Citation: Yu CHEN, Xin-Yu TIAN, Ning-Na CHEN, Rui-Qing LIU, Xiu-Jing LIN, Xiao-Miao FENG. Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2317-2327. doi: 10.11862/CJIC.2023.169 shu

Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), School of Materials Science & Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China

Corresponding author: Xiao-Miao FENG, iamxmfeng@njupt.edu.cn
Received Date: 28 June 2023
Revised Date: 21 September 2023

Figures(9)

A 2D nickel-manganese layered double hydroxide was generated on the surface of carbon cloth (CC) by hydrothermal method, and it was converted into a two-dimensional Ni-Mn metal-organic framework Ni-Mn (MOF) by solvothermal method, and its morphology could be maintained well. The effects of molar ratio of Ni and Mn, reaction temperature, and reaction time on the morphology, structure, and properties of the material were investigated. The optimal electrochemical performance of the Ni-Mn MOF/CC electrode was achieved when the molar ratio of Ni and Mn elements was 9∶1, the reaction temperature was 120 ℃, and the reaction time was 12 hours, respectively. The area specific capacitance of the electrode can be reached as high as 4 007.5 mF·cm^-2 at a current density of 1 mA·cm^-2, and it showed good cycling stability. The electrode can be applied to a flexible symmetric supercapacitor, which can be bent 180°. The capacitance retention rate was 83.6% after 5 000 cycles at a current density of 10 mA·cm^-2, demonstrating good cycling stability and flexibility.
- Ni-Mn metal-organic framework,
- flexible supercapacitors,
- two-dimensional nanosheet,
- carbon cloth
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沈阳化工大学材料科学与工程学院沈阳 110142

Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com