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Citation: Xu WU, Wei CHEN, Bo WANG, Jiao-Jing SHAO, Quan-Sheng OUYANG. Perovskite Ba0.97Ca0.03Sn0.08Ti0.92O3-δ as polysulfide immobilizer for lithium-sulfur batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1800-1806. doi: 10.11862/CJIC.2023.145 shu

Perovskite Ba0.97Ca0.03Sn0.08Ti0.92O3-δ as polysulfide immobilizer for lithium-sulfur batteries

  • 1.

    School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China

  • 2.

    Military Representative Station of Arm Equipment Department in Guiyang, Guiyang 550025, China

  • 3.

    Advanced Batteries and Materials Engineering Research Center, Guizhou Light Industry Technical College, Guiyang 550025, China

Figures(4)

  • We prepared perovskite Ba0.97Ca0.03Sn0.08Ti0.92O3-δ (BCST) with oxygen vacancies as polysulfide (LiPS) immobilizer in Li-S batteries through strong bonding interactions. As a catalyst for promoting LiPS conversion, Ba0.97Ca0.03Sn0.08Ti0.92O3-δ/Ketjen black/sulfur (BCST/KB/S) cathode delivered a high initial specific discharge capacity of 1 164.3 mAh·g-1 and exceptional cycling stability with a low-capacity decay of only 0.052% per cycle over 800 cycles.
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