Citation: Zhuo WANG, Junshan ZHANG, Shaoyan YANG, Lingyan ZHOU, Yedi LI, Yuanpei LAN. Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067 shu

Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition

  • Corresponding author: Yuanpei LAN, yplan@gzu.edu.cn
  • Received Date: 27 February 2024
    Revised Date: 11 July 2024

Figures(11)

  • CeCO3OH-rGO (reduced graphene oxide) was prepared by a one-step hydrothermal method, and CeO2-rGO composites were prepared by roasting under argon (Ar) atmosphere. The phase composition, microstructure, vacancy defects, and photoelectrochemical properties of the composites were studied by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, UV visible diffuse reflectance spectroscopy (UV-Vis DRS), etc. The photocatalytic performance of the composites with different GO (graphene oxide) and NH4HCO3 addition amounts respectively were comparatively studied. It was found that the CeO2-10rGO-15 with GO and NH4HCO3 addition amounts of 10 mg and 15 mmol respectively had the narrowest band-gap width (3.17 eV), and the photocatalytic degradation ratio of methylene blue (MB) could reach 80.66%. It is beneficial to the formation vacancy defect of CeO2 and the separation of photogenic carriers for rGO loading suitably, thus promoting photocatalytic performance.
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