Citation: Ying-Xin ZHAO, Hao HU, Xin ZHOU, Shui-Jin YANG, Yun YANG. Preparation and photocatalytic degradation performance of MOF-808/BiOCl composites[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1553-1563. doi: 10.11862/CJIC.2023.114 shu

Preparation and photocatalytic degradation performance of MOF-808/BiOCl composites

Ying-Xin ZHAO ¹ ,
Hao HU ¹ ,
Xin ZHOU ¹ ,
Shui-Jin YANG ^1,, ,
Yun YANG ^2,,

1.
College of Chemistry and Chemical Engineering, Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University, Huangshi, Hubei 435002, China
2.
College of Chemistry and Environmental Engineering, Hanjiang Normal University, Shiyan, Hubei 442000, China

Corresponding author: Shui-Jin YANG, yangshuijin@hbnu.edu.cn Yun YANG, yangyunhub@163.com
Received Date: 10 January 2023
Revised Date: 26 May 2023

Figures(13)

A novel MOF-808/BiOCl composite heterojunction material was prepared by combining highly stable MOF-808 with BiOCl by simple hydrothermal method. The photocatalytic performance of composite MOF-808/BiOCl on ciprofloxacin (CIP) was investigated using CIP as a contaminant. Compared with pure BiOCl, the performance of composite materials has been improved. Among them, composites containing 10% MOF-808 (MOF-808/BiOCl-10%) showed the best photocatalytic activity. Within 20 min of UV light irradiation, the photocatalytic degradation efficiency of CIP by MOF-808/BiOCl-10% was as high as 94.7%. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), infrared spectroscopy (FT-IR), fluorescence spectroscopy, ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), photocurrent, electrochemical impedance, and other characterization techniques were performed to analyze the phase composition, morphology and photoelectrochemical properties of materials. The formation of MOF-808 and BiOCl heterojunctions is beneficial to suppress the compounding efficiency of photogenerated carriers and improving photocatalytic activity. The UV-Vis diffuse reflectance spectroscopy results show that the light absorption range of MOF-808/BiOCl-10% material is improved. At the same time, radical trapping experiments were carried out. It indicates that ·O₂^- and h⁺ are the active species that play a major role in the degradation of CIP by MOF-808/BiOCl-10%. Based on the above experimental data, the possible photocatalytic mechanism of MOF-808/BiOCl composites was proposed.
- Zr-MOF,
- BiOCl,
- photocatalysis,
- antibiotics,
- degradation mechanism
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