Citation: Yu ZHANG, Fangfang ZHAO, Cong PAN, Peng WANG, Liangming WEI. Application of double-side modified separator with hollow carbon material in high-performance Li-S battery[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412 shu

Application of double-side modified separator with hollow carbon material in high-performance Li-S battery

Yu ZHANG ^{1, 2} ,
Fangfang ZHAO ² ,
Cong PAN ^3,, ,
Peng WANG ^4,, ,
Liangming WEI ^2,,

1.
College of Advanced Materials Engineering, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China
2.
School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
3.
College of Data Science, Jiaxing University, Jiaxing, Zhejiang 314001, China
4.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

Corresponding author: Cong PAN, pancong@zjxu.edu.cn Peng WANG, pengwang@zjxu.edu.cn Liangming WEI, lmwei@sjtu.edu.cn
Received Date: 30 October 2023
Revised Date: 31 March 2024

Figures(7)

To reduce the "shuttle effects" of lithium polysulfides (LIPs) and the lithium dendrites in Li-S batteries, the separator modified by hollow carbon material was prepared by the simple scraping method. It can be found from the contact angle tests that the layers formed by the porous carbon of uniform width exhibited both stronger attractions to LIPs and better permeability of electrolytes than the bare polypropylene (PP) separator. Permeation tests further showed an effective block over LIPs by the modification layers. Cathode symmetrical batteries with Celgard 3501 separator were assembled and the current response tests implied a conversion of LIPs to Li₂S catalyzed by hollow carbon materials. Lithium symmetrical batteries with modified separators were assembled and the voltage-time profile of charge-discharge processes showed better stability owing to the prevention of lithium dendrites. The Li-S batteries were assembled with sulfur loading of 1.8-2.0 mg·cm^-2 and with the bare PP, single-side modified, and double-side modified separators. Calculations of the diffusion coefficient of lithium-ion from galvanostatic intermittent titration technique (GITT) tests and Nyquist plots both indicated the faster ion transportation for the modified separators. Smaller semicircles for impedance were also found in the plots. Nyquist plots after the 1st, 5th, 10th, 50th, and 100th cycles were analyzed to show a stable diffusion behavior of lithium ions, which should be caused by the multichannel from hollow carbon material to provide more paths for Li⁺ ion transportation. Li-S batteries with double-side modified separators presented a high specific capacity of 1 035 mAh·g^-1 in the first cycle and 500 mAh·g^-1 after 700 cycles at the current density of 0.2C, 630 mAh·g^-1 after 100 cycles at 1C, and 505 mAh·g^-1 after 100 cycles at 2C. The rate performance also behaved superior to the cells with bare PP as the separator. The cell assembled with higher sulfur content (3.2 mg·cm^-2) also presented the reverse specific capacity of 500 mAh·g^-1 at 0.2C. These battery performances could be ascribed to the porous hollow carbon materials for their adsorption and conversion of LIPs and their prevention of dendrites. Thus, the physicochemical interaction between hollow carbon and LIPs effectively alleviates the shuttle effect and the bifunctional modification of the separator could prevent the growth of lithium dendrites to improve the safety of the Li-S batteries.
- Li-S battery,
- porous carbon,
- polysulfide,
- separator modification
1. [1]
  Sungjemmenla , Soni C B, Vineeth S K, Kumar V. Exploration of the unique structural chemistry of sulfur cathode for high-energy rechargeable beyond-Li batteries[J]. Adv. Energy Sustain. Res., 2021,3(5)2100157.
2. [2]
  Ma L B, Lv Y H, Wu J X, Chen Y M, Jin Z. Recent advances in emerging non-lithium metal-sulfur batteries: A review[J]. Adv. Energy Mater., 2021,11(24)2100770. doi: 10.1002/aenm.202100770
3. [3]
  ZHANG W, LIANG H S, ZHU K R, TIAN Y, LIU Y, CHEN J Y, LI W. Three-dimensional macro-/mesoporous C-TiC nanocomposites for dendrite-free lithium metal anode[J]. Acta Phys.-Chim. Sin., 2024,38(6)2105024.
4. [4]
  Zuo Y Z, Yan T, Zhu Y J, Zhou J, Su W M, Shi X L, Tang Y F, Chen Y F. MnO₂ nanoflowers grown on a polypropylene separator for use as both a barrier and an accelerator of polysulfides for high-performance Li-S batteries[J]. Dalton Trans., 2020,49(28):9719-9727. doi: 10.1039/D0DT01435D
5. [5]
  Zeng P, Chen M F, Jiang S X, Li Y F, Xie X, Liu H, Hu X Y, Wu C, Shu H B, Wang X Y. Architecture and performance of the novel sulfur host material based on Ti₂O₃ microspheres for lithium-sulfur batteries[J]. ACS Appl. Mater. Interfaces, 2019,11(25):22439-22448. doi: 10.1021/acsami.9b05874
6. [6]
  Chen M F, Wang X Y, Cai S Y, Ma Z Y, Song P, Fisher A C. Enhancing the performance of lithium-sulfur batteries by anchoring polar polymers on the surface of sulfur host materials[J]. J. Mater. Chem. A, 2016,4(41):16148-16156. doi: 10.1039/C6TA06863D
7. [7]
  Zhang Y, Ma L, Tang R X, Zhao F F, Niu S L, Su W D, Pan C, Wei L M. Hollow carbon nanospheres coated by δ-MnO₂ as S host to enhance the catalytic conversion of polysulfides in Li-S batteries[J]. Appl. Surf. Sci., 2022,585152498. doi: 10.1016/j.apsusc.2022.152498
8. [8]
  Du Z L, Lei Z P, Yan H L, Wang D D, Wang J C, Yan J C, Li Z K, Shui H F, Ren S B, Wang Z C, Kong Y. HNO₃ pre-oxidation-tuned microstructures of porous carbon derived from high-sulfur coal for enhancing capture and catalytic conversion of polysulfides[J]. Fuel, 2022,326125066. doi: 10.1016/j.fuel.2022.125066
9. [9]
  WANG X W. Layered hexagonal Co_1-xS decorating N-doped carbon nanotubes as a sulfur host for Li-S batteries[J]. Chinese J. Inorg. Chem., 2022,38(10):2065-2071. doi: 10.11862/CJIC.2022.180
10. [10]
  SUN L, XIE J, CHENG F, CHEN R Y, ZHU Q L, JIN Z. Rapid construction of two-dimensional N, S-co-doped porous carbon for realizing high-performance lithium-sulfur batteries[J]. Chinese J. Inorg. Chem., 2022,38(6):1189-1198.
11. [11]
  Tian D, Song X Q, Wang M X, Wu X, Qiu Y, Guan B, Xu X Z, Fan L S, Zhang N Q, Sun K N. MoN supported on graphene as a bifunctional interlayer for advanced Li-S batteries[J]. Adv. Energy Mater., 2019,9(46)1901940. doi: 10.1002/aenm.201901940
12. [12]
  Wang X M, Zhang H G, Jiao H, Zhang X R, Shen Z H, Wen Y, He Q Y, Yao J, Cheng H T, Gao T, Wang X, Zhang H, Jiao H. CrP nanocatalyst within porous MOF architecture to accelerate polysulfide conversion in lithium-sulfur batteries[J]. ACS Appl. Mater. Interfaces, 2023,15(17):21040-21048. doi: 10.1021/acsami.3c01427
13. [13]
  Yoshida L, Hakari T, Matsui Y, Ishikawa M. Polyglycerol-functionalized microporous carbon/sulfur cathode for Li-S battery[J]. Electrochim. Acta, 2022,429141000. doi: 10.1016/j.electacta.2022.141000
14. [14]
  Li R X, Dai Y, Zhu W K, Xiao M, Dong Z W, Yu Z, Xiao H B, Yang T. Construction of porous carbon nanofibers with encapsulated sulfur as free-standing cathode material of lithium-sulfur batteries[J]. Ionics, 2022,28(5):2155-2162. doi: 10.1007/s11581-022-04476-9
15. [15]
  PAN P F, CHEN P, FANG Y N, SHAN Q, CHEN N N, FENG X M, LIU R Q, LI P, MA Y W. V₂O₅ hollow spheres as high efficient sulfur host for Li-S batteries[J]. Chinese J. Inorg. Chem., 2020,36(3):575-583.
16. [16]
  Wei C L, Wang Y S, Zhang Y C, Tan L W, Qian Y, Tao Y, Xiong S L, Feng J K. Flexible and stable 3D lithium metal anodes based on self-standing Mxene/COF frameworks for high-performance lithium-sulfur batteries[J]. Nano Res., 2021,14(10):3576-3584. doi: 10.1007/s12274-021-3433-9
17. [17]
  Zhou C, Hong M, Hu N T, Yang J H, Zhu W H, Kong L W, Li M. Bi-metallic coupling-induced electronic-state modulation of metal phosphides for kinetics-enhanced and dendrite-free Li-S batteries[J]. Adv. Funct. Mater., 2023,33(14)2213310. doi: 10.1002/adfm.202213310
18. [18]
  Yang C, You C Y, Zhang J, Yang R, Tian N, Ma L. Lithium-magnesium alloy as an anode for lithium-sulfur based batteries[J]. Int. J. Electrochem. Sci., 2019,14(9):8595-8600. doi: 10.20964/2019.09.25
19. [19]
  Liang X, Wen Z Y, Liu Y, Wu M F, Jin J, Zhang H, Wu X W. Improved cycling performances of lithium sulfur batteries with LiNO_3^-modified electrolyte[J]. J. Power Sources, 2011,196(22):9839-9843. doi: 10.1016/j.jpowsour.2011.08.027
20. [20]
  Xu R, Li J C M, Lu J, Amine K, Belharouak I. Demonstration of highly efficient lithium-sulfur batteries[J]. J. Mater. Chem. A, 2015,3(8):4170-4179. doi: 10.1039/C4TA06641C
21. [21]
  Zhang L, Ling M, Feng J, Mai L Q, Liu G, Guo J H. The synergetic interaction between LiNO₃ and lithium polysulfides for suppressing shuttle effect of lithium-sulfur batteries[J]. Energy Storage Mater., 2018,11:24-29. doi: 10.1016/j.ensm.2017.09.001
22. [22]
  Hu B, Ding B, Xu C, Fan Z J, Luo D R, Li P, Dou H, Zhang X G. Fabrication of a covalent triazine framework functional interlayer for high-performance lithium-sulfur batteries[J]. Nanomaterials, 2022,12(2)255. doi: 10.3390/nano12020255
23. [23]
  Chen D L, Zhu M, Zhan W W, Long L, Yu L, Zhu T, Kang P B, Yang X P, Sui G. Fe, N co-doped mesoporous carbon spheres as barrier layer absorbing and reutilizing polysulfides for high-performance Li-S batteries[J]. J. Mater. Sci., 2022,57(28):13527-13540.
24. [24]
  Wang X, Yang L W, Li R, Chen Y X, Wu Z G, Zhong B H, Guo X D. Heteroatom-doped ginkgo folium porous carbon modified separator for high-capacity and long-cycle lithium-sulfur batteries[J]. Appl. Surf. Sci., 2022,602154342. doi: 10.1016/j.apsusc.2022.154342
25. [25]
  Tan T X, Chen N N, Wang Z K, Tang Z M, Zhang H R, Lai Q X, Liang Y Y. Thorn-like carbon nanofibers combined with molybdenum nitride nanosheets as a modified separator coating: An efficient chemical anchor and catalyst for Li-S batteries[J]. ACS Appl. Energy Mater., 2022,5(6):6654-6662. doi: 10.1021/acsaem.2c00080
26. [26]
  YANG X B, HU X N, SUN X. Effect of acetylene black coating on properties of lithium-sulfur batteries[J]. Chinese J. Inorg. Chem., 2021,37(12):2203-2208. doi: 10.11862/CJIC.2021.248
27. [27]
  Liu C, Yin Z J, Deng H, Liu C, Zhao J, Lan Q, Tang S, Liang J, Cheng Q, Liu J, Cao Y C, Liu Z. Nitrogen-doped porous carbon as high-performance cathode material for lithium-sulfur battery[J]. ChemistrySelect, 2017,2(34):11030-11034. doi: 10.1002/slct.201702228
28. [28]
  Hu X Q, Shen K M, Han C, Li M Y, Guo J, Yan M Y, Zhang M A. Rational design of ultrathin Mo₂C/C nanosheets decorated on mesoporous hollow carbon spheres as a multifunctional sulfur host for advanced Li-S batteries[J]. J. Alloy. Compd., 2022,918165667. doi: 10.1016/j.jallcom.2022.165667
29. [29]
  Zhang Y, Tang R X, Ma L, Zhao F F, Tang G, Wang Y, Pan C, Pang A M, Li W, Wei L M. Nitrogen-doped hollow carbon boosting the anchoring of sulfur capacity for high-loading lithium-sulfur batteries[J]. Microporous Mesoporous Mater., 2022,335111837. doi: 10.1016/j.micromeso.2022.111837
30. [30]
  Zhang W, Zhang J F, Zhao Y, Wang X. Multi-functional carbon cloth infused with N-doped and co-coated carbon nanofibers as a current collector for ultra-stable lithium-sulfur batteries[J]. Mater. Lett., 2019,255126595. doi: 10.1016/j.matlet.2019.126595
31. [31]
  Lin D C, Liu Y Y, Liang Z, Lee H W, Sun J, Wang H T, Yan K, Xie J, Cui Y. Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes[J]. Nat. Nanotechnol., 2016,11(7):626-632. doi: 10.1038/nnano.2016.32
32. [32]
  Aslam M K, Jamil S, Hussain S, Xu M W. Effects of catalysis and separator functionalization on high-energy lithium-sulfur batteries: A complete review[J]. Energy Environ. Mater., 2023,6(3)e12420. doi: 10.1002/eem2.12420
33. [33]
  Ren W C, Zheng Y N, Cui Z H, Tao Y S, Li B X, Wang W T. Recent progress of functional separators in dendrite inhibition for lithium metal batteries[J]. Energy Storage Mater., 2021,35:157-168. doi: 10.1016/j.ensm.2020.11.019
34. [34]
  Baik S, Park J H, Lee J W. One-pot conversion of carbon dioxide to CNT-grafted graphene bifunctional for sulfur cathode and thin interlayer of Li-S battery[J]. Electrochim. Acta, 2020,330135264. doi: 10.1016/j.electacta.2019.135264
35. [35]
  Pang Y, Wei J S, Wang Y G, Xia Y Y. Synergetic protective effect of the ultralight mwcnts/ncqds modified separator for highly stable lithium-sulfur batteries[J]. Adv. Energy Mater., 2018,8(10)1702288. doi: 10.1002/aenm.201702288
36. [36]
  Cai W L, Li G R, He F, Jin L M, Liu B H, Li Z P. A novel laminated separator with multi functions for high-rate dischargeable lithium-sulfur batteries[J]. J. Power Sources, 2015,283:524-529. doi: 10.1016/j.jpowsour.2015.03.085
37. [37]
  Chung S H, Manthiram A. High-performance Li-S batteries with an ultra-lightweight MWCNT-coated separator[J]. J. Phys. Chem. Lett., 2014,5(11):1978-1983. doi: 10.1021/jz5006913
38. [38]
  Zhao T, Ye Y, Peng X, Divitini G, Kim H K, Lao C Y, Coxon P R, Xi K, Liu Y J, Ducati C, Chen R, Kumar R V. Advanced lithium-sulfur batteries enabled by a bio-inspired polysulfide adsorptive brush[J]. Adv. Funct. Mater., 2016,26(46):8418-8426. doi: 10.1002/adfm.201604069
39. [39]
  Zhu J D, Ge Y Q, Kim D, Lu Y, Chen C, Jiang M J, Zhang X W. A novel separator coated by carbon for achieving exceptional high performance lithium-sulfur batteries[J]. Nano Energy, 2016,20:176-184. doi: 10.1016/j.nanoen.2015.12.022
40. [40]
  Vizintin A, Lozinšek M, Chellappan R K, Foix D, Krajnc A, Mali G, Drazic G, Genorio B, Dedryvère R, Dominko R. Fluorinated reduced graphene oxide as an interlayer in Li-S batteries[J]. Chem. Mater., 2015,27(20):7070-7081. doi: 10.1021/acs.chemmater.5b02906
41. [41]
  Yang K, Zhong L, Guan R T, Xiao M, Han D M, Wang S J, Meng Y Z. Carbon felt interlayer derived from rice paper and its synergistic encapsulation of polysulfides for lithium-sulfur batteries[J]. Appl. Surf. Sci., 2018,441:914-922. doi: 10.1016/j.apsusc.2018.02.108
42. [42]
  Li S Q, Ren G F, Hoque M N F, Dong Z H, Warzywoda J, Fan Z Y. Carbonized cellulose paper as an effective interlayer in lithium-sulfur batteries[J]. Appl. Surf. Sci., 2017,396:637-643. doi: 10.1016/j.apsusc.2016.10.208
43. [43]
  Hou J, Cao T, Idrees F, Cao C. A co-sol-emulsion-gel synthesis of tunable and uniform hollow carbon nanospheres with interconnected mesoporous shells[J]. Nanoscale, 2016,8(1):451-457. doi: 10.1039/C5NR06279A
44. [44]
  Jiang S X, Chen M F, Wang X Y, Zeng P, Li Y F, Liu H, Li X L, Huang C, Shu H B, Luo Z G, Wu C. A tin disulfide nanosheet wrapped with interconnected carbon nanotube networks for application of lithium sulfur batteries[J]. Electrochim. Acta, 2019,313:151-160. doi: 10.1016/j.electacta.2019.05.001
45. [45]
  Yao W Q, Zheng W Z, Xu J, Tian C X, Han K, Sun W Z, Xiao S X. ZnS-SnS@NC heterostructure as robust lithiophilicity and sulfiphilicity mediator toward high-rate and long-life lithium-sulfur batteries[J]. ACS Nano, 2021,15(4):7114-7130. doi: 10.1021/acsnano.1c00270
46. [46]
  Guo P Q, Sun K, Shang X N, Liu D Q, Wang Y R, Liu Q M, Fu Y J, He D Y. Nb₂O₅/rGO nanocomposite modified separators with robust polysulfide traps and catalytic centers for boosting performance of lithium-sulfur batteries[J]. Small, 2019,15(40)1902363. doi: 10.1002/smll.201902363
47. [47]
  Hu N N, Lv X S, Dai Y, Fan L L, Xiong D B, Li X F. SnO₂/reduced graphene oxide interlayer mitigating the shuttle effect of Li-S batteries[J]. ACS Appl. Mater. Interfaces, 2018,10(22):18665-18674. doi: 10.1021/acsami.8b03255
48. [48]
  Chen X, Huang Y D, Li J, Wang X C, Zhang Y, Guo Y, Ding J, Wang L. Bifunctional separator with sandwich structure for high-performance lithium-sulfur batteries[J]. J. Colloid Interface Sci., 2020,559:13-20. doi: 10.1016/j.jcis.2019.10.001
49. [49]
  Wang X Y, Hao H, Liu J L, Huang T, Yu A S. A novel method for preparation of macroposous lithium nickel manganese oxygen as cathode material for lithium ion batteries[J]. Electrochim. Acta, 2011,56(11):4065-4069. doi: 10.1016/j.electacta.2010.12.108
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