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Citation: Huimin YU, Zhikang WANG, Jie LI, Yinglin SONG, Minghao DU, Jianping LANG. [WS3Cu2] cluster-based supramolecular frame: Assembly, structure, and third-order nonlinear optical response[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 71-78. doi: 10.11862/CJIC.20230228 shu

[WS3Cu2] cluster-based supramolecular frame: Assembly, structure, and third-order nonlinear optical response

  • Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Figures(4)

  • Reactions of (Et4N) (Tp*WS3) (A) (Tp* =hydridotris(3, 5 -dimethylpyrazol -1 -yl)borate) and Cu (Ⅰ) salts [Cu(MeCN)4]PF6 with di(pyridin-4-yl)sulfane (L1) or bis(4-(pyridin-4-yl)phenyl)methanone (L2) gave rise to two W/Cu/ S cluster-based supramolecular compounds with the formula of [Tp*WS3Cu2(L1)]2(PF6)2·2MeCN·2CHCl3 (1·2MeCN·2CHCl3) and [Tp*WS3Cu2(L2)(MeCN)]2(PF6)2·4MeCN (2·4MeCN), respectively. Both cluster-based supramolecular compounds were structurally characterized by single -crystal X -ray diffraction, 1H NMR, MS, IR, UV -Vis, and elemental analysis. Single crystal X-ray diffraction demonstrates that both compounds are cationic cluster-based supramolecule frames with similar butterfly-like cores. 1H NMR and high-resolution electrospray ionization mass spectrometry (HRESI -MS) demonstrated their stability in DMF solution. In addition, the Z -scan measurement reveals the third-order nonlinear optical responses of 1·2MeCN·2CHCl3 and 2·4MeCN were enhanced compared to that of their precursor A.
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