Citation: Lin-Tao YU, Qi-Yang LI, Zhi SHEN, Wen-Jun Lü, Qiang ZHAO. Synthesis, fluorescence, and magnetic characterization of nicotinic acid ligand-based dysprosium, holmium, erbium, and thulium complexes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2181-2187. doi: 10.11862/CJIC.2023.187 shu

Synthesis, fluorescence, and magnetic characterization of nicotinic acid ligand-based dysprosium, holmium, erbium, and thulium complexes

College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

Corresponding author: Qiang ZHAO, zhaoqiang0522@126.com
Received Date: 31 May 2023
Revised Date: 28 September 2023

Fund Project: 河南省青年骨干教师资助项目 2020GGJS180南阳师范学院培育项目 2023PY001

Figures(6)

Four isomorphic rare earth complexes[M(Hcpna)(cpna)(H₂O)₃]_n, where M=Dy (1), Ho (2), Er (3), Tm (4), have been synthesized by a solvothermal method based on 5-(4-carboxyphenoxy)nicotinic acid ligand (H₂cpna) and rare earth metal ions Dy³⁺, Ho³⁺, Er³⁺, and Tm³⁺. Single crystal X-ray diffraction analyses reveal that complexes 1, 2, 3, and 4 are isostructural, and the structures are all 1D chain structures. The complexes were characterized by IR, elemental analysis, and powder X-ray diffraction, while the fluorescence and magnetic properties of the complexes were studied. The fluorescence test results show that the fluorescence intensity of complexes 1-4 were all lower than that of the H₂cpna ligand. The magnetism of complexes 1-4 were studied in the 2-300 K range at 1 kOe dc field. The χ_mT values of complexes 1, 2, 3, and 4 were 14.04, 14.15, 11.08, and 6.83 cm³·mol^-1·K respectively at room temperature.
- dysprosium(Ⅲ),
- holmium(Ⅲ),
- erbium(Ⅲ),
- thulium(Ⅲ),
- fluorescence,
- magnetism
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