Citation: Xiao SANG, Qi LIU, Jianping LANG. Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158 shu

Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands

Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: Qi LIU, qi.liu@suda.edu.cn Jianping LANG, jplang@suda.edu.cn
Received Date: 7 May 2024
Revised Date: 12 July 2024

Figures(7)

Solvothermal reactions of 3, 5‐dinitrobenzoic acid (3, 5‐HDNBA), 4‐pyrazolecarboxylic acid (4‐H₂PyC) or 4‐ethylbenzoic acid (4‐HEBA) with Zn(NO₃)₂·6H₂O and 1, 2, 4, 5‐tetrakis(4‐vinylpyridyl) benzene (tkpvb) gave rise to three kinds of coordination polymers (CPs), [Zn(tkpvb)(3, 5‐DNBA)₂]_n (CP1), {[Zn(tkpvb)(4‐PyC)]·2H₂O]}_n (CP2), and {[Zn(tkpvb)_0.5(4‐EBA)₂]·H₂O}_n (CP3). CP1 has a 1D zigzag chain structure composed of Zn(Ⅱ), tkpvb, and 4‐EBA ligands. CP2 is a 3D topological structure that can be seen constructed from 2D [Zn(4‐PyC)₃]_n layers connected by tkpvb ligands. CP3 holds a 4 ‐ connected 3D topological structure, where 1D channels are present. CP1‐CP3 showed a fluorescence emission phenomenon, and they had certain responses to inorganic metal ions. Among them, Fe³⁺ ions had the greatest impact on the fluorescence intensity of CP1. In addition, after the addition of Fe³⁺, the fluorescence lifetime and fluorescence quantum yield of CP1 were significantly enhanced compared to CP2 and CP3, with a detection limit of 0.020 μmol·L^-1. This may be due to the interaction between Fe³⁺ and the uncoordinated pyridine groups in CP1.
- tetravinylpyridine,
- coordination polymer,
- structure,
- fluorescence,
- metal ion detection
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