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Citation: Hao-Yu XU, Rui WANG, Qiao-Ling KANG, Dong-Yun LI, Yang XU, Hong-Liang GE, Qing-Yi LU. Research progress on design of high entropy oxides and their applications in lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2241-2255. doi: 10.11862/CJIC.2023.206 shu

Research progress on design of high entropy oxides and their applications in lithium-ion batteries

  • 1.

    College of Materials and Chemistry, China Jiliang University, Hangzhou 310018, China

  • 2.

    School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Figures(11)

  • Revolutionary changes in energy storage technology have put forward higher requirements on next-generation anode materials for lithium-ion battery. Recently, a new class of materials with complex stoichiometric ratios, high entropy oxides (HEOs), has gradually emerging into sight and embracing the prosperity. The ideal elemental adjustability and attractive synergistic effect make HEOs promising to break through the integrated performance bottleneck of conventional anodes and provide new impetus for the design and development of electrochemical energy storage materials. Here, this review shares our unique viewpoints through an overview of the research status of HEOs anodes and specific descriptions regarding material design and electrochemical behavior. Specifically, the chemical composition regulation and structure design by combing the recent research of our group and important domestic and foreign literature. The control of intrinsic activity of HEOs including the introduction of metal heteroatom doping and non-metallic heteroatom doping. The influence of the increase of active-sites of HEOs to promote lithium storage performance is reviewed from the structural design including the construction of one-dimensional structures, two-dimensional structures, three-dimensional structures, hollow structures, carbon material composite. Finally, we envision the prospects and related challenges in this field, which will bring some enlightening guidance and criteria for researchers to further unlock the mysteries of HEO anodes.
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