Citation: Hai-Feng YU, Ting FENG, Shao-Juan CHENG, Ya-Hui GAO, Qi XIAO, Fang WANG. Nitrogen-rich doped carbon hollow nanocage structure cooperating with cobalt-nickel sulfide to improve the performance of supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1597-1609. doi: 10.11862/CJIC.2023.088 shu

Nitrogen-rich doped carbon hollow nanocage structure cooperating with cobalt-nickel sulfide to improve the performance of supercapacitors

Hai-Feng YU ¹ ,
Ting FENG ² ,
Shao-Juan CHENG ^1,, ,
Ya-Hui GAO ¹ ,
Qi XIAO ¹ ,
Fang WANG ^1,,

1.
College of Chemistry and Chemistry, Luoyang Institute of Technology, Luoyang, Henan 471023, China
2.
College of Materials Science and Engineering, Henan University of Science and Technology, Luoyang, Henan 471000, China

Corresponding author: Shao-Juan CHENG, chengshaojuan2004@126.com Fang WANG, wangfang1116@163.com
Received Date: 15 January 2023
Revised Date: 11 April 2023

Figures(9)

A novel nitrogen-rich doped carbon hollow nanocage (NC) supported binary metal sulfide nanoparticle (CoNi_xS_y) composite CoNi_xS_y/NC was successfully prepared by a simple pyrolysis-vulcanization two-step method. In this strategy, dimethylglyoxime nickel was used as the nickel source to increase the active site, and the core-shell structure of the precursor ZIF-8@Ni-ZIF-67 provided the possibility for the construction of hollow carbon nanocages. More importantly, this unique hollow structure loaded with binary metal sulfide nanoparticles made the CoNi_xS_y/NC possess more active sites, high conductivity, and structural stability when used as an electrode material, thereby providing a higher specific capacity (629.2 F·g^-1 at 1 A·g^-1) and excellent cycle stability (93.4% capacity retention after 1 000 cycles at 1 A·g^-1). When further assembled into a symmetrical supercapacitor, a specific capacitance of 207.2 F·g^-1 can be provided at 1 A·g^-1, and the retention rate was 85.36% after 1 000 cycles of stabilization.
- transition metal sulfide,
- metal-organic framework,
- hollow nanocage,
- supercapacitors
1. [1]
  Li C, Huang Y, Feng X S, Zhang Z, Gao H, Huang J X. Silica-assisted cross-linked polymer electrolyte membrane with high electrochemical stability for lithium-ion batteries[J]. J. Colloid Interface Sci., 2021,594:1-8. doi: 10.1016/j.jcis.2021.02.128
2. [2]
  Gayathri S, Arunkumar P, Saha D, Han J H. Composition engineering of ZIF-derived cobalt phosphide/cobalt monoxide heterostructures for high-performance asymmetric supercapacitors[J]. J. Colloid Interface Sci., 2021,588:557-570. doi: 10.1016/j.jcis.2020.11.129
3. [3]
  Li C, Zhang X, Wang K, Su F Y, Chen C M, Liu F Y, Wu Z S, Ma Y W. Recent advances in carbon nanostructures prepared from carbon dioxide for high-performance supercapacitors[J]. J. Energy Chem., 2021,54:352-367. doi: 10.1016/j.jechem.2020.05.058
4. [4]
  Wu Y L, Guo W, Lian X J, Tian Y M, Wang W G, Li J Y, Wang S. Self-assembled three-dimensional hierarchical CoMoO₄ nanosheets on NiCo₂O₄ for high-performance supercapacitor[J]. J. Alloy. Compd., 2019,793:418-424. doi: 10.1016/j.jallcom.2019.04.189
5. [5]
  Wen Y X, Liu Y P, Dang S, Tian S H, Li H Q, Wang Z L, He D Y, Wu Z S, Cao G Z, Peng S L. High mass loading Ni-decorated Co₉S₈ with enhanced electrochemical performance for flexible quasi-solid-state asymmetric supercapacitors[J]. J. Power Sources, 2019,423:106-114. doi: 10.1016/j.jpowsour.2019.03.045
6. [6]
  Zhang J T, Zhao X S. On the configuration of supercapacitors for maximizing electrochemical performance[J]. ChemSusChem, 2012,5:818-841. doi: 10.1002/cssc.201100571
7. [7]
  Robert F. New 'supercapacitor' promises to pack more electrical punch[J]. Science, 2006,313902. doi: 10.1126/science.313.5789.902
8. [8]
  Miller J R, Burker A. Electrochemical capacitors: Challenges and opportunities for real-world applications[J]. Electrochem. Soc. Interface, 2021,17:53-57.
9. [9]
  HE Y Z, ZHAO H Q, LIU P, SUI Y W, WEI F X, QI J Q, MENG Q K, REN Y J, ZHUANG D D. Electrodeposition of NiS on CoNi₂S₄ for flexible solid-state asymmetric supercapacitors[J]. Chinese J. Inorg. Chem., 2021,37:171-179. doi: 10.11862/CJIC.2021.011
10. [10]
  CHEN X L, ZHU Z P, WU B X, CHEN S G, ZHOU P, HE H. Design and synthesis of sandwich-like Co₉S₈/NiTe/Ni composites for high-performance supercapacitors[J]. Chinese J. Inorg. Chem., 2021,37(2):295-304.
11. [11]
  Gao Y, Zhao L J. Review on recent advances on nanostructured transition-metal-sulfide-based electrode materials for cathode materials of asymmetric supercapacitors[J]. Chem. Eng. J., 2022,430132745. doi: 10.1016/j.cej.2021.132745
12. [12]
  Kang C X, Ma L, Chen Y C, Fu L K, Hu Q, Zhou C B, Liu Q M. Metal-organic framework derived hollow rod-like NiCoMn ternary metal sulfide for high-performance asymmetric supercapacitors[J]. Chem. Eng. J., 2022,427131003. doi: 10.1016/j.cej.2021.131003
13. [13]
  Yang X, Mao J J, Niu H, Wang Q, Zhu K, Ye K, Wang G L, Cao D X, Yan J. NiS₂/MoS₂ mixed phases with abundant active edge sites induced by sulfidation and graphene introduction towards high-rate supercapacitors[J]. Chem. Eng. J., 2021,406126713. doi: 10.1016/j.cej.2020.126713
14. [14]
  Dahiya Y, Hariram M, Kumar M, Jain A, Sarkar D. Modified transition metal chalcogenides for high performance supercapacitors: Current trends and emerging opportunities[J]. Coord. Chem. Rev., 2022,451214265. doi: 10.1016/j.ccr.2021.214265
15. [15]
  Dong C F, Liang J W, He Y Y, Li C C, Chen X X, Guo L J, Tian F, Qian Y T, Xu L Q. NiS_1.03 hollow spheres and cages as superhigh rate capacity and stable anode materials for half/full sodium-ion batteries[J]. ACS Nano, 2018,12:8277-8287. doi: 10.1021/acsnano.8b03541
16. [16]
  Shi J H, Li X C, He G H, Zhang L, Li M. Electrodeposition of high-capacitance 3D CoS/graphene nanosheets on nickel foam for high-performance aqueous asymmetric supercapacitors[J]. J. Mater. Chem. A, 2015,3:20619-20626. doi: 10.1039/C5TA04464B
17. [17]
  Wang H F, Zhang K F, Song Y Q, Qiu J, Wu J, Yan L F. MnCo₂S₄ nanoparticles anchored N and S dual-doped 3D graphene as a prominent electrode for asymmetric supercapacitors[J]. Carbon, 2019,146:420-429. doi: 10.1016/j.carbon.2019.02.035
18. [18]
  JIANG M H, SHENG L Z, WANG C, JIANG L L, FAN Z J. Graphene film for supercapacitors: Preparation, foundational unit structure and surface regulation[J]. Acta Phys.-Chim. Sin., 2022,38(2)2012085.
19. [19]
  WEI F, BI H H, JIAO S, HE X J. Interconnected graphene-like nanosheets for supercapacitors[J]. Acta Phys.-Chim. Sin., 2020,36(2)1903043.
20. [20]
  Wu D, Xie X B, Ma Y P, Zhang J J, Hou C X, Sun X Q, Yang X Y, Zhang Y P, Kimura H, Du W. Morphology controlled hierarchical NiS/carbon hexahedrons derived from nitrilotriacetic acid-assembly strategy for high-performance hybrid supercapacitors[J]. Chem. Eng. J., 2022,433133673. doi: 10.1016/j.cej.2021.133673
21. [21]
  Yan Y, Li A R, Lu C X, Zhai T F, Lu S F, Li W M, Zhou W. Double-layered yolk-shell microspheres with NiCo₂S₄-Ni₉S₈-C hetero-interfaces as advanced battery-type electrode for hybrid supercapacitors[J]. Chem. Eng. J., 2020,396125316. doi: 10.1016/j.cej.2020.125316
22. [22]
  Qi J Q, Huang M Y, Ruan C Y, Zhu D D, Zhu L, Wei F X, Sui Y W, Meng Q K. Construction of CoNi₂S₄ nanocubes interlinked by few-layer Ti₃C₂T_x MXene with high performance for asymmetric supercapacitors[J]. Rare Met., 2022,41:4116-4126. doi: 10.1007/s12598-022-02167-y
23. [23]
  Xie L X, Li M J, Zhu P, Xiao X B, Jia Z F, Wei Z Q, Jiang J L. Novel combination of nickel-cobalt sulfide and oxide derived from Ni₂CoS₄@ZIF-67 for high performance supercapacitor[J]. J. Alloy. Compd., 2022,898162861. doi: 10.1016/j.jallcom.2021.162861
24. [24]
  Yang Q J, Liu Y, Yan M, Lei Y, Shi W D. MOF-derived hierarchical nanosheet arrays constructed by interconnected core-shell nanoparticles for high-performance asymmetric supercapacitors[J]. Chem. Eng. J., 2019,370:666-676. doi: 10.1016/j.cej.2019.03.239
25. [25]
  Yang Q J, Liu Y, Deng C Y, Yan M, Shi W D. MOF-derived 3D hierarchical nanoarrays consisting of NiCoZn-S nanosheets coupled with granular NiCo₂S₄ nanowires for high-performance hybrid supercapacitors[J]. J. Mater. Chem. A, 2019,7:26131-26138. doi: 10.1039/C9TA09692B
26. [26]
  Qu G M, Zhang X X, Xiang G T, Wei Y R, Yin J M, Wang Z H, Zhang X L, Xu X J. ZIF-67 derived hollow Ni-Co-Se nano-polyhedrons for flexible hybrid supercapacitors with remarkable electrochemical performances[J]. Chin. Chem. Lett., 2020,31:2007-2012. doi: 10.1016/j.cclet.2020.01.040
27. [27]
  Yang B L, Li B J, Xiang Z H. Advanced MOF-based electrode materials for supercapacitors and electrocatalytic oxygen reduction[J]. Nano Res., 2022,16:1338-1361.
28. [28]
  Wang K B, Li Q Q, Ren Z J, Li C, Chu Y, Wang Z K, Zhang M D, Wu H, Zhang Q C. 2D metal-organic frameworks (MOFs) for high-performance BatCap hybrid devices[J]. Small, 2020,162001987. doi: 10.1002/smll.202001987
29. [29]
  Feng T, Wang F, Xu Y J, Chang M J, Jinn X J, Zhou Y L, Piao J H, Lei J F. CoP/Ni₂P heteronanoparticles integrated with atomic Co/Ni dual sites for enhanced electrocatalytic performance toward hydrogen evolution[J]. Int. J. Hydrog. Energy, 2021,46:8431-8443. doi: 10.1016/j.ijhydene.2020.12.060
30. [30]
  YU H F, WANG F, FENG T, LIU S B, MA F G, YANG M X, LIANG P J. Preparation of Zn-doped Co₉S₈ nanomaterials and application for supercapacitor and hydrogen evolution reaction of electrocatalysis[J]. Chinese J. Inorg. Chem., 2020,36:1318-1326. doi: 10.11862/CJIC.2020.147
31. [31]
  Wang J M, Huang Y, Han X P, Zhang S, Wang M Y, Yan J, Chen C, Zong M. Construction of hierarchical Co₉S₈@NiO synergistic microstructure for high-performance asymmetric supercapacitor[J]. J. Colloid Interface Sci., 2021,603:440-449. doi: 10.1016/j.jcis.2021.06.118
32. [32]
  Wang X Z, Wang S J, Su D C, Xu S G, Cao S K, Xiao Y H. Constructing a p-n heterojunction in 3D urchin-like CoNi_xS_y/g-C₃N₄ composite microsphere for high performance asymmetric supercapacitors[J]. J. Alloy. Compd., 2022,902163784. doi: 10.1016/j.jallcom.2022.163784
33. [33]
  Wang C, Sui G Z, Guo D X, Li J L, Zhang L, Li S B, Xin J J, Chai D F, Guo W X. Structure-designed synthesis of hollow/porous cobalt sulfide/phosphide based materials for optimizing supercapacitor storage properties and hydrogen evolution reaction[J]. J. Colloid Interface Sci., 2021,599:577-585. doi: 10.1016/j.jcis.2021.04.118
34. [34]
  Gong J X, Wang Y R, Wang J H, Liu Y X, Hu C H, Zhou T L, Yu Q L, Yang J X, Dai Y T. Hollow nickel-cobalt sulfide nanospheres cathode hybridized with carbon spheres anode for ultrahigh energy density asymmetric supercapacitors[J]. Int. J. Hydrog. Energy, 2022,47:10056-10068. doi: 10.1016/j.ijhydene.2022.01.083
35. [35]
  Li H J, Liu M Y, Li Y, Yuan L, Zhang P, Cai Z, Chen H, Zhou J L. ZIF-8@ZIF-67-derived ZnCo₂O₄@nitrogen-doped carbon/carbon nanotubes wrapped by a carbon layer: A stable oxygen reduction catalyst with a competitive strength in acid media[J]. Mater. Today Energy, 2021,19100574. doi: 10.1016/j.mtener.2020.100574
36. [36]
  Pan Y, Sun K A, Liu S J, Cao X, Wu K L, Chen Z, Wang Y, Li Y, Liu Y Q, Wang D S, Peng Q, Chen C, Li Y D. Core-shell ZIF-8@ZIF-67 derived CoP nanoparticles-embedded N-doped carbon nanotube hollow polyhedron for efficient over-all water splitting[J]. J. Am. Chem. Soc., 2018,140:2610-2618. doi: 10.1021/jacs.7b12420
37. [37]
  Tang J, Salunkhe R R, Liu J, Torad N L, Lmura M, Furukawa S, Yamauchi Y. Thermal conversion of core-shell metal-organic frameworks: A new method for selectively functionalized nanoporous hybrid carbon[J]. J. Am. Chem. Soc., 2015,137:1572-1580. doi: 10.1021/ja511539a
38. [38]
  Chen Y Z, Wang C, Wu Z Y, Xiong Y J, Xu Q, Yu S H, Jiang H L. From bimetallic metal-organic framework to porous carbon: High surface area and multicomponent active dopants for excellent electrocatalysis[J]. Adv. Mater., 2015,27:5010-5016. doi: 10.1002/adma.201502315
39. [39]
  Liu S, Wang Z, Zhou S, Yu F, Yu M, Chiang C Y, Zhou W, Zhao J, Qiu J. Metal-organic-framework-derived hybrid carbon nanocages as a bifunctional electrocatalyst for oxygen reduction and evolution[J]. Adv. Mater., 2017,291700874. doi: 10.1002/adma.201700874
40. [40]
  Wu Z B, Pu X L, Ji X B, Zhu Y R, Jing M J, Chen Q Y, Jiao F P. High energy density asymmetric supercapacitors from mesoporous NiCo₂S₄ nanosheets[J]. Electrochim. Acta, 2015,174:238-245. doi: 10.1016/j.electacta.2015.06.011
41. [41]
  Zhang D Y, Gao S Y, Zhang J W, Wang J R, She W N, Wang K J, Xia X, Yang B, Meng X X. Facile solid-phase synthesis of layered NiS/rGO nanocomposite for high-performance hybrid supercapacitor[J]. J. Power Sources, 2021,514230590. doi: 10.1016/j.jpowsour.2021.230590
42. [42]
  Nandhini S, Muralidharan G. Graphene encapsulated NiS/Ni₃S₄ mesoporous nanostructure: A superlative high energy supercapacitor device with excellent cycling performance[J]. Electrochim. Acta, 2021,365137367. doi: 10.1016/j.electacta.2020.137367
43. [43]
  Sambathkumar C, Ranjithkumar R, Arasi S E, Manikandan A, Nallamuthu N, Kumar M K, Arivarrasan A, Devendran P. High-performance nickel sulfide modified electrode material from single-source precursor for energy storage application[J]. J. Mater. Sci.-Mater. Electron., 2021,32:20058-20070. doi: 10.1007/s10854-021-06383-7
44. [44]
  Wu Y, Tong H, Chen X D, Zhou Y, Wu C Q, Gong D X, Xiao J P, Zhang X G. Preparation of nanosheets of Ni₅P₂@Ni₉S₈/CoS_1.097 heterostructure for aqueous asymmetric supercapacitors with high electrochemical performance[J]. J. Alloy. Compd., 2022,923166378. doi: 10.1016/j.jallcom.2022.166378
45. [45]
  Chen L N, Wan J F, Fan L, Wei Y H, Zou J L. Construction of CoNi₂S₄ hollow cube structures for excellent performance asymmetric supercapacitors[J]. Appl. Surf. Sci., 2021,570151174. doi: 10.1016/j.apsusc.2021.151174
46. [46]
  Zhu J, Xiang L, Xi D, Zhou Y Z, Yang J. One-step hydrothermal synthesis of flower-like CoS hierarchitectures for application in supercapacitors[J]. Bull. Mater. Sci., 2018,4154. doi: 10.1007/s12034-018-1570-x
47. [47]
  Peng S, Xu Q, Fan L L, Wei C Z, Bao H F, Xu W L, Xu J. Flexible polypyrrole/cobalt sulfide/bacterial cellulose composite membranes for supercapacitor application[J]. Synth. Met., 2016,222:285-292. doi: 10.1016/j.synthmet.2016.11.002
48. [48]
  Ji Z Y, Li N, Xie M H, Shen X P, Dai W Y, Liu K, Xu K Q, Zhu G X. High-performance hybrid supercapacitor realized by nitrogen-doped carbon dots modified cobalt sulfide and reduced graphene oxide[J]. Electrochim. Acta, 2020,334135632. doi: 10.1016/j.electacta.2020.135632
49. [49]
  Wu X Y, Wang C C, Wang Z, Qin Y, Kong Y. Nanostructured Co₉S₈/polypyrrole hybrids grown on carbon cloth for battery-type supercapacitor electrode[J]. Synth. Met., 2022,286117034. doi: 10.1016/j.synthmet.2022.117034
50. [50]
  Mao X L, He X, Yang W Y, Liu H, Zhou Y J, Xu J H, Yang Y J. Hierarchical holey Co₉S₈@S-rGO hybrid electrodes for high-performance asymmetric supercapacitors[J]. Electrochim. Acta, 2019,328135078. doi: 10.1016/j.electacta.2019.135078
51. [51]
  Gao J S, Zhang Z M, Wang H H, Liu Z M, He Y. Construction of 3D Co/Co₉S₈ encapsulated by graphite carbon for high performance supercapacitor[J]. J. Electroanal. Chem., 2022,921116670. doi: 10.1016/j.jelechem.2022.116670
52. [52]
  Sambathkumara C, Nallamuthua N, Kumar M K, Sudhaharb S, Devendran P. Electrochemical exploration of cobalt sulfide nanoparticles synthesis using cobalt diethyldithiocarbamate as single source precursor for hybrid supercapacitor device[J]. J. Alloy. Compd., 2022,920165839. doi: 10.1016/j.jallcom.2022.165839
53. [53]
  Qiu L R, Yang W S, Zhao Q, Lu S S, Wang X H, Zhou M, Tao B F, Xie Q, Ruan Y J. Electrochemical exploration of cobalt sulfide nanoparticles synthesis using cobalt diethyldithiocarbamate as single source precursor for hybrid supercapacitor device[J]. ACS Appl. Nano Mater., 2022,5:6192-6200. doi: 10.1021/acsanm.2c00142
54. [54]
  Ansari S A, Kotb H M, Ahmad M M. Wrinkle-shaped nickel sulfide grown on three-dimensional nickel foam: A binder-free electrode designed for high-performance electrochemical supercapacitor applications[J]. Crystals, 2022,12757. doi: 10.3390/cryst12060757
55. [55]
  Zhang Y P, Shen Y H, Xie X B, Du W, Kang L T, Wang Y, Sun X Q, Li Z H, Wang B. One-step synthesis of the reduced graphene oxide@ NiO composites for supercapacitor electrodes by electrode-assisted plasma electrolysis[J]. Mater. Des., 2020,196109111. doi: 10.1016/j.matdes.2020.109111
1. [1]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
2. [2]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
3. [3]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
6. [6]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
7. [7]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
8. [8]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
11. [11]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
12. [12]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
13. [13]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
14. [14]
  Xin Chen , Meng Zhao , Yan-Yuan Jia . Stable Eu(III)-based metal-organic framework for fluorescence sensing of benzaldehyde and its analogues. Chinese Journal of Structural Chemistry, 2025, 44(3): 100445-100445. doi: 10.1016/j.cjsc.2024.100445
15. [15]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
16. [16]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
17. [17]
  Sixiao Liu , Tianyi Wang , Lei Zhang , Chengyin Wang , Huan Pang . Cerium-based metal-organic framework-modified natural mineral vermiculite for photocatalytic nitrogen fixation under visible-light irradiation. Chinese Chemical Letters, 2025, 36(3): 110058-. doi: 10.1016/j.cclet.2024.110058
18. [18]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
19. [19]
  Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu . Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100116-100116. doi: 10.1016/j.cjsc.2023.100116
20. [20]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(2216)
HTML views(79)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142