Citation: Long TANG, Yaxin BIAN, Luyuan CHEN, Xiangyang HOU, Xiao WANG, Jijiang WANG. Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180 shu

Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands

1.
Yan′an University Key Laboratory of New Energy & New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, Shaanxi 716000, China
2.
Shaanxi Jingyi Chemical Co., Ltd., Yulin, Shaanxi 719300, China

Corresponding author: Long TANG, ydtangl@126.com Jijiang WANG, yadxwjj@126.com
Received Date: 16 May 2024
Revised Date: 9 July 2024

Figures(17)

Three coordination polymers [Mn(epda)(2,2′-bipy)(H₂O)] (1), [Mn(epda)(phen)] (2), and [Co₂(epda)₂(bpe)₂(H₂O)₄]·5H₂O (3) (H₂epda=5-ethyl-pyridine-2,3-dicarboxylic acid, 2,2′-bipy=2,2′-bipyridine, phen=phenanthroline, bpe=1,2-bis(4-pyridyl) ethylene) were synthesized by solvothermal reactions and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, IR spectroscopy and elemental analysis. 1 displays a 1D chain structure, and these chains are joined by O—H…O hydrogen bonding and π-π stacking interactions to generate a 2D layer structure. 2 displays a 2D layer structure, and adjacent layers are generated 3D architecture through π-π stacking interactions. 3 displays a 1D chain structure, and adjacent chains are generated double layer structure through O—H…O hydrogen bonding. The fluorescent properties of 1 and 3 indicate that they can potentially be used as a luminescent sensor. 1 was highly selective and sensitive towards o-nitrophenol through different detection mechanisms, however, 3 was highly selective and sensitive towards 2,4,6-trinitrophenol. In addition, the magnetic behavior of 2 has also been investigated.
- coordination polymers,
- 5-ethyl-pyridine-2,3-dicarboxylate ligand,
- crystal structures,
- fluorescent properties,
- magnetic behavior
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