Citation: Teng-Yue MA, Jin-Ling AN, Peng ZHANG, Jin-Rong LIU, Wei-Yan HE. Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1023-1030. doi: 10.11862/CJIC.2023.077 shu

Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode

School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: Wei-Yan HE, heweiyan@imut.edu.cn
Received Date: 11 January 2023
Revised Date: 18 April 2023

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Layered nickel-based cathode materials are of great interest due to their high voltage and specific capacities for sodium ion batteries. However, the Jahn-Teller effect is detrimental for achieving considerable cycling stability at high voltage (4.5 V) and rate capability. Herein, a P2-type Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ cathode material was synthesized by adjusting the process conditions of sol-gel, and used as positive active materials to assemble sodium ion battery in air environment. The improved cycling and rate performance under high voltage can be achieved by Mnsubstitution and Bi-substitution. In a wide voltage range of 1.2 to 4.5 V, the material maintained a specific discharge capacity of 90.39 mAh·g^-1 after 50 cycles. The cathode obtained a remarkable capacity retention of 96.96% after 50 cycles at 1C (115 mA·g^-1) and 80.15% capacity retention up to 850 cycles from 2.0 to 4.0 V. The above data indicate that the cathode materials own an extremely long cycling life and better rate capability.
- sodium-ion battery,
- nickel-based oxide,
- manganese doping,
- bismuth doping,
- electrochemical performance
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Synthesis and properties of P2-Na2/3Mn1/3Bi1/3Ni1/3O2 as long-life and high voltage sodium-ion battery cathode

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通讯作者: 陈斌, bchen63@163.com

Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode