Citation: Han ZHANG, Jianfeng SUN, Jinsheng LIANG. Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098 shu

Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor

Han ZHANG ¹ ,
Jianfeng SUN ^{1, 2} ,
Jinsheng LIANG ^{1, 2,,}

1.
Key Laboratory of Special Functional Materials for Ecological Environment and Information of Ministry of Education, Hebei University of Technology, Tianjin 300130, China
2.
Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Tianjin 300130, China

Corresponding author: Jinsheng LIANG, Liangjinsheng@hebut.edu.cn
Received Date: 27 March 2024
Revised Date: 27 October 2024

Figures(6)

A broadband near-infrared Na₃CrF₆ phosphor was synthesized by hydrothermal method, and its structure, microstructure, and photoluminescence properties were investigated. The results show that under excitation of 435 nm, the Na₃CrF₆ phosphor can emit broadband near-infrared light of 650-850 nm, with a peak at 738 nm and a half maximum width of 95 nm. The crystal field intensity of Cr³⁺ in Na₃CrF₆ phosphor was calculated to be 1.72 by analyzing spectral data, indicating that Cr³⁺ is located in the weak crystal field environment. The luminescent intensity of Na₃CrF₆ phosphor decreased slowly with the increase of heating temperature in the temperature range of 298-473 K.
- broadband near-infrared phosphor,
- hydrothermal synthesis,
- Na₃CrF₆,
- photoluminescent property,
- phosphor-converted light-emitting diode
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Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor