Citation: Youlin SI, Shuquan SUN, Junsong YANG, Zijun BIE, Yan CHEN, Li LUO. Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061 shu

Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands

Youlin SI ^1,, ,
Shuquan SUN ¹ ,
Junsong YANG ¹ ,
Zijun BIE ¹ ,
Yan CHEN ¹ ,
Li LUO ^2,,

1.
Public Basic Institute, Bengbu Medical University, Bengbu, Anhui 233030, China
2.
School of Chemistry and Bioengineering, Suzhou University of Science and Technology, Suzhou, Jiangsu 215009, China

Corresponding author: Youlin SI, syl@bbmc.edu.cn Li LUO, luolichem08@163.com
Received Date: 26 February 2024
Revised Date: 21 June 2024

Figures(7)

Solvothermal reactions of a tetradentate imidazole-containing ligand, 3, 3', 5, 5'-tetraimidazolyl biphenyl (L), combined with Zn(Ⅱ) salt in the presence of varied auxiliary dicarboxylic acids yield two new metal-organic frameworks (MOFs) with (4, 4) topologies, namely [Zn₂(L) (BPDC)2]·H₂O (1) and [Zn₂(L) (OBA)₂] ·6H₂O (2), where H₂BPDC=4, 4'-biphenyldicarboxylic acid, H₂OBA=4, 4'-oxydibenzoic acid. Single crystal X-ray diffraction analysis has shown that complex 1 consists of 1D chains interconnected by Zn—N bonds, forming a layer structure, which can be further linked by BPDC^2- ligands, resulting in the formation of a 3D framework, while complex 2 consists of 2D layers with different 46-membered macrocycles, which are further connected by carboxylates to bring about 3D frameworks. Furthermore, activated complex 2(2') possesses remarkable selective adsorption characteristics for H₂O and EtOH. The photoluminescence properties of these MOFs were also thoroughly examined.
- 3, 3', 5, 5'-tetraimidazolyl biphenyl,
- metal-organic frameworks,
- mixed-ligand strategy,
- conjugated system,
- sorption property
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