Citation: Baohua LÜ, Yuzhen LI. Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H) ferroelectric materials[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105 shu

Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H) ferroelectric materials

  • Corresponding author: Baohua LÜ, lvbaohua@ycu.edu.cn
  • Received Date: 2 April 2024
    Revised Date: 16 July 2024

Figures(6)

  • The mechanical stripping method prepared the 2H-phase α-In2Se3 (α-In2Se3(2H)) nanosheets. The structure and ferroelectric properties of the nanosheets were characterized by X-ray diffraction (XRD), Raman spectroscopy, spherical aberration electron microscopy, and piezoelectric force microscopy. The nanosheets were identified as α-In2Se3(2H) ferroelectric materials with a special structure. Further, a planar four-terminal device based on α-In2Se3 (2H) ferroelectricity was successfully constructed on the SiO2/Si substrate, and its photoresponse in all directions was investigated in detail. The results show that α-In2Se3(2H) with intrinsic structure has no photoresponse in both mutually perpendicular directions. After applying voltages at each end of the device, the α-In2Se3(2H) device shows obvious photoresponse in the mutually perpendicular directions. In particular, after utilizing a point voltage close to the direction of the easy polarization axis, the α-In2Se3(2H) device shows an anisotropic photoresponse.
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    1. [1]

      HUANG Y M, YUAN M J, LI Y L. Two-dimensional semiconducting materials and devices: From traditional two-dimensional optoelectronic materials to graphdiyne[J]. Chinese J. Inorg. Chem., 2017,33(11):1914-1936.

    2. [2]

      Pan Y, Zhao Q X, Gao F, Dai M J, Gao W, Zheng T, Su S C, Li J B, Chen H Y. Strong in-plane optical and electrical anisotropies of multilayered γ-InSe for high-responsivity polarization-sensitive photodetectors[J]. ACS Appl. Mater. Interfaces, 2022,14(18):21383-21391. doi: 10.1021/acsami.2c04204

    3. [3]

      Yang Y S, Liu S C, Li Z B, Xue D J, Hu J S. In-plane anisotropic 2D Ge-based binary materials for optoelectronic applications[J]. Chem. Commun., 2021,57(5):565-575. doi: 10.1039/D0CC04476H

    4. [4]

      Zhang Y, Yu W Z, Li J, Chen J, Dong Z, Xie L, Li C, Shi X Y, Guo W L, Lin S H, Mokkapati S, Zhang K. Ultra-broadband photodetection based on two-dimensional layered Ta2NiSe5 with strong anisotropy and high responsivity[J]. Mater. Des., 2021,208109894. doi: 10.1016/j.matdes.2021.109894

    5. [5]

      Chen W L, Chen A, Zhang R, Zeng J M, Zhang L H, Gu M Y, Wang C F, Huang M Y, Guo Y B, Duan H X, Hu C G, Shen W F, Niu B X, Watanabe K, Taniguchi T, Zhang J Y, Li J J, Cai X H, Liu G. Strong in-plane optoelectronic anisotropy and polarization sensitivity in low-symmetry 2D violet phosphorus[J]. Nano Lett., 2023,23(23):10821-10831. doi: 10.1021/acs.nanolett.3c02951

    6. [6]

      Sar H, Gao J, Yang X D. 2D layered SiP as anisotropic nonlinear optical material[J]. Sci. Rep., 2021,11(1)6372. doi: 10.1038/s41598-021-85938-4

    7. [7]

      Xie X, Ding J N, Wu B, Zheng H H, Li S F, Wang C T, He J, Liu Z W, Wang J T, Duan J A, Liu Y P. Observation of optical anisotropy and a linear dichroism transition in layered silicon phosphide[J]. Nanoscale, 2023,15(29):12388-12397. doi: 10.1039/D3NR01765F

    8. [8]

      Seo S B, Nah S, Sajjad M, Singh N, Shin Y, Kim Y, Kim J, Sim S. Ultrafast tunable broadband optical anisotropy in two-dimensional ReS2[J]. Phys. Rev. Appl., 2022,18(1)014010. doi: 10.1103/PhysRevApplied.18.014010

    9. [9]

      Cao Y D, Sun Y H, Shi S F, Wang R M. Anisotropy of two-dimensional ReS2 and advances in its device application[J]. Rare Met., 2021,40(12):3357-3374. doi: 10.1007/s12598-021-01781-6

    10. [10]

      Zhou Z Q, Shen T, Wang P, Guo Q L, Wang Q H, Ma C J, Xin K Y, Zhao K, Yu Y L, Qin B, Liu Y Y, Yang J H, Hong H, Liu K H, Liu C, Deng H X, Wei Z M. Low symmetric sub-wavelength array enhanced lensless polarization-sensitivity photodetector of germanium selenium[J]. Sci. Bull., 2023,68(2):173-179. doi: 10.1016/j.scib.2023.01.013

    11. [11]

      Cui Y, Zhou Z Q, Wang X H, Wang X T, Ren Z H, Pan L F, Yang J H. Wavelength-selectivity polarization dependence of optical absorption and photoresponse in SnS nanosheets[J]. Nano Res., 2021,14(7):2224-2230. doi: 10.1007/s12274-020-3197-7

    12. [12]

      Zhao J L, Ma D Y, Wang C, Guo Z N, Zhang B, Li J Q, Nie G H, Xie N, Zhang H. Recent advances in anisotropic two-dimensional materials and device applications[J]. Nano Res., 2020,14(4):897-919.

    13. [13]

      Cui C J, Hu W J, Yan X X, Addiego C, Gao W P, Wang Y, Wang Z, Li L Z, Cheng Y C, Li P, Zhang X X, Alshareef H N, Wu T, Zhu W G, Pan X Q, Li L J. Intercorrelated in-plane and out-of-plane ferroelectricity in ultrathin two-dimensional layered semiconductor In2Se3[J]. Nano Lett., 2018,18(2):1253-1258. doi: 10.1021/acs.nanolett.7b04852

    14. [14]

      Xiao J, Zhu H Y, Wang Y, Feng W, Hu Y X, Dasgupta A, Han Y, Wang Y, Muller D A, Martin L W, Hu P A, Zhang X X. Intrinsic two-dimensional ferroelectricity with dipole locking[J]. Phys. Rev. Lett., 2018,120(22)227601. doi: 10.1103/PhysRevLett.120.227601

    15. [15]

      Dai M J, Li K, Wang F K, Hu Y X, Zhang J, Zhai T Y, Yang B, Fu Y Q, Cao W W, Jia D C, Zhou Y, Hu P A. Intrinsic dipole coupling in 2D van der Waals ferroelectrics for gate-controlled switchable rectifier[J]. Adv. Electron. Mater., 2019,6(2)1900975.

    16. [16]

      Ding W J, Zhu J B, Wang Z, Gao Y F, Xiao D, Gu Y, Zhang Z Y, Zhu W G. Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other Ⅲ2-Ⅵ3 van der Waals materials[J]. Nat. Commun., 2017,814956. doi: 10.1038/ncomms14956

    17. [17]

      Küpers M, Konze P M, Meledin A, Mayer J, Englert U, Wuttig M, Dronskowski R. Controlled crystal growth of indium selenide, In2Se3, and the crystal structures of α-In2Se3[J]. Inorg. Chem., 2018,57(18):11775-11781. doi: 10.1021/acs.inorgchem.8b01950

    18. [18]

      Liu L X, Dong J Y, Huang J Q, Nie A M, Zhai K, Xiang J Y, Wang B C, Wen F S, Mu C P, Zhao Z S, Gong Y J, Tian Y J, Liu Z Y. Atomically resolving polymorphs and crystal structures of In2Se3[J]. Chem. Mater., 2019,31(24):10143-10149. doi: 10.1021/acs.chemmater.9b03499

    19. [19]

      Xue F, He J H, Zhang X X. Emerging van der Waals ferroelectrics: Unique properties and novel devices[J]. Appl. Phys. Rev., 2021,8021316. doi: 10.1063/5.0028079

    20. [20]

      Lv B H, Yan Z, Xue W H, Yang R L, Li J Y, Ci W J, Pang R X, Zhou P, Liu G, Liu Z Y, Zhu W G, Xu X H. Layer-dependent ferroelectricity in 2H-stacked few-layer α-In2Se3[J]. Mater. Horiz., 2021,8(5):1472-1480. doi: 10.1039/D0MH01863E

    21. [21]

      Wang S Y, Yang Z H, Wang D, Tan C, Yang L, Wang Z G. Strong anisotropic two-dimensional In2Se3 for light intensity and polarization dual-mode high-performance detection[J]. ACS Appl. Mater. Interfaces, 2023,15(2):3357-3364. doi: 10.1021/acsami.2c19660

    22. [22]

      Xue F, He X, Liu W H, Periyanagounder D, Zhang C H, Chen M G, Lin C H, Luo L Q, Yengel E, Tung V, Anthopoulos T D, Li L J, He J H, Zhang X X. Optoelectronic ferroelectric domain-wall memories made from a single van der Waals ferroelectric[J]. Adv. Funct. Mater., 2020,30(52)2004206. doi: 10.1002/adfm.202004206

    23. [23]

      Wan S Y, Li Y, Li W, Mao X Y, Zhu W G, Zeng H L. Room-temperature ferroelectricity and a switchable diode effect in two-dimensional α-In2Se3 thin layers[J]. Nanoscale, 2018,10(31):14885-14892. doi: 10.1039/C8NR04422H

    24. [24]

      Xue F, Hu W J, Lee K C, Lu L S, Zhang J W, Tang H L, Han A L, Hsu W T, Tu S B, Chang W H, Lien C H, He J H, Zhang Z D, Li L J, Zhang X X. Room-temperature ferroelectricity in hexagonally layered α-In2Se3 nanoflakes down to the monolayer limit[J]. Adv. Funct. Mater., 2018,28(50)1803738. doi: 10.1002/adfm.201803738

    25. [25]

      Xue F, Zhang J W, Hu W J, Hsu W T, Han A L, Leung S F, Huang J K, Wan Y, Liu S H, Zhang J L, He J H, Chang W H, Wang Z L, Zhang X X, Li L J. Multidirection piezoelectricity in mono- and multilayered hexagonal α-In2Se3[J]. ACS Nano, 2018,12(5):4976-4983. doi: 10.1021/acsnano.8b02152

    26. [26]

      Wang S Y, Liu L, Gan L R, Chen H W, Hou X, Ding Y, Ma S L, Zhang D W, Zhou P. Two-dimensional ferroelectric channel transistors integrating ultra-fast memory and neural computing[J]. Nat. Commun., 2021,12(1)53. doi: 10.1038/s41467-020-20257-2

    27. [27]

      Hou P F, Wang X H, Liu Y X, Chen Y, Dong S J, Guo H X, Wang J B, Zhong X L, Ouyang X P. A neutron irradiation-induced displacement damage of indium vacancies in α-In2Se3 nanoflakes[J]. Phys. Chem. Chem. Phys., 2020,2215799. doi: 10.1039/D0CP02375B

    28. [28]

      Zhou Y, Wu D, Zhu Y H, Cho Y J, He Q, Yang X, Herrera K, Chu Z D, Han Y, Downer M C, Peng H L, Lai K J. Out-of-plane piezoelectricity and ferroelectricity in layered α-In2Se3 nanoflakes[J]. Nano Lett., 2017,17(9):5508-5513. doi: 10.1021/acs.nanolett.7b02198

    29. [29]

      Lv B H, Xue W H, Yan Z, Yang R L, Wu H, Wang P, Zhang Y Y, Hou J N, Zhu W G, Xu X H. Control of photocurrent and multi-state memory by polar order engineering in 2H-stacked α-In2Se3 ferroelectric[J]. Sci. China Mater., 2022,65(6):1639-1645. doi: 10.1007/s40843-021-1920-9

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