J. Electrocatalytic carbon dioxide reduction: From fundamental principles to catalyst design[J]. Mater. Today Adv., 2020,7100074. doi: 10.1016/j.mtadv.2020.100074
3. [3]
  PENG W K, LI F F, KONG S Y, GUO C X, WU H T, WANG J C, SHEN Y, MENG X G, ZHANG M X. Recent advances in nickel based catalysts in e CO₂RR for carbon neutrality[J]. Carbon Energy, 2024,6(2)e498. doi: 10.1002/cey2.498
4. [4]
  CHEN H, DONG F Y, MINTEER S D. The progress and outlook of bioelectrocatalysis for the production of chemicals, fuels and materials[J]. Nat. Catal., 2020,3(3):225-244. doi: 10.1038/s41929-019-0408-2
5. [5]
  LIANG J, LI Z X, HE X, LUO Y S, ZHENG D D, WANG Y, LI T S, YING B W, SUN S J, CAI Z W, LIU Q, TANG B, SUN X P. Electrocatalytic seawater splitting: Nice designs, advanced strategies, challenges and perspectives[J]. Mater. Today, 2023,69:193-235. doi: 10.1016/j.mattod.2023.08.024
6. [6]
  WANG G X. A significant breakthrough in electrocatalytic reduction of CO₂ to ethylene and ethanol[J]. Sci. China Chem., 2020,63(8)10231024.
7. [7]
  WEI B. Structural regulation of copperand carbonbased catalysts and their electrochemical CO₂ conversion performance[D]. Zhenjiang: Jiangsu University, 2021: 1-6
8. [8]
  ADEGOKE K A, ADEGOKE R O, IBRAHIM A O, ADEGOKE S A, BELLO O S. Electrocatalytic conversion of CO₂ to hydrocarbon and alcohol products: Realities and prospects of Cu based materials[J]. Sustain. Mater. Technol., 2020,25e00200.
9. [9]
  LI X D, WANG S M, LI L, ZU X L, SUN Y F, XIE Y. Opportunity of atomically thin two-dimensional catalysts for promoting CO₂ electroreduction[J]. Accounts Chem. Res., 2020,53(12):2964-2974. doi: 10.1021/acs.accounts.0c00626
10. [10]
  LI R Z, WANG D S. Superiority of dual-atom catalysts in electrocatalysis: One step further than singleatom catalysts[J]. Adv. Energy Mater., 2022,12(9)2103564. doi: 10.1002/aenm.202103564
11. [11]
  LIU K H, LI J, LIU Y Y, WANG M R, CUI H T. Dual metal atom catalysts: Advantages in electrocatalytic reactions[J]. J. Energy Chem., 2023,79:515-534. doi: 10.1016/j.jechem.2023.01.021
12. [12]
  REN S, LEES E W, HUNT C, JEWLAL A, KIM Y, ZHANG Z S, MOWBRAY B A W, FINK A G, MELO L, GRANT E R, BERLINGUETTE C P. Catalyst aggregation matters for immobilized molecular CO₂RR electrocatalysts[J]. J. Am. Chem. Soc., 2023,145(8):4414-4420. doi: 10.1021/jacs.2c08380
13. [13]
  LI J C, KUANG Y, MENG Y T, TIAN X, HUNG W H, ZHANG X, LI A W, XU M Q, ZHOU W, KU C Y, CHIANG C Y, ZHU G Z, GUO J Y, SUN X M, DAI H J. Electroreduction of CO₂ to formate on a copper based electrocatalyst at high pressures with high energy conversion efficiency[J]. J. Am. Chem. Soc., 2020,142(16)72767282.
14. [14]
  THEVENON A, ROSAS-HERNáNDEZ A, FONTANI HERREROS A M, AGAPIE T, PETERS J C. Dramatic HER suppression on Ag electrodes via molecular films for highly selective CO₂ to CO reduction[J]. ACS Catal., 2021,11(8):4530-4537. doi: 10.1021/acscatal.1c00338
15. [15]
  ZHU Y T, CUI X Y, LIU H L, GUO Z G, DANG Y F, FAN Z X, ZHANG Z C, HU W P. Tandem catalysis in electrochemical CO₂ reduction reaction[J]. Nano Res., 2021,14(12):4471-4486. doi: 10.1007/s12274-021-3448-2
16. [16]
  ZHANG B A, NOCERA D G. Cascade electrochemical reduction of carbon dioxide with bimetallic nanowire and foam electrodes[J]. ChemElectroChem, 2021,8(10):1918-1924. doi: 10.1002/celc.202100295
17. [17]
  REN H A, WANG X Y, ZHOU X M, WANG T, LIU Y P, WANG C, GUAN Q X, LI W. In-situ constructing Cu₁Bi₁ bimetallic catalyst to promote the electroreduction of CO₂ to formate by synergistic electronic and geometric effects[J]. J. Energy Chem., 2023,79:263-271. doi: 10.1016/j.jechem.2023.01.017
18. [18]
  ZHAO G X, HUANG X B, WANG X X, WANG X K. Progress in catalyst exploration for heterogeneous CO₂ reduction and utilization: A critical review[J]. J. Mater. Chem. A, 2017,5(41):21625-21649. doi: 10.1039/C7TA07290B
19. [19]
  MENG Y X, HUANG H J, ZHANG Y, CAO Y Y, LU H F, LI X. Recent advances in the theoretical studies on the electrocatalytic CO₂ reduction based on single and double atoms[J]. Front. Chem., 2023,111172146. doi: 10.3389/fchem.2023.1172146
20. [20]
  ROTH ZAWADZKI A M, NIELSEN A J, TANKARD R E, KIBSGAARD J. Dual and triple atom electrocatalysts for energy conversion (CO₂RR, NRR, ORR, OER, and HER): Synthesis, characterization, and activity evaluation[J]. ACS Catal., 2024,14(2):1121-1145. doi: 10.1021/acscatal.3c05000
21. [21]
  CHEN Y, LIN J, PAN Q, LIU X, MA T Y, WANG X D. Inter-metal interaction of dual atom catalysts in heterogeneous catalysis[J]. Angew. Chem.-Int. Edit., 2023,62e202306469. doi: 10.1002/anie.202306469
22. [22]
  ZHAO Q, CRESPO-OTERO R, DI TOMMASO D. The role of copper in enhancing the performance of heteronuclear diatomic catalysts for the electrochemical CO₂ conversion to C1 chemicals[J]. J. Energy Chem., 2023,85:490-500. doi: 10.1016/j.jechem.2023.06.029
23. [23]
  YE R Z, ZHU J Y, TONG Y, FENG D M, CHEN P Z. Metal oxides heterojunction derived Bi-In hybrid electrocatalyst for robust electroreduction of CO₂ to formate[J]. J. Energy Chem., 2023,83:180-188. doi: 10.1016/j.jechem.2023.04.011
24. [24]
  WANG J, ZHU F F, CHEN B Y, DENG S, HU B C, LIU H, WU M, HAO J H, LI L H, SHI W D. B atom dopant-manipulate electronic structure of CuIn nanoalloy delivering wide potential activity over electrochemical CO₂RR[J]. Chin. J. Catal., 2023,49:132-140. doi: 10.1016/S1872-2067(23)64443-2
25. [25]
  JIA Y F, DING Y X, SONG T, XU Y L, LI Y Q, DUAN L L, LI F, SUN L C, FAN K. Dynamic surface reconstruction of amphoteric metal (Zn, Al) doped Cu₂O for efficient electrochemical CO₂ reduction to C 2+ products[J]. Adv. Sci., 2023,10(28)2303726. doi: 10.1002/advs.202303726
26. [26]
  CHANG F F, ZHU K, LIU C H, WEI J C, YANG S W, ZHANG Q, YANG L, WANG X L, BAI Z Y. Construction of Cu-Ni atomic pair with bimetallic atom-cluster sites for enhanced CO₂ electroreduction[J]. Adv. Funct. Mater., 2024,34(34)2400893. doi: 10.1002/adfm.202400893
27. [27]
  ZHANG Y Q, LIU H W, ZHAO S Y, XIE C, HUANG Z G, WANG S Y. Insights into the dynamic evolution of defects in electrocatalysts[J]. Adv. Mater., 2023,35(9)2209680. doi: 10.1002/adma.202209680
28. [28]
  ZHANG Y Y, LIU S L, JI N N, WEI L Z, LIANG Q Y, LI J J, TIAN Z Q, SU J W, CHEN Q W. Modulation of the electronic structure of metallic bismuth catalysts by cerium doping to facilitate electrocatalytic CO₂ reduction to formate[J]. J. Mater. Chem. A, 2024,12(13):7528-7535. doi: 10.1039/D4TA00091A
29. [29]
  GUO Y, WANG M L, ZHU Q J, XIAO D Q, MA D. Ensemble effect for single atom, small cluster and nanoparticle catalysts[J]. Nat. Catal., 2022,5(9):766-776. doi: 10.1038/s41929-022-00839-7
30. [30]
  WU M, XIONG Y S, HU B C, ZHANG Z Y, WEI B, LI L H, HAO J H, SHI W D. Indium doped bismuth subcarbonate nanosheets for efficient electrochemical reduction of carbon dioxide to formate in a wide potential window[J]. J. Colloid Interface Sci., 2022,624:261-269. doi: 10.1016/j.jcis.2022.05.054
31. [31]
  SHEN X Y, LIU X K, WANG S C, CHEN T, ZHANG W, CAO L L, DING T, LIN Y, LIU D, WANG L, ZHANG W, YAO T. Synergistic modulation at atomically dispersed Fe/Au interface for selective CO₂ electroreduction[J]. Nano Lett., 2021,21(1):686-692. doi: 10.1021/acs.nanolett.0c04291
32. [32]
  WEI H L, TAN A D, XIANG Z P, ZHANG J, PIAO J H, LIANG Z X, WAN K, FU Z Y. Modulating p-orbital of bismuth nanosheet by nickel doping for electrocatalytic carbon dioxide reduction reaction[J]. ChemSusChem, 2022,15(15)e202200752. doi: 10.1002/cssc.202200752
33. [33]
  BARREAU M, SALUSSO D, LI J, ZHANG J M, BORFECCHIA E, SOBCZAK K, BRAGLIA L, GALLET J J, TORELLI P, GUO H, LIN S, ZAFEIRATOS S. Ionic nickel embedded in ceria with high specific CO₂ methanation activity[J]. Angew. Chem. - Int. Edit., 2023e202302087.
34. [34]
  HASSAN J Z, ZAHEER A, RAZA A, LI G. Au-based heterostructure composites for photo and electro catalytic energy conversions[J]. Sustain. Mater. Technol., 2023,36e00609.
35. [35]
  GE Y Y, HUANG Z Q, LING C Y, CHEN B, LIU G G, ZHOU M, LIU J W, ZHANG X, CHENG H F, LIU G H, DU Y H, SUN C J, TAN C L, HUANG J T, YIN P F, FAN Z X, CHEN Y, YANG N L, ZHANG H. Phase selective epitaxial growth of heterophase nanostructures on unconventional 2H-Pd nanoparticles[J]. J. Am. Chem. Soc., 2020,142(44):18971-18980. doi: 10.1021/jacs.0c09461
36. [36]
  LI C, YAN S H, FANG J Y. Construction of lattice strain in bimetallic nanostructures and its effectiveness in electrochemical applications[J]. Small, 2021,17(46)e2102244. doi: 10.1002/smll.202102244
37. [37]
  SUN C W, HAO J H, WEI B, WU M, LIU H, XIONG Y S, HU B C, LI L H, CHEN M, SHI W D. Cu/CdCO₃ catalysts for efficient electrochemical CO₂ reduction over the wide potential window[J]. Chin. Chem. Lett., 2023,34(12)108520. doi: 10.1016/j.cclet.2023.108520
38. [38]
  XIONG Y S, WEI B, WU M, HU B C, ZHU F F, HAO J H, SHI W D. Rapid synthesis of amorphous bimetallic copper-bismuth electrocatalysts for efficient electrochemical CO₂ reduction to formate in a wide potential window[J]. J. CO₂ Util., 2021,51101621. doi: 10.1016/j.jcou.2021.101621
39. [39]
  ZHANG Y Z, JANG H, GE X, ZHANG W, LI Z J, HOU L Q, ZHAI L, WEI X Q, WANG Z, KIM M G, LIU S G, QIN Q, LIU X, CHO J. Singleatom Sn on tensile-Strained ZnO nanosheets for highly efficient conversion of CO₂ into formate[J]. Adv. Energy Mater., 2022,12(45)2202695. doi: 10.1002/aenm.202202695
40. [40]
  WANG H B, ZHANG H, HUANG Y, WANG H Y, OZDEN A, YAO K L, LI H M, GUO Q Y, LIU Y C, VOMIERO A, WANG Y H, QIAN Z, LI J, WANG Z Y, SUN X H, LIANG H Y. Strain in copper/ceria heterostructure promotes electrosynthesis of multicarbon products[J]. ACS Nano, 2023,17(1):346-354. doi: 10.1021/acsnano.2c08453
41. [41]
  ZHU Y, SUN X, ZHANG R, FENG X C, ZHU Y. Interfacial electronic interaction in amorphous-crystalline CeOx-Sn heterostructures for optimizing CO₂ to formate conversion[J]. Small, 2024,20(32)2400191. doi: 10.1002/smll.202400191
42. [42]
  BAO K L, ZHOU Y J, WU J, LI Z N, YAN X, HUANG H, LIU Y, KANG Z H. Super branched PdCu alloy for efficiently converting carbon dioxide to carbon monoxide[J]. Nanomaterials, 2023,13(3)603. doi: 10.3390/nano13030603
43. [43]
  HUANG H Z, LIU D, CHEN L W, ZHU Z J J, LI J N, YU Z L, SU X, JING X T, WU S Q, TIAN W J, YIN A X. Ultrathin dendritic Pd-Ag nanoplates for efficient and durable electrocatalytic reduction of CO₂ to formate[J]. Chem.-Asian J., 2023,18(9)e202300110. doi: 10.1002/asia.202300110
44. [44]
  LI H X, YUE X, QIU Y S, XIAO Z, YU X B, XUE C, XIANG J H. Selective electroreduction of CO₂ to formate over the coelectrodeposited Cu/Sn bimetallic catalyst[J]. Mater. Today Energy, 2021,21100797. doi: 10.1016/j.mtener.2021.100797
45. [45]
  LIU L Z, AKHOUNDZADEH H, LI M T, HUANG H W. Alloy cata-lysts for electrocatalytic CO₂ reduction[J]. Small Methods, 2023,7(9)2300482. doi: 10.1002/smtd.202300482
46. [46]
  TODOROKI N, ISHIJIMA M, CUYA HUAMAN J L, TANAKA Y, BALACHANDRAN J. Composition sensitive selectivity and activity of electrochemical carbon dioxide reduction on Pd-Cu solid-solution alloy nanoparticles[J]. Catal. Sci. Technol., 2023,13(17):5025-5032. doi: 10.1039/D3CY00748K
47. [47]
  XU Y Z, LI C L, XIAO Y Q, WU C H, LI Y M, LI Y B, HAN J G, LIU Q H, HE J F. Tuning the selectivity of liquid products of CO₂RR by Cu-Ag alloying[J]. ACS Appl. Mater. Interfaces, 2022,14(9):11567-11574. doi: 10.1021/acsami.2c00593
48. [48]
  KIM D, RESASCO J, YU Y, ASIRI A M, YANG P D. Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold copper bimetallic nanoparticles[J]. Nat. Commun., 2014,5(1)4948. doi: 10.1038/ncomms5948
49. [49]
  ILLAS F. Fundamental concepts in heterogeneous catalysis[J]. Angew. Chem.-Int. Edit., 2015,54(36):10404-10405. doi: 10.1002/anie.201506018
50. [50]
  WANG M, LIU S, CHEN B, TIAN F Y, PENG C. Synergistic geometric and electronic effects in Bi-Cu bimetallic catalysts for CO₂ electroreduction to formate over a wide potential window[J]. ACS Sustain. Chem. Eng., 2022,10(17):5693-5701. doi: 10.1021/acssuschemeng.2c01409
51. [51]
  SUN Y D, WANG F F, LIU F, ZHANG S K, ZHAO S L, CHEN J, HUANG Y, LIU X J, WU Y P, CHEN Y H. Accelerating Pd electrocatalysis for CO₂-to-formate conversion across a wide potential window by optimized incorporation of Cu[J]. ACS Appl. Mater. Interfaces, 2022,14(7):8896-8905. doi: 10.1021/acsami.1c19847
52. [52]
  DONG H, ZHU H, LI Q, ZHOU M, REN X C, MA T, LIU J Z, ZENG Z Y, LUO X L, LI S, CHENG C. Atomically structured metal-organic frameworks: A powerful chemical path for noble metal-based electrocatalysts[J]. Adv. Funct. Mater., 2023,33(22)2300294. doi: 10.1002/adfm.202300294
53. [53]
  WANG G Z, MA Y B, WANG J, LU P Y, WANG Y H, FAN Z X. Metal functionalization of two-dimensional nanomaterials for electrochemical carbon dioxide reduction[J]. Nanoscale, 2023,15(14)64566475.
54. [54]
  WANG F Q, ZHANG W L, WAN H B, LI C X, AN W K, SHENG X, LIANG X Y, WANG X P, REN Y L, ZHENG X, LV D C, QIN Y C. Recent progress in advanced core shell metal based catalysts for electrochemical carbon dioxide reduction[J]. Chin. Chem. Lett., 2022,33(5):2259-2269. doi: 10.1016/j.cclet.2021.08.074
55. [55]
  JIANG Y H, WANG Y T, CHEN R Z, LI Y H, LI C Z. Minireview and perspectives of bimetallic metal-organic framework electrocatalysts for carbon dioxide reduction[J]. Energy Fuel, 2023,37(23):17951-17965. doi: 10.1021/acs.energyfuels.3c01657
56. [56]
  DU C, LI P, ZHUANG Z H, FANG Z Y, HE S J, FENG L G, CHEN W. Highly porous nanostructures: Rational fabrication and promising application in energy electrocatalysis[J]. Coord. Chem. Rev., 2022,466214604. doi: 10.1016/j.ccr.2022.214604
57. [57]
  LI X F, ZHU Q L. MOF-based materials for photoand electrocatalytic CO₂ reduction[J]. EnergyChem, 2020,2(3)100033. doi: 10.1016/j.enchem.2020.100033
58. [58]
  WANG J, ZHANG Y M, MA Y B, YIN J W, WANG Y H, FAN Z X. Electrocatalytic reduction of carbon dioxide to high-value multicarbon products with metal-organic frameworks and their derived materials[J]. ACS Mater. Lett., 2022,4(11):2058-2079. doi: 10.1021/acsmaterialslett.2c00751
59. [59]
  LIU M X, PENG Y, CHEN W B, CAO S, CHEN S G, MENG F L, JIN Y C, HOU C C, ZOU R Q, XU Q. Metal-organic frameworks for carbon-neutral catalysis: State of the art, challenges, and opportunities[J]. Coord. Chem. Rev., 2024,506215726. doi: 10.1016/j.ccr.2024.215726
60. [60]
  GAO Y, XIAO H, MA X F, YUE Z Z, LIU C M, ZHAO M, ZHANG L, ZHANG J M, LUO E G, HU T J, LV B L, JIA J F, WU H S. Gallium-indium bimetal sites in the indiumgallium metal organic framework for efficient electrocatalytic reduction of carbon dioxide into formate[J]. J. Mater. Chem. A, 2024,12(14):8272-8280. doi: 10.1039/D4TA00270A
61. [61]
  YANG X X, DU Y R, LI X Q, DUAN G Y, CHEN Y M, XU B H. Covalent organic frameworks boost the silver electrocatalyzed reduction of CO₂: The electronic and confinement effect[J]. ACS Appl. Mater. Interfaces, 2023,15(26):31533-31542. doi: 10.1021/acsami.3c05679
62. [62]
  WANG J Y, HU H Y, LU S L, HU J D, ZHU H, DUAN F, DU M L. Conductive metal and covalent organic frameworks for electrocatalysis: Design principles, recent progress and perspective[J]. Nanoscale, 2022,14(2):277-288. doi: 10.1039/D1NR06197F
63. [63]
  WEI B, HAO J H, GE B X, LUO W, CHEN Y F, XIONG Y S, LI L H, SHI W D. Highly efficient electrochemical carbon dioxide reduction to syngas with tunable ratios over pyridinic-nitrogen rich ultrathin carbon nanosheets[J]. J. Colloid Interface Sci., 2022,60826502659.
64. [64]
  MA S C, WU K, FAN S J, LI Y, XIE Q, MA J X, YANG L J. Electrocatalytic CO₂ reduction enhanced by Sb doping in MOF-derived carbon-supported Bi-based materials[J]. Sep. Purif. Technol., 2024,339126520. doi: 10.1016/j.seppur.2024.126520
65. [65]
  ZHANG Q, HU P A, XU Z Y, TANG B B, ZHANG H R, XIAO Y H, WU Y C. Unravelling intrinsic descriptors based on a two-stage activity regulation of bimetallic 2D c-MOFs for CO₂RR[J]. Nanoscale, 2023,15(10):4991-5000. doi: 10.1039/D2NR07301C
66. [66]
  CHEN S H, LI W H, JIANG W J, YANG J R, ZHU J X, WANG L Q, OU H H, ZHUANG Z C, CHEN M Z, SUN X H, WANG D S, LI Y D. MOF encapsulating N-heterocyclic carbene-ligated copper singleatom site catalyst towards efficient methane electrosynthesis[J]. Angew. Chem.-Int. Edit., 2022,61(4)e202114450.
67. [67]
  WANG Q R, YANG X F, ZANG H, CHEN F R, WANG C, YU N, GENG B Y. Metal-organic framework-derived BiIn bimetallic oxide nanoparticles embedded in carbon networks for efficient electrochemical reduction of CO₂ to formate[J]. Inorg. Chem., 2022,61(30):12003-12011. doi: 10.1021/acs.inorgchem.2c01961
68. [68]
  YUE Y, CAI P Y, XU K, LI H Y, CHEN H Z, ZHOU H C, HUANG N. Stable bimetallic polyphthalocyanine covalent organic frameworks as superior electrocatalysts[J]. J. Am. Chem. Soc., 2021,143(43):18052-18060. doi: 10.1021/jacs.1c06238
69. [69]
  HOANG M T, HAN C, MA Z P, MAO X, YANG Y, MADANI S S, SHAW P, YANG Y C, PENG L Y, TOE C Y, PAN J, AMAL R, DU A J, TESFAMICHAEL T, HAN Z J, WANG H X. Efficient CO₂ reduction to formate on CsPbI 3 nanocrystals wrapped with reduced graphene oxide[J]. Nano-Micro Lett., 2023,15(1)161. doi: 10.1007/s40820-023-01132-3
70. [70]
  JIANG K, SANDBERG R B, AKEY A J, LIU X Y, BELL D C, NØRSKOV J K, CHAN K R, WANG H T. Metal ion cycling of Cu foil for selective C-C coupling in electrochemical CO₂ reduction[J]. Nat. Catal., 2018,1(2):111-119. doi: 10.1038/s41929-017-0009-x
71. [71]
  ZHANG T, TANG Y F, YU M L, LIU S, LIU L B, FU X Z, LUO J L, LIU S B. Smart design strategies of metal-based compounds for electrochemical CO₂ reduction: From microscopic structure to atomic level active site[J]. Chem. Catalysis, 2024,4(2)100906. doi: 10.1016/j.checat.2024.100906
72. [72]
  MA Y B, YU J L, SUN M Z, CHEN B, ZHOU X C, YE C L, GUAN Z Q, GUO W H, WANG G, LU S Y, XIA D S, WANG Y H, HE Z, ZHENG L, YUN Q B, WANG L Q, ZHOU J W, LU P Y, YIN J W, ZHAO Y F, LUO Z B, ZHAI L, LIAO L W, ZHU Z L, YE R Q, CHEN Y, LU Y, XI S B, HUANG B L, LEE C S, FAN Z X. Confined growth of silver copper Janus nanostructures with 100 facets for highly selective tandem electrocatalytic carbon dioxide reduction[J]. Adv. Mater., 2022,34(19)e2110607. doi: 10.1002/adma.202110607
73. [73]
  WEI B, XIONG Y S, ZHANG Z Y, HAO J H, LI L H, SHI W D. Efficient electrocatalytic reduction of CO₂ to HCOOH by bimetallic In-Cu nanoparticles with controlled growth facet[J]. Appl. Catal. B- Environ., 2021,283119646. doi: 10.1016/j.apcatb.2020.119646
74. [74]
  HAN L, WANG C W, LUO S S, ZHOU Y T, LI B, LIU M. Facet effects on bimetallic ZnSn hydroxide microcrystals for selective electrochemical CO₂ reduction[J]. Green Energy Environ., 2023,9(8):1314-1320.
75. [75]
  GU L, FTOUNI J, CHOWDHURY A D. Evaluating carbon dioxide reduction over copper supported on precipitated calcium carbonate via electrochemical route[J]. Mater. Today Chem., 2023,30101539. doi: 10.1016/j.mtchem.2023.101539
76. [76]
  ZHANG X H, SUN Z H, JIN R, ZHU C W, ZHAO C L, LIN Y, GUAN Q Q, CAO L N, WANG H W, LI S, YU H C, LIU X Y, WANG L L, WEI S Q, LI W X, LU J L. Conjugated dual size effect of core-shell particles synergizes bimetallic catalysis[J]. Nat. Commun., 2023,14(1)530. doi: 10.1038/s41467-023-36147-2
77. [77]
  SU X R, WANG C Y, ZHAO F, WEI T X, ZHAO D, ZHANG J T. Size effects of supported Cu based catalysts for the electrocatalytic CO₂ reduction reaction[J]. J. Mater. Chem. A, 2023,11(43):23188-23210. doi: 10.1039/D3TA04929A
78. [78]
  XIONG L K, ZHANG X, CHEN L, DENG Z, HAN S, CHEN Y F, ZHONG J, SUN H, LIAN Y B, YANG B Y, YUAN X Z, YU H, LIU Y, YANG X Q, GUO J, RÜMMELI M H, JIAO Y, PENG Y. Geometric modulation of local CO flux in Ag@Cu₂Onanoreactors for steering the CO₂RR pathway toward high-efficacy methane production[J]. Adv. Mater., 2021,33(32)2101741. doi: 10.1002/adma.202101741
79. [79]
  LIU L C, CORMA A. Structural transformations of solid electrocatalysts and photocatalysts[J]. Nat. Rev. Chem., 2021,5(4):256-276. doi: 10.1038/s41570-021-00255-8
80. [80]
  LI X D, WANG S M, LI L, SUN Y F, XIE Y. Progress and perspective for in situ studies of CO₂ reduction[J]. J. Am. Chem. Soc., 2020,142(21):9567-9581.
81. [81]
  MENDOZA D, DONG S T, LASSALLE-KAISER B. In situ/operando X-ray spectroscopy applied to electrocatalytic CO₂ reduction: Status and perspectives[J]. Curr. Opin. Colloid Interface Sci., 2022,61101635. doi: 10.1016/j.cocis.2022.101635
82. [82]
  HE Y Z, LIU S S, WANG M F, CHENG Q Y, JI H Q, QIAN T, YAN C L. Advanced in situ characterization techniques for direct observation of gas involved electrochemical reactions[J]. Energy Environ. Mater., 2023,6(6)e12552. doi: 10.1002/eem2.12552
83. [83]
  CAO X Y, TAN D X, WULAN B, HUI K S, HUI K N, ZHANG J T. In situ characterization for boosting electrocatalytic carbon dioxide reduction[J]. Small Methods, 2021,5(10)2100700. doi: 10.1002/smtd.202100700
84. [84]
  GONG Y, HE T. Gaining deep understanding of electrochemical CO₂RR with in situ/operando techniques[J]. Small Methods, 2023,7(11)2300702. doi: 10.1002/smtd.202300702
85. [85]
  LEE S H, LIN J C, FARMAND M, LANDERS A T, FEASTER J T, AVILÉS ACOSTA J E, BEEMAN J W, YE Y F, YANO J, MEHTA A, DAVIS R C, JARAMILLO T F, HAHN C, DRISDELL W S. Oxidation state and surface reconstruction of Cu under CO₂ reduction conditions from in situ X-ray characterization[J]. J. Am. Chem. Soc., 2020,143(2):588-592.
86. [86]
  XU Z Z, LIANG Z B, GUO W H, ZOU R Q. In situ/operando vibrational spectroscopy for the investigation of advanced nanostructured electrocatalysts[J]. Coord. Chem. Rev., 2021,436213824. doi: 10.1016/j.ccr.2021.213824
87. [87]
  HAN Y, XU H Z, LI Q, DU A J, YAN X C. DFT-assisted low-dimensional carbon-based electrocatalysts design and mechanism study: A review[J]. Front. Chem., 2023,111286257. doi: 10.3389/fchem.2023.1286257
88. [88]
  KIM H J, LEE G, OH S H V, STAMPFL C, SOON A. Recalibrating the experimentally derived structure of the metastable surface oxide on copper via machine learning-accelerated in silico global optimization[J]. ACS Nano, 2024,18(5):4559-4569. doi: 10.1021/acsnano.3c12249
89. [89]
  ZHANG Q M, WANG Z Y, ZHANG H, LIU X H, ZHANG W, ZHAO L B. Micro-kinetic modelling of CO reduction reaction on single atom catalysts accelerated by machine learning[J]. Phys. Chem. Chem. Phys., 2024,26(14):11037-11047. doi: 10.1039/D4CP00325J
90. [90]
  FENG H S, DING H, HE P N, WANG S, LI Z Y, ZHENG Z K, YANG Y S, WEI M, ZHANG X. Data-driven design of dual-metalsite catalysts for the electrochemical carbon dioxide reduction reaction[J]. J. Mater. Chem. A, 2022,10(36):18803-18811. doi: 10.1039/D2TA04556G
91. [91]
  ZHAI Z B, YAN W, DONG L, DENG S Q, WILKINSON D P, WANG X M, ZHANG L, ZHANG J J. Catalytically active sites of MOF derived electrocatalysts: Synthesis, characterization, theoretical calculations, and functional mechanisms[J]. J. Mater. Chem. A, 2021,9(36):20320-20344. doi: 10.1039/D1TA02896K
92. [92]
  ZHENG Y B, ZHANG Q, SHI J, LI J L, MEI S N, YU Q W, YANG J M, LÜ J. Research progress of catalysts for electrocatalytic reduction of CO₂ to various products[J]. Chemical Industry and Engineering Progress, 2022,41(3):1209-1223.
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