Citation: Jing LIANG, Qian WANG, Junfeng BAI. Synthesis and structures of cdq-topological quaternary and (4, 4, 8)-c topological quinary Zn-MOFs with both oxalic acid and triazole ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2186-2192. doi: 10.11862/CJIC.20240177 shu

Synthesis and structures of cdq-topological quaternary and (4, 4, 8)-c topological quinary Zn-MOFs with both oxalic acid and triazole ligands

School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Qian WANG, wangqhf@njtech.edu.cn Junfeng BAI, bjunfeng@njtech.edu.cn
Received Date: 15 May 2024
Revised Date: 21 August 2024

Figures(2)

Different solvothermal reactions of ZnC₂O₄ with oxalic acid (H₂ox) and 1, 2, 4-triazole (Htrz) successfully gave a new quaternary (NJTU-Bai83, NJTU-Bai=Nanjing Tech University Bai's group) and a new quinary (NJTU- Bai84) anionic metal-organic frameworks (MOFs), where NJTU-Bai83=(Me₂NH₂)₂[Zn₃(trz)₂(ox)₃]·2H₂O and NJTU-Bai84=(Me₂NH₂)[Zn₃(trz)₃(ox)₂]·H₂O, respectively. With the [Zn₂(ox)₄(trz)₂] secondary building unit (SBU) in NJTU- Bai83 replaced by the [Zn₃(ox)₂(trz)₆] and planar [Zn(ox)₂(trz)₂] ones in NJTU-Bai84, 2D supramolecular building layers (SBLs) are changed from the A-layer and B-layer to another A-layer, while pillars are transformed from the tetrahedral [Zn(ox)₂(trz)₂] SBU to the irregular tetrahedral [Zn(ox)₂(trz)₂] and planar [Zn(ox)₂(trz)₂] SBUs. Thus, cdq-topological quaternary NJTU-Bai83 is tuned to (4, 4, 8)-c new topological quinary NJTU-Bai84. Two MOFs were well characterized by powder X-ray diffraction, thermogravimetric analysis, elemental analysis, etc.
- controlled synthesis,
- multivariant metal-organic frameworks,
- pillar-layer typed structures
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