Citation: Huihui LIU, Baichuan ZHAO, Chuanhui WANG, Zhi WANG, Congyun ZHANG. Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059 shu

Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram

1.
School of Materials Science and Engineering, North University of China, Taiyuan 030051, China
2.
School of Environmental Science and Engineering, Qingdao University, Qingdao, Shandong 266071, China

Corresponding author: Zhi WANG, shikouri@163.com Congyun ZHANG, zhangcy@qdu.edu.cn
Received Date: 3 February 2024
Revised Date: 16 July 2024

Figures(8)

Metal-organic framework (MOF) MIL-101 and surface plasmon polariton (SPP) supported gold nanoparticles (Au NPs) hybrid systems were developed as a highly sensitive and reproducible surface-enhanced Raman scattering (SERS) detection platform, in which a green electrostatic self-assembly technology was adopted to construct the substrate. In an aqueous solution, the electronegativity of the particles can be used to prepare the composite substrate without any surface modifier. Due to the enrichment capacity of MIL-101 and the electromagnetic enhancement from Au NPs, the well-designed MIL-101/Au composites possessed ultrahigh sensitivity with the detection limit of Rhodamine 6G (R6G) as low as 10^-10 mol·L^-1. Meanwhile, the substrate exhibits high stability, excellent reproducibility, and recyclability. Additionally, the novel substrate can be explored for direct capture, and sensitively detect pesticide residues such as thiram.
- MIL-101,
- Au nanoparticle,
- surface-enhanced Raman scattering,
- thiram
1. [1]
  Bernat A, Samiwala M, Albo J, Jiang X Y, Rao Q C. Challenges in SERS-based pesticide detection and plausible solutions[J]. J. Agric. Food. Chem., 2019,67(45):12341-12347. doi: 10.1021/acs.jafc.9b05077
2. [2]
  Zhao P N, Liu H Y, Zhang L N, Zhu P H, Ge S G, Yu J H. Paper-based SERS sensing platform based on 3D silver dendrites and molec-ularly imprinted identifier sandwich hybrid for neonicotinoid quantifi-cation[J]. ACS Appl. Mater. Interfaces, 2020,12(7):8845-8854. doi: 10.1021/acsami.9b20341
3. [3]
  Jin X, Zhu Q Y, Feng L, Li X, Zhu H Y, Miao H Y, Zeng Z F, Shi G. Light-trapping SERS substrate with regular bioinspired arrays for detecting trace dyes[J]. ACS Appl. Mater. Interfaces, 2021,13(9):11535-11542. doi: 10.1021/acsami.1c00702
4. [4]
  Li G J, Zhang X, Liu T T, Fan H X, Liu H C, Li S Y, Wang D W, Ding L. Dynamic microwave-assisted extraction combined with liquid phase microextraction based on the solidification of a floating drop for the analysis of organochlorine pesticides in grains followed by GC[J]. Food Sci. Human Wellness, 2021,10(3):375-382. doi: 10.1016/j.fshw.2021.02.029
5. [5]
  Birader K, Kumar P, Tammineni Y, Barla J A, Barla R, Suman P. Col-orimetric aptasensor for on-site detection of oxytetracycline antibiotic in milk[J]. Food Chem., 2021,356129659. doi: 10.1016/j.foodchem.2021.129659
6. [6]
  Park E, Lee J, Lee J, Lee J, Lee H S, Shin Y, Kim J H. Method for the simultaneous analysis of 300 pesticide residues in hair by LC-MS/MS and GC-MS/MS, and its application to biomonitoring of agricultural workers[J]. Chemosphere, 2021,277130215. doi: 10.1016/j.chemosphere.2021.130215
7. [7]
  Chen Z J, Wu H L, Xiao Z L, Fu H J, Shen Y D, Luo L, Wang H, Lei H T, Xu Z L. Rational hapten design to produce high-quality antibod-ies against carbamate pesticides and development of immunochro-matographic assays for simultaneous pesticide screening[J]. J. Hazard. Mater., 2021,412125241. doi: 10.1016/j.jhazmat.2021.125241
8. [8]
  Liebel M, Calderon I, Pazos-Perez N, Hulst N F V, Alvarez-Puebla R A. Widefield SERS for high-throughput nanoparticle screening[J]. Angew. Chem. Int. Ed., 2022,61(20)e202200072. doi: 10.1002/anie.202200072
9. [9]
  Zhu W Q, Crozier K B. Quantum mechanical limit to plasmonic enhancement as observed by surface-enhanced Raman scattering[J]. Nat. Commun., 2014,55228. doi: 10.1038/ncomms6228
10. [10]
  LIU Y J, YE F, WANG W, ZHANG J H, YAN C, YUAN A H. Fabri-cation of honeycomb-like Ag nanoparticles film used as surface enhanced Raman scattering substrate[J]. Chinese J. Inorg. Chem., 2019,35(10):1861-1868.
11. [11]
  Langer J, Jimenez de Aberasturi D, Aizpurua J. Present and future of surface-enhanced Raman scattering[J]. ACS Nano, 2019,14(1):28-117.
12. [12]
  Luo X J, Zhao X J, Wallace G Q, Wallace M H, Wilkinson K J, Wu P, Cai C X, Bazuin C J, Masson J F. Multiplexed SERS detection of microcystins with aptamer-driven core-satellite assemblies[J]. ACS Appl. Mater. Interfaces, 2021,13(5):6545-6556. doi: 10.1021/acsami.0c21493
13. [13]
  Zhang D J, You H J, Yuan L, Hao R, Li T, Fang J X. Hydrophobic slippery surface-based surface-enhanced Raman spectroscopy plat-form for ultrasensitive detection in food safety applications[J]. Anal. Chem., 2019,91(7):4687-4695. doi: 10.1021/acs.analchem.9b00085
14. [14]
  Lin J J, Liang L B, Ling X, Zhang S Q, Mao N N, Zhang N, Sumpter B J, Meunier V, Tong L M, Zhang J. Enhanced Raman scattering on in-plane anisotropic layered materials[J]. J. Am. Chem. Soc., 2015,137(49):15511-15517. doi: 10.1021/jacs.5b10144
15. [15]
  Ding S Y, You E M, Tian Z Q, Moskovits M. Electromagnetic theo-ries of surface-enhanced Raman spectroscopy[J]. Chem. Soc. Rev., 2017,46(13):4042-4076. doi: 10.1039/C7CS00238F
16. [16]
  LIU X Y, ZHANG D J, ZHANG H J, ZHANG C Y, LIU Y Q. Synthesis of Au@Ag core-shell nanoparticles for sensitive surface-enhanced Raman scattering by precisely adjust its morphology[J]. Chinese J. Inorg. Chem., 2018,34(4):712-718.
17. [17]
  Zhang K G, Yao S, Li G K, Hu Y L. One-step sonoelectrochemical fabrication of gold nanoparticle/carbon nanosheet hybrids for effi-cient surface-enhanced Raman scattering[J]. Nanoscale, 2015,7(6):2659-2666. doi: 10.1039/C4NR07082H
18. [18]
  Koh C S L, Sim H Y F, Leong S X, Boong S K, Chong C, Ling X Y. Plasmonic nanoparticle-metal-organic framework (NP-MOF) nanohy-brid platforms for emerging plasmonic applications[J]. ACS Mater. Lett., 2021,3(5):557-573. doi: 10.1021/acsmaterialslett.1c00047
19. [19]
  Lai H S, Li G K, Xu F G, Zhang Z M. Metal-organic frameworks: Opportunities and challenges for surface-enhanced Raman scatter-ing-A review[J]. J. Mater. Chem. C, 2020,8(9):2952-2963. doi: 10.1039/D0TC00040J
20. [20]
  Zhang Y, Xue C, Li P, Cui S S, Cui D X, Jin H. Metal-organic frame-work engineered corn-like SERS active Ag@Carbon with controlla-ble spacing distance for tracking trace amount of organic com-pounds[J]. J. Hazard. Mater., 2022,424127686. doi: 10.1016/j.jhazmat.2021.127686
21. [21]
  Xu Y J, Shi L X, Jing X H, Miao H Y, Zhang Y. SERS-active com-posites with Au-Ag Janus nanoparticles/perovskite in immunoassays for staphylococcus aureus enterotoxins[J]. ACS App.l Mater. Interfaces, 2022,14(2):3293-3301. doi: 10.1021/acsami.1c21063
22. [22]
  Sun H Z, Cong S, Zheng Z H, Wang Z, Chen Z G, Zhao Z G. Metal-organic frameworks as surface enhanced Raman scattering sub-strates with high tailorability[J]. J. Am. Chem. Soc., 2018,141(2):870-878.
23. [23]
  Sun H Z, Song G, Lu W B, Cong S, Zhao Z G, Gong W. Stabilizing photo-induced vacancy defects in MOF matrix for high-performance SERS detection[J]. Nano Res, 2022,15(6):5347-5354. doi: 10.1007/s12274-022-4185-x
24. [24]
  Osterrieth J W M, Wright D, Noh H, Kung C W, Vulpe D, Li A, Park J E, Jimenez D F. Core-shell gold nanorod@zirconium-based metal-organic framework composites as in situ size-selective Raman probes[J]. J. Am. Chem. Soc., 2019,141(9):3893-3900. doi: 10.1021/jacs.8b11300
25. [25]
  Li J, Liu Z F, Tian D H, Li B J, Shao L, Lou Z Z. Assembly of gold nanorods functionalized by zirconium-based metal-organic frame-works for surface enhanced Raman scattering[J]. Nanoscale, 2022,14(14):5561-5568. doi: 10.1039/D2NR00298A
26. [26]
  ZHENG L Z, KANG X W, JI Y, ZOU Z J, WANG Y M, CHEN J F. Preparation of Ag/ZIF-90 self-assembled membrane and its high SERS performance[J]. Chinese J. Inorg. Chem., 2015,31(3):465-471.
27. [27]
  Sun Y, Yu X X, Hu J Y, Zhuang X M, Wang J J, Qiu H X, Ren H T, Zhang S H, Zhang Y S, Hu Y J. Constructing a highly sensitivity SERS sensor based on a magnetic metal-organic framework (MOF) to detect the trace of thiabendazole in fruit juice[J]. ACS Sustain Chem. Eng., 2022,10:8400-8410.
28. [28]
  Liao J, Wang D M, Liu A Q, Hu Y L, Li G K. Controlled stepwise-synthesis of core-shell Au@MIL-100(Fe) nanoparticles for sensitive surface-enhanced Raman scattering detection[J]. Analyst, 2015,140(24):8165-8171.
29. [29]
  Cai Y Z, Wu Y P, Xuan T, Guo X Y, Wen Y, Yang H F. Core-shell Au@metal-organic frameworks for promoting Raman detection sensi-tivity of methenamine[J]. ACS Appl. Mater. Interfaces, 2018,10(18):15412-15417.
30. [30]
  He J C, Dong J W, Hu Y F, Li G K, Hu Y L. Design of Raman tag-bridged core-shell Au@Cu-3(BTC)(2) nanoparticles for Raman imag-ing and synergistic chemo-photothermal therapy[J]. Nanoscale, 2019,11(13):6089-6100.
31. [31]
  Zheng G C, de Marchi S, Lopez-Puente V, Sentosun K, Sentosun L, Perez-Juste I, Hill E H, Bals S, Liz-Marzán L M, Pastoriza-Santos I, Perez-Juste J. Encapsulation of single plasmonic nanoparticles within ZIF-8 and SERS analysis of the MOF flexibility[J]. Small, 2016,12(29):3935-3943.
32. [32]
  Jiang P C, Hu Y, Li G K. Biocompatible Au@Ag nanorod@ZIF-8 core-shell nanoparticles for surface-enhanced Raman scattering imaging and drug delivery[J]. Talanta, 2019,200:212-217.
33. [33]
  Li D, Cao X K, Zhang Q M, Ren X G, Jiang L, Li D W, Deng W, Liu H T. Facile in situ synthesis of core-shell MOF@Ag nanoparticle composites on screen-printed electrodes for ultrasensitive SERS detection of polycyclic aromatic hydrocarbons[J]. J. Mater. Chem. A, 2019,7(23):14108-14117.
34. [34]
  Zhang P, Liu G Q, Feng S J, Zhou X, Xu W S, Cai W P. Engineering of flexible granular Au nanocap ordered array and its surface en-hanced Raman spectroscopy effect[J]. Nanotechnology, 2020,31(3)035303.
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