Citation: Jin CHANG. Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108 shu

Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂

Jin CHANG ^,

College of Energy and Materials Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

Corresponding author: Jin CHANG, changjin621@163.com
Received Date: 3 April 2024
Revised Date: 24 July 2024

Figures(11)

Co-doped Ni(OH)₂ was prepared by a simple co-precipitation method, and the electrochemical performance was improved by the Co/Ni synergistic effect. Co-doping refined the grain size of Ni(OH)₂, improved the morphology of the material, exposed more active sites, and improved the electrochemical activity of the material. Meanwhile, the first-principle calculation showed that Co-doping also changed the electron density distribution of Ni, leading to the improvement of the charge transport and ion diffusion properties of the material. Due to the appropriate quantity of Co doping, Ni_0.84Co_0.16(OH)₂ had excellent electrochemical energy storage of 1 589.6 F·g^-1 at the current density of 1 A·g^-1, far higher than that of Ni(OH)₂ (1 191.7 F·g^-1). Meanwhile, the assembled asymmetric super-capacitor had an energy density of 8.30 Wh·kg^-1 when the power density was 21.33 kW·kg^-1, showing a good energy storage performance and cycle performance.
- supercapacitor,
- nickel hydroxide,
- Co-doping
1. [1]
  Simon P, Gogotsi Y. Perspectives for electrochemical capacitors and related devices[J]. Nat. Mater., 2020,19(11):1151-1163.
2. [2]
  Zhu Q C, Zhao D Y, Cheng M Y, Zhou J Q, Owusu K A, Mai L Q, Yu Y. A new view of supercapacitors: Integrated supercapacitors[J]. Adv. Energy Mater., 2019,9(36)1901081. doi: 10.1002/aenm.201901081
3. [3]
  Zhang L, Yang S H, Chang J, Zhao D G, Wang J Q, Yang C, Cao B Q. A review of redox electrolytes for supercapacitors[J]. Front. Chem., 2020,8413. doi: 10.3389/fchem.2020.00413
4. [4]
  Libich J, Máca J, Vondrák J, Čech O, Sedlaříková M. Supercapacitors: Properties and applications[J]. J. Energy Storage, 2018,17:224-227. doi: 10.1016/j.est.2018.03.012
5. [5]
  Chatterjee D P, Nandi A K. A review on the recent advances in hybrid supercapacitors[J]. J. Mater. Chem. A, 2021,9(29):15880-15918. doi: 10.1039/D1TA02505H
6. [6]
  Choudhary N, Li C, Moore J, Nagaiah N, Zhai L, Jung Y, Thomas J. Asymmetric supercapacitor electrodes and devices[J]. Adv. Mater., 2017,29(21)1605336. doi: 10.1002/adma.201605336
7. [7]
  Shao Y L, El-Kady M F, Sun J Y, Li Y G, Zhang Q H, Zhu M F, Wang H Z, Dunn B, Kaner R B. Design and mechanisms of asymmetric supercapacitors[J]. Chem. Rev., 2018,118(18):9233-9280. doi: 10.1021/acs.chemrev.8b00252
8. [8]
  Liu R, Zhou A, Zhang X R, Mu J B, Che H W, Wang Y M, Wang T T, Zhang Z X, Kou Z K. Fundamentals, advances and challenges of transition metal compounds-based supercapacitors[J]. Chem. Eng. J., 2021,412128611. doi: 10.1016/j.cej.2021.128611
9. [9]
  Natarajan S, Ulaganathan M, Aravindan V. Building next-generation supercapacitors with battery type Ni(OH)₂[J]. J. Mater. Chem. A, 2021,9(28):15542-15585. doi: 10.1039/D1TA03262C
10. [10]
  Wu X L, Zeng F, Song X Y, Sha X F, Zhou H T, Zhang X G, Liu Z, Yu M H, Jiang C Z. In-situ growth of Ni(OH)₂ nanoplates on highly oxidized graphene for all-solid-state flexible supercapacitors[J]. Chem. Eng. J., 2023,456140947. doi: 10.1016/j.cej.2022.140947
11. [11]
  Zhu Y Y, An S L, Cui J L, Qiu H R, Sun X J, Zhang Y Q, He W X. Improving the specific capacity of nickel hydroxide nanocrystals via yttrium doping for application in hybrid supercapacitors[J]. CrystEngComm, 2019,21(27):4079-4084. doi: 10.1039/C9CE00625G
12. [12]
  Liao W X, Zhou G. Conditions for magnetic and electronic properties of ultrathin Ni-Fe hydroxide nanosheets as catalysts: A DFT+U study[J]. Sci. China-Mater., 2017,60(7):664-673. doi: 10.1007/s40843-017-9048-1
13. [13]
  Zhang L, Qin R Y, Pan Y P, Duan Z A, Li Y, Xi N, Jian L, Han S M. Boosting discharge capability of α-Ni(OH)₂ by cobalt doping based on robust spherical structure[J]. Int. J. Hydrog. Energy, 2022,47(2):1083-1091. doi: 10.1016/j.ijhydene.2021.10.040
14. [14]
  Bao Y X, Liu P, Zhang J X, Wang L, Wang M H, Mei H, Zhang Q, Chen C, Xiao Z Y. Construction of carbon quantum dots embed α-Co/Ni(OH)₂ hollo nanocages with enhanced supercapacitor performance[J]. J. Am. Ceram. Soc., 2020,103(8):4342-4351. doi: 10.1111/jace.17095
15. [15]
  Ma L, Kang C X, Fu L K, Cao S Y, Zhu H J, Liu Q M. Core-shell Ni_1.5Sn@Ni(OH)₂ nanoflowers as battery-type supercapacitor electrodes with high rate and capacitance[J]. J. Colloid Interface Sci., 2022,613:244-255. doi: 10.1016/j.jcis.2022.01.054
16. [16]
  Zhong W D, Li W L, Yang C F, Wu J, Zhao R, Idrees M, Xiang H, Zhang Q, Li X K. Interfacial electron rearrangement: Ni activated Ni(OH)₂ for efficient hydrogen evolution[J]. J. Energy Chem., 2021,61:236-242. doi: 10.1016/j.jechem.2021.02.013
17. [17]
  Zhu F, Zhou S Y, Sun M Y, Ma J F, Zhang W, Li K J, Cheng H, Komarneni S. Heterogeneous activation of persulfate by Mg doped Ni(OH)₂ for efficient degradation of phenol[J]. Chemosphere, 2022,286(Part 1)131647.
18. [18]
  Liang D W, Wu S L, Liu J, Tian Z F, Liang C H. Co-doped Ni hydroxide and oxide nanosheet networks: Laser-assisted synthesis, effective doping, and ultrahigh pseudocapacitor performance[J]. J. Mater. Chem. A, 2016,4(27):10609-10617. doi: 10.1039/C6TA03408J
19. [19]
  Chen H, Hu L F, Chen M, Yan Y, Wu L M. Nickel-cobalt layered double hydroxide nanosheets for high-performance supercapacitor electrode materials[J]. Adv. Funct. Mater., 2014,24(7):934-942. doi: 10.1002/adfm.201301747
20. [20]
  Liu Y, Fu N Q, Zhang G G, Xu M, Lu W, Zhou L M, Huang H T. Design of hierarchical Ni-Co@Ni-Co layered double hydroxide core-shell structured nanotube array for high-performance flexible all-solid-state battery-type supercapacitors[J]. Adv. Funct. Mater., 2017,27(8)1605307.
21. [21]
  Wang L, Chen H, Daniel Q, Duan L L, Philippe B, Yang Y, Rensmo H, Sun L C. Promoting the water oxidation catalysis by synergistic interactions between Ni(OH)₂ and carbon nanotubes[J]. Adv. Energy Mater., 2016,6(15)1600516.
22. [22]
  Li X, Wu H J, Elshahawy A M, Wang L, Pennycook S J, Guan C, Wang J. Cactus-like NiCoP/NiCo-OH 3D architecture with tunable composition for high-performance electrochemical capacitors[J]. Adv. Funct. Mater., 2018,28(20)1800036.
23. [23]
  Xu Z X, Ying Y R, Zhang G G, Li K Z, Liu Y, Fu N Q, Guo X Y, Yu F, Huang H T. Engineering NiFe layered double hydroxide by valence control and intermediate stabilization toward the oxygen evolution reaction[J]. J. Mater. Chem. A, 2020,8(48):26130-26138.
24. [24]
  Yue L G, Chen L, Wang X Y, Lu D Z, Zhou W L, Shen D J, Yang Q, Xiao S F, Li Y Y. Ni/Co-MOF@aminated MXene hierarchical electrodes for high-stability supercapacitors[J]. Chem. Eng. J., 2023,451138687.
25. [25]
  Li J H, Wang L L, He H J, Chen Y Q, Gao Z R, Ma N, Wang B, Zheng L L, Li R L, Wei Y J, Xu J Q, Xu Y, Cheng B W, Yin Z, Ma D. Interface construction of NiCo LDH/NiCoS based on the 2D ultrathin nanosheet towards oxygen evolution reaction[J]. Nano Res., 2022,15(6):4986-4995.
26. [26]
  Zhang W, Fan H F, Liu Q F, Ta N, Pu Y G, Chen X Z, Sui Y W, Wang E, Cao P. Nickel-rich NiCo LDHs supported on hollow carbon shells for hybrid supercapacitors[J]. Electrochim. Acta, 2021,395139167.
27. [27]
  Li Z L, Ning S L, Xu J C, Zhu J M, Yuan Z X, Wu Y L, Chen J, Xie F Y, Jin Y S, Wang N, Meng H, Sun S H. In situ electrochemical activation of Co(OH)₂@Ni(OH)₂ heterostructures for efficient ethanol electrooxidation reforming and innovative zinc-ethanol-air batteries[J]. Energy Environ. Sci., 2022,15(12):5300-5312.
28. [28]
  Zhao B T, Zhang L, Zhang Q B, Chen D C, Cheng Y, Deng X, Chen Y, Murphy R, Xiong X H, Song B, Wong C P, Wang M S, Liu M L. Rational design of nickel hydroxide-based nanocrystals on graphene for ultrafast energy storage[J]. Adv. Energy Mater., 2017,8(9)1702247.
29. [29]
  Chang J, Zhang S, Shi M J, Feng J, Liu Z, Wei T, Fan Z J. Ni, Co hydroxide modified by partial substitution of OH^- with Cl^- for boosting ultra-fast redox kinetics up to 500 mV·s^-1 in supercapacitors[J]. Adv. Funct. Mater., 2022,32(17)2109225.
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
4. [4]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
9. [9]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
10. [10]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
11. [11]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
12. [12]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
13. [13]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
14. [14]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
15. [15]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
17. [17]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
18. [18]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
19. [19]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(1081)
HTML views(241)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2

Metrics

通讯作者: 陈斌, bchen63@163.com

Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂