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Citation: Jinglin CHENG, Xiaoming GUO, Tao MENG, Xu HU, Liang LI, Yanzhe WANG, Wenzhu HUANG. NiAlNd catalysts for CO2 methanation derived from the layered double hydroxide precursor[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152 shu

NiAlNd catalysts for CO2 methanation derived from the layered double hydroxide precursor

  • School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Figures(9)

  • The glycol solvent -thermal method prepared a serial of NiAlNd catalysts based on layered double hydrox-ides (LDHs) precursor. The introduction of Nd greatly promoted the catalytic activity for CO2 methanation at low temperatures. The CO2 conversion on the NiAlNd - 0.4 catalyst reached 83.9% under the reaction condition: T= 210 ℃, WHSV (weight hourly space velocity)=24 000 mL·g-1·h-1, p=100 kPa. The substitution of Nd3+ for Al3+ hin-dered the formation of LDHs structure in the precursor but decreased the particle size of the calcined catalyst. The interaction between NiO and Al2O3 was weakened with the introduction of Nd, resulting in better NiO component reducibility and high intrinsic activity of the Ni site. Moreover, the presence of Nd increased the number of surface basic sites of the catalyst, thus increasing the adsorption of CO2. With the increase in Nd, the surface area of metallic Ni in the reduced catalyst takes on a volcano-shape variation trend. The catalytic activities of NiAlNd catalysts are affected by the number and intrinsic activity of Ni sites simultaneously.
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