Citation: Weizhong LING, Xiangyun CHEN, Wenjing LIU, Yingkai HUANG, Yu LI. Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068 shu

Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid

Weizhong LING ^{1, #} ,
Xiangyun CHEN ^{2, #} ,
Wenjing LIU ² ,
Yingkai HUANG ² ,
Yu LI ^2,,

1.
Southern Marine Science and Engineering Guangdong Laboratory (Zhanjiang), Zhanjiang, Guangdong 524025, China
2.
Guangdong Engineering Technology Research Center of Special Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic University, Guangzhou 510300, China

Corresponding author: Yu LI, liyuletter@163.com
Received Date: 28 February 2024
Revised Date: 28 June 2024

Figures(11)

Three zinc(Ⅱ), cobalt(Ⅱ), and nickel(Ⅱ) coordination polymers, namely [Zn(μ₃-cpna)(μ-dpea)_0.5]_n (1), [Co(μ₃-cpna)(μ-dpey)_0.5]_n (2), and [Ni(μ₃-cpna)(μ-dpey)_0.5(H₂O)]_n (3), have been constructed hydrothermally using H₂cpna (5-(4-carboxyphenoxy)nicotinic acid), dpea (1, 2-di(4-pyridyl)ethane), dpey (1, 2-di(4-pyridyl)ethylene), and zinc, cobalt, and nickel chlorides at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system, space group P1. Compounds 1-3 show 2D layer structures. The catalytic activities in the Knoevenagel condensation reaction of these compounds were investigated. Compounds 1 and 2 exhibit effective catalytic activities in the Knoevenagel condensation reaction at room temperature. For this reaction, various parameters were optimized, followed by the investigation of the substrate scope.
- coordination polymer,
- dicarboxylic acid,
- catalytic property,
- Knoevenagel condensation reaction
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