Citation: Yang LIU, Guang FAN, Feng-Qin GAO, Lei HOU, Dong-Yu ZHU, Yao-Yu WANG. A terbium complex for the detection of dimetridazole and tetracycline in an aqueous solution[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1235-1243. doi: 10.11862/CJIC.2023.116 shu

A terbium complex for the detection of dimetridazole and tetracycline in an aqueous solution

Yang LIU ^1,, ,
Guang FAN ¹ ,
Feng-Qin GAO ¹ ,
Lei HOU ^2,, ,
Dong-Yu ZHU ¹ ,
Yao-Yu WANG ²

1.
School of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shannxi 712000, China
2.
College of Chemistry & Materials Science, Northwest University, Xi′an 710069, China

Corresponding author: Yang LIU, liuyang@xync.edu.cn Lei HOU, lhou2009@nwu.edu.cn
Received Date: 27 March 2023
Revised Date: 26 April 2023

Figures(7)

One complex with formula [Tb(L)_0.5(H₂O)₂]·7H₂O (1) was prepared under the solvothermal condition by employing (1, 1′∶3′, 1″-triphenyl)-3, 3″, 4′, 5, 5″, 6′-hexacarboxylic acid (H₆L) and Tb³⁺ ion. The structure and composition of complex 1 were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. The fluorescence property of complex 1 was also studied. The results show that complex 1 belongs to the orthorhombic system, Cmca space group with cell parameters: a=2.661 61(7) nm, b=1.421 03(4) nm, c=2.109 88(6) nm. Topological calculation shows that complex 1 is a novel (6, 6)-connected 3D network with the symbol (4⁸.6⁶.8)(4⁹.6⁶). Further study shows that complex 1 has strong fluorescence emission. It was sensitive in the detection of dimetridazole (MDZ) and tetracycline (TET) in an aqueous solution with high sensitivity, low detection limit, and good recyclability. The mechanism of fluorescence quenching was disclosed through the combination of experiments and density functional theory calculations.
- complex,
- crystal structure,
- antibiotic,
- fluorescence sensing
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