Citation: Yu CHEN, Xin-Yu TIAN, Ning-Na CHEN, Rui-Qing LIU, Xiu-Jing LIN, Xiao-Miao FENG. Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2317-2327. doi: 10.11862/CJIC.2023.169 shu

Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), School of Materials Science & Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China

Corresponding author: Xiao-Miao FENG, iamxmfeng@njupt.edu.cn
Received Date: 28 June 2023
Revised Date: 21 September 2023

Figures(9)

A 2D nickel-manganese layered double hydroxide was generated on the surface of carbon cloth (CC) by hydrothermal method, and it was converted into a two-dimensional Ni-Mn metal-organic framework Ni-Mn (MOF) by solvothermal method, and its morphology could be maintained well. The effects of molar ratio of Ni and Mn, reaction temperature, and reaction time on the morphology, structure, and properties of the material were investigated. The optimal electrochemical performance of the Ni-Mn MOF/CC electrode was achieved when the molar ratio of Ni and Mn elements was 9∶1, the reaction temperature was 120 ℃, and the reaction time was 12 hours, respectively. The area specific capacitance of the electrode can be reached as high as 4 007.5 mF·cm^-2 at a current density of 1 mA·cm^-2, and it showed good cycling stability. The electrode can be applied to a flexible symmetric supercapacitor, which can be bent 180°. The capacitance retention rate was 83.6% after 5 000 cycles at a current density of 10 mA·cm^-2, demonstrating good cycling stability and flexibility.
- Ni-Mn metal-organic framework,
- flexible supercapacitors,
- two-dimensional nanosheet,
- carbon cloth
1. [1]
  JI W J, WANG D, WANG G J, SUN X L, FU Y L. High performance supercapacitors constructed with isomorphic MOFs doped graphene oxide electrode materials[J]. Chinese J. Inorg. Chem., 2021,37(11):1931-1942. doi: 10.11862/CJIC.2021.241
2. [2]
  NIU B T, XIA W N, LAI S Q, GUO H X, CHEN Z X. Solvent-controlled morphology of Ni-BTC and Ni-BDC metal-organic frameworks for supercapacitors[J]. Chinese J. Inorg. Chem., 2022,38(8):1643-1654. doi: 10.11862/CJIC.2022.160
3. [3]
  SU L X, WANG X M, JIANG Q Y, ZHANG H M, LU Y W, LIU Q. A two-dimensional Co-based coordination polymer[KCo(pa)(OH)]_n as the electrode material of supercapacitors with higher-capacity[J]. Chinese J. Inorg. Chem., 2023,39(8):1481-1488. doi: 10.11862/CJIC.2023.099
4. [4]
  Du Y Q, Xiao P, Yuan J, Chen J W. Research progress of graphene-based materials on flexible supercapacitors[J]. Coatings, 2020,10(9)892. doi: 10.3390/coatings10090892
5. [5]
  Wang C, Hu K, Li W J, Wang H Y, Li H, Zuo Y, Zhao C C, Li Z, Yu M, Tan P C, Li Z. Wearable wire-shaped symmetric supercapacitors based on activated carbon-coated graphite fibers[J]. ACS Appl. Mater. Inter., 2018,10(40):34302-34310. doi: 10.1021/acsami.8b12279
6. [6]
  Kang C S, Ko Y I, Fujisawa K, Yokokawa T, Kim J H, Han J H, Wee J H, Kim Y A, Muramatsu H, Hayashi T. Hybridized double-walled carbon nanotubes and activated carbon as free-standing electrode for flexible supercapacitor applications[J]. Carbon Lett., 2020,30(5):527-534. doi: 10.1007/s42823-020-00122-4
7. [7]
  Ghanashyam G, Jeong H K. Plasma treated carbon nanofiber for flexible supercapacitors[J]. J. Energy Storage, 2021,40102806. doi: 10.1016/j.est.2021.102806
8. [8]
  Tang M, Wu Y T, Yang J H, Wang H X, Lin T, Xue Y H. Graphene/tungsten disulfide core-sheath fibers: High-performance electrodes for flexible all-solid-state fiber-shaped supercapacitors[J]. J. Alloy. Compd., 2021,858157747. doi: 10.1016/j.jallcom.2020.157747
9. [9]
  WANG C, LIU Q H, QI C Y, WANG Z Y, ZHAO X L, YANG X W. Synthesis and supercapacitor performances of 0D/2D MXene composite membrane[J]. Chinese J. Inorg. Chem., 2022,38(9):1707-1715. doi: 10.11862/CJIC.2022.178
10. [10]
  Asbani B, Robert K, Roussel P, Brousse T, Lethien C. Asymmetric micro-supercapacitors based on electrodeposited RuO₂ and sputtered VN films[J]. Energy Storage Mater., 2021,37:207-214. doi: 10.1016/j.ensm.2021.02.006
11. [11]
  Yu F, Pang L, Wang H X. Preparation of mulberry-like RuO₂ electrode material for supercapacitors[J]. Rare Met., 2021,40(2):440-447. doi: 10.1007/s12598-020-01561-8
12. [12]
  Zhou Y, Cheng X Y, Tynan B, Sha Z, Huang F, Islam M S, Zhang J, Rider A N, Dai L M, Chu D W, Wang D W, Han Z J, Wang C H. High-performance hierarchical MnO₂/CNT electrode for multifunctional supercapacitors[J]. Carbon, 2021,184:504-513. doi: 10.1016/j.carbon.2021.08.051
13. [13]
  Swain N, Mitra A, Saravanakumar B, Balasingam S K, Mohanty S, Nayak S K, Ramadoss A. Construction of three-dimensional MnO₂/Ni network as an efficient electrode material for high performance supercapacitors[J]. Electrochim. Acta, 2020,342136041. doi: 10.1016/j.electacta.2020.136041
14. [14]
  Zhang H, Han X R, Gan R, Guo Z H, Ni Y H, Zhang L. A facile biotemplate-assisted synthesis of mesoporous V₂O₅ microtubules for high performance asymmetric supercapacitors[J]. Appl. Surf. Sci., 2020,511145527. doi: 10.1016/j.apsusc.2020.145527
15. [15]
  Zhou Y J, Sun L L, Wu D Y, Li X, Huo P W, Wang H Q, Yan Y S. Preparation of 3D porous g-C₃N₄@V₂O₅ composite electrode via simple calcination and chemical precipitation for supercapacitors[J]. J. Alloy. Compd., 2020,817152707. doi: 10.1016/j.jallcom.2019.152707
16. [16]
  Kung C Y, Wang T L, Lin H Y, Yang C H. A high-performance covalently bonded self-doped polyaniline-graphene assembly film with superior stability for supercapacitors[J]. J. Power Sources, 2021,490229538. doi: 10.1016/j.jpowsour.2021.229538
17. [17]
  Yang J, Xiong P X, Zheng C, Qiu H Y, Wei M D. Metal-organic frameworks: A new promising class of materials for a high performance supercapacitor electrode[J]. J. Mater. Chem. A, 2014,2(39):16640-16644. doi: 10.1039/C4TA04140B
18. [18]
  Morozan A, Jaouen F. Metal organic frameworks for electrochemical applications[J]. Energy Environ. Sci., 2012,5(11):9269-9290. doi: 10.1039/c2ee22989g
19. [19]
  Sule R, Mishra A K, Nkambule T T. Recent advancement in consolidation of MOFs as absorbents for hydrogen storage[J]. Int. J. Energy Res., 2021,45(9):12481-12499. doi: 10.1002/er.6608
20. [20]
  He H B, Li R, Yang Z H, Chai L Y, Jin L F, Alhassan S I, Ren L L, Wang H Y, Huang L. Preparation of MOFs and MOFs derived materials and their catalytic application in air pollution: A review[J]. Catal. Today, 2021,375:10-29. doi: 10.1016/j.cattod.2020.02.033
21. [21]
  Zhang X, Qu N, Yang S X, Lei D, Liu A M, Zhou Q. Cobalt induced growth of hollow MOF spheres for high performance supercapacitors[J]. Mater. Chem. Front., 2021,5(1):482-491. doi: 10.1039/D0QM00597E
22. [22]
  Lv Y, Wang Y Q, Yang M, Mu Z Y, Liu S T, Ding W P, Ding M N. Nitrogen reduction through confined electro-catalysis with carbon nanotube inserted metal-organic frameworks[J]. J. Mater. Chem. A, 2021,9(3):1480-1486. doi: 10.1039/D0TA11797H
23. [23]
  Luo Z D, Fan S R, Gu C Y, Liu W C, Chen J X, Li B H, Liu J Q. Metal-organic framework (MOF)-based nanomaterials for biomedical applications[J]. Curr. Med. Chem., 2019,26(18):3341-3369. doi: 10.2174/0929867325666180214123500
24. [24]
  Raje P G, Gurav S R, Waikar M R, Rasal A S, Chang J Y, Sonkawade R G. The review of different dimensionalities based pristine metal organic frameworks for supercapacitor application[J]. J. Energy Storage, 2022,56105700. doi: 10.1016/j.est.2022.105700
25. [25]
  Ran F T, Xu X Q, Pan D, Liu Y Y, Bai Y P, Shao L. Ultrathin 2D metal-organic framework nanosheets in situ interpenetrated by functional CNTs for hybrid energy storage device[J]. Nano-Micro Lett., 2020,12(1)46. doi: 10.1007/s40820-020-0382-x
26. [26]
  Pathak I, Acharya D, Chhetri K, Chandra L P, Subedi S, Muthurasu A, Kim T, Ko T H, Dahal B, Kim H Y. Ti₃C₂T_x MXene embedded metal-organic framework-based porous electrospun carbon nanofibers as a freestanding electrode for supercapacitors[J]. J. Mater. Chem. A, 2023,11(10):5001-5014. doi: 10.1039/D2TA09726E
27. [27]
  Dennyson S A, Justin R C, Kale A M, Kim B C. Road map for in situ grown binder-free MOFs and their derivatives as freestanding electrodes for supercapacitors[J]. Small, 2023,19(20)2207713. doi: 10.1002/smll.202207713
28. [28]
  Liu Q, Guo Z Q, Wang C, Guo S, Xu Z W, Hu C G, Liu Y J, Wang Y L, He J, Wong W Y. A Cobalt-based metal-organic framework nanosheet as the electrode for high-performance asymmetric supercapacitor[J]. Adv. Sci., 2023,10(18)2207545. doi: 10.1002/advs.202207545
29. [29]
  Sahoo R, Ghosh S, Chand S, Chand Pal S, Kuila T, Das M C. Highly scalable and pH stable 2D Ni-MOF-based composites for high performance supercapacitor[J]. Composites Part B, 2022,245110174. doi: 10.1016/j.compositesb.2022.110174
30. [30]
  Ye C J, Qin Q Q, Liu J Q, Mao W P, Yan J, Wang Y, Cui J W, Zhang Q, Yang L P, Wu Y C. Coordination derived stable Ni-Co MOFs for foldable all-solid-state supercapacitors with high specific energy[J]. J. Mater. Chem. A, 2019,7(9):4998-5008. doi: 10.1039/C8TA11948A
31. [31]
  Wang J, Zhong Q, Xiong Y H, Cheng D Y, Zeng Y Q, Bu Y F. Fabrication of 3D Co-doped Ni-based MOF hierarchical micro-flowers as a high-performance electrode material for supercapacitors[J]. Appl. Surf. Sci., 2019,483:1158-1165. doi: 10.1016/j.apsusc.2019.03.340
32. [32]
  Yue L G, Chen L, Wang X Y, Lu D Z, Zhou W L, Shen D J, Yang Q, Xiao S F, Li Y Y. Ni/Co-MOF@aminated MXene hierarchical electrodes for high-stability supercapacitors[J]. Chem. Eng. J., 2023,451138687. doi: 10.1016/j.cej.2022.138687
33. [33]
  Bhartiya S, Singh R, Singh A, Balal M, Bhardwaj P, Kohli D K, Singh M K. Nitrogen-doped carbon aerogel synthesis by solvothermal gelation for supercapacitor application[J]. J. Solid State Electr., 2022,26(12):2829-2839. doi: 10.1007/s10008-022-05289-6
34. [34]
  Bardi N, Giannakopoulou T, Vavouliotis A, Trapalis C. Electrodeposited films of graphene, carbon nanotubes, and their mixtures for supercapacitor applications[J]. ACS Appl. Nano Mater., 2020,3(10):10003-10013. doi: 10.1021/acsanm.0c02002
35. [35]
  Zheng D C, Wen H, Sun X, Guan X, Zhang J, Tian W L, Feng H, Wang H J, Yao Y D. Ultrathin Mn doped Ni-MOF nanosheet array for highly capacitive and stable asymmetric supercapacitor[J]. Chem. Eur. J., 2020,26(71):17149-17155. doi: 10.1002/chem.202003220
36. [36]
  Zheng S Q, Lim S S, Foo C Y, Haw C Y, Chiu W S, Chia C H, Khiew P S. Solvothermal synthesis of nanostructured nickel-based metal- organic frameworks (Ni-MOFs) with enhanced electrochemical performance for symmetric supercapacitors[J]. J. Mater. Sci., 2023,58(29):11894-11913. doi: 10.1007/s10853-023-08747-2
37. [37]
  Cheng W R, Lu X F, Luan D Y, Lou X W D. NiMn-based bimetal- organic framework nanosheets supported on multi-channel carbon fibers for efficient oxygen electrocatalysis[J]. Angew. Chem. Int. Ed., 2020,59(41):18234-18239. doi: 10.1002/anie.202008129
38. [38]
  Cheng J Y, Chen S M, Chen D, Dong L B, Wang J J, Zhang T L, Jiao T P, Liu B, Wang H, Kai J J, Zhang D Q, Zheng G P, Zhi L J, Kang F Y, Zhang W J. Editable asymmetric all-solid-state supercapacitors based on high-strength, flexible, and programmable 2D- metal-organic framework/reduced graphene oxide self-assembled papers[J]. J. Mater. Chem. A, 2018,6(41):20254-20266. doi: 10.1039/C8TA06785F
39. [39]
  Lu P Y, Jiang X T, Guo W L, Wang L, Zhang T, Boyjoo Y, Si W P, Hou F, Liu J, Dou S X, Liang J. A Ni-Co sulfide nanosheet/carbon nanotube hybrid film for high-energy and high-power flexible supercapacitors[J]. Carbon, 2021,178:355-362. doi: 10.1016/j.carbon.2021.02.103
40. [40]
  Li Y C, Lin L Y. Novel pseudo-parallel activated carbon/carbon cloth electrodes connected in novel series for flexible symmetric supercapacitor with enlarged potential window[J]. Electrochim. Acta, 2020,363137275. doi: 10.1016/j.electacta.2020.137275
1. [1]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
2. [2]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
5. [5]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
6. [6]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
7. [7]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
8. [8]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
9. [9]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
10. [10]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
11. [11]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
14. [14]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
15. [15]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
16. [16]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
17. [17]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
18. [18]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
19. [19]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
20. [20]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(913)
HTML views(188)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Two-dimensional Ni-Mn MOF grown on carbon cloth for flexible supercapacitors

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com