Citation: Jie-Li LÜ, Bian YANG, Jie CUI, Shao-Dong SUN. Controlled reshaping and plasmon tuning of gold nanotetrapods using the thin layer of Ag[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2256-2264. doi: 10.11862/CJIC.2023.199 shu

Controlled reshaping and plasmon tuning of gold nanotetrapods using the thin layer of Ag

School of Materials Science and Engineering, Xi′an University of Technology, Xi′an 710048, China

Corresponding author: Jie-Li LÜ, jielilyu@xaut.edu.cn Shao-Dong SUN, sdsun@xaut.edu.cn
Received Date: 21 July 2023
Revised Date: 8 November 2023

Figures(8)

The effects of different temperatures and different solution components (introduction of I^-) on the gold nanotetrapods (GNTPs) reshaping process were investigated, revealing that the GNTPs reshaping mechanism is Ostwald ripening, that is, the dissolution of weakly bound surface atoms of Au at areas with high convex curvature and re-deposition at concave areas. This reshaping process can be stopped at any time in a few seconds by a thin layer of silver coating, and the morphology of GNTPs can be well stabilized to the greatest extent, thereby also preventing the evolution of optical properties. On this basis, the stability of GNTPs/Ag was further investigated by ultraviolet-visible-near-infrared (UV-Vis-NIR) absorption spectroscopy and synchrotron-based small-angle X-ray scattering (SAXS), as well as GNTPs/Ag results in an optical response, which is demonstrated by surface-enhanced Raman scattering (SERS) spectroscopy.
- gold nanotetrapods,
- reshaping,
- Ostwald ripening,
- surface-enhanced Raman scattering
1. [1]
  FENG R X, FAN Y, FANG Y, XIA Y M. Strategy for regulating surface protrusion of gold nanoflowers and their surface-enhanced raman scattering[J]. Acta Phys.-Chim. Sin., 2024,402304020.
2. [2]
  LAI W Z, ZHAO W, YANG R, LI X G. Preparation and optical properties of triangular silver nanoplates by a dual-reduction method[J]. Acta Phys.-Chim. Sin., 2010,26(4):1177-1183.
3. [3]
  RAO Y Y, LI Z L, HUANG J H, JIANG Y H, ZHAO X X. Preparation and SERS properties of 3D ordered gold nanoshells arrays[J]. Chinese J. Inorg. Chem., 2018,34(7):1231-1239.
4. [4]
  Cai J, Raghavan V, Bai Y J, Zhou M H, Liu X L, Liao C Y, Ma P, Shi L, Dockery P, Keogh I, Fan H M, Olivo M. Controllable synthesis of tetrapod gold nanocrystals with precisely tunable near-infrared plasmon resonance towards highly efficient surface enhanced Raman spectroscopy bioimaging[J]. J. Mater. Chem. B, 2015,3:7377-7385. doi: 10.1039/C5TB00785B
5. [5]
  Xie J P, Zhang Q B, Lee J Y, Wang D I C. The synthesis of SERS-active gold nanoflower tags for in vivo applications[J]. ACS Nano, 2008,2:2473-2480. doi: 10.1021/nn800442q
6. [6]
  Webb J A, Erwin W R, Zarick H F, Aufrecht J, Manning H W, Lang M J, Pint C L, Bardhan R. Geometry-dependent plasmonic tunability and photothermal characteristics of multibranched gold nanoantennas[J]. J. Phys. Chem. C, 2014,118:3696-3707.
7. [7]
  Kumar P S, Pastoriza-Santos I, Rodríguez-González B, García de Abajo F J, Liz-Marzán L M. High-yield synthesis and optical response of gold nanostars[J]. Nanotechnology, 2008,19015606. doi: 10.1088/0957-4484/19/01/015606
8. [8]
  Lyu J L, Rondepierre F, Jonin C, Brevet P F, Hamon C, Constantin D. Shape-controlled second-harmonic scattering from gold nanotetrapods[J]. J. Phys. Chem. C, 2022,126(23):9831-9835. doi: 10.1021/acs.jpcc.2c01867
9. [9]
  Vanrompay H, Bladt E, Albrecht W, Béché A, Zakhozheva M, Sánchez-Iglesias A, Liz-Marzán L M, Bals S. 3D characterization of heat-induced morphological changes of Au nanostars by fast in situ electron tomography[J]. Nanoscale, 2018,10(48):22792-22801. doi: 10.1039/C8NR08376B
10. [10]
  Kennedy W J, Izor S, Anderson B D, Frank G, Varshney V, Ehlert G J. Thermal reshaping dynamics of gold nanorods: Influence of size, shape, and local environment[J]. ACS Appl. Mater. Interfaces, 2018,10(50):43865-43873. doi: 10.1021/acsami.8b12965
11. [11]
  Chang Y X, Zhang N N, Xing Y C, Zhang Q F, Oh A, Gao H M, Zhu Y, Baik H, Kim B, Yang Y, Chang W S, Sun T M, Zhang J H, Lu Z Y, Lee K, Link S, Liu K. Gold Nanotetrapods with unique topological structure and ultranarrow plasmonic band as multifunctional therapeutic agents[J]. J. Phys. Chem. Lett., 2019,10:4505-4510. doi: 10.1021/acs.jpclett.9b01589
12. [12]
  González-Rubio G, Díaz-Núñez P, Rivera A, Prada A, Tardajos G, González-Izquierdo J, Bañares L, Llombart P, Macdowell L G, Palafox M A, Liz-Marzán L M, Peña-Rodríguez O, Guerrero-Martínez A. Femtosecond laser reshaping yields gold nanorods with ultranarrow surface plasmon resonances[J]. Science, 2017,358(6363):640-644. doi: 10.1126/science.aan8478
13. [13]
  Scarabelli L, Sánchez-Iglesias A, Pérez-Juste J, Liz-Marzán L M. A "tips and tricks" practical guide to the synthesis of gold nanorods[J]. J. Phys. Chem. Lett., 2015,6:4270-4279. doi: 10.1021/acs.jpclett.5b02123
14. [14]
  Hendel T, Wuithschick M, Kettemann F, Birnbaum A, Rademann K, Polte J. In situ determination of colloidal gold concentrations with UV-Vis spectroscopy: Limitations and perspectives[J]. Anal. Chem., 2014,86:11115-11124. doi: 10.1021/ac502053s
15. [15]
  Kline S R. Reduction and analysis of SANS and USANS data using IGOR Pro[J]. J. Appl. Crystallogr., 2006,39:895-900. doi: 10.1107/S0021889806035059
16. [16]
  Rodríguez-Lorenzo L, Romo-Herrera J M, Pérez-Juste J, Alvarez-Puebla R A, Liz-Marzán L M. Reshaping and LSPR tuning of Au nanostars in the presence of CTAB[J]. J. Mater. Chem., 2011,21:11544-11549. doi: 10.1039/c1jm10603a
17. [17]
  Lyu J L, Geertsen V, Hamon C, Constantin D. Determining the morphology and concentration of core-shell Au/Ag nanoparticles[J]. Nanoscale Adv., 2020,2(10):4522-4528.
18. [18]
  Hao F, Nehl C L, Hafner J H, Nordlander P. Plasmon resonances of a gold nanostar[J]. Nano Lett., 2007,7(3):729-732.
19. [19]
  Rodríguez-Lorenzo L, Álvarez-Puebla R A, Pastoriza-Santos I, Mazzucco S, Stéphan O, Kociak M, Liz-Marzán L M, De Abajo F J G. Zeptomol detection through controlled ultrasensitive surface-enhanced raman scattering[J]. J. Am. Chem. Soc., 2009,131(13):4616-4618.
20. [20]
  Lyu J L, Chaâbani W, Modin E, Chuvilin A, Bizien T, Smallenburg F, Impéror-Clerc M, Constantin D, Hamon C. Double-lattice packing of pentagonal gold bipyramids in supercrystals with triclinic symmetry[J]. Adv. Mater., 2022,342200883.
1. [1]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
2. [2]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
3. [3]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
4. [4]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
5. [5]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
6. [6]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
7. [7]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
8. [8]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
9. [9]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
10. [10]
  Gonglan Ye , Xia Yin , Feng Xu , Peng Yang , Yingpeng Wu , Huilong Fei . Innovations in “Four-in-One” Inorganic Chemistry Education. University Chemistry, 2024, 39(8): 136-141. doi: 10.3866/PKU.DXHX202401071
11. [11]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
12. [12]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
13. [13]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
14. [14]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
15. [15]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
16. [16]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
17. [17]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
18. [18]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
19. [19]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
20. [20]
  Zian Fang , Qianqian Wen , Yidi Wang , Hongxia Ouyang , Qi Wang , Qiuping Li . The Test Paper for Metal Ion: A Popular Science Experiment Based on Color Aesthetics. University Chemistry, 2024, 39(5): 108-115. doi: 10.3866/PKU.DXHX202310032

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(616)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142