Citation: Hong-Mei CHAI, Jia-Ling YAN, Xue-Hua SUN, Gang-Qiang ZHANG, Yi-Xia REN, Lou-Jun GAO. Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe³⁺ and ciprofloxacin hydrochloride[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 775-784. doi: 10.11862/CJIC.2023.039 shu

Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe³⁺ and ciprofloxacin hydrochloride

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
2.
Xinjiang Xuanli Environmental Protection Energy Co., Ltd., Hami, Xinjiang 839000, China

Corresponding author: Yi-Xia REN, renyixia1@163.com Lou-Jun GAO, glj@yau.edu.cn
Received Date: 17 October 2022
Revised Date: 18 January 2023

Figures(9)

Using nitrogen-containing tetra-carboxylate ligands 3, 5-bis (3', 5'-dicarboxyphenyl)-1H-1, 2, 4-triazole (H₄BDT), four isostructural lanthanide metal-organic frameworks (Ln-MOFs): {[La₃(BDT)₂(HCOO)(H₂O)₅]·0.5H₂O· 3DMF}_n(1), {[Ce₃(BDT)₂(HCOO)(H₂O)₅]·3DMF}_n(2), {[Pr₃(BDT)₂(HCOO)(H₂O)₅]·3DMF}_n(3), and{[Nd₃(BDT)₂(HCOO)(H₂O)₅]·3DMF}_n(4), have been synthesized by solvothermal method and characterized by single-crystal Xray diffraction, powder X-ray diffraction, elemental analysis, thermogravimetric analysis, FT-IR, adsorption experiment of N₂, and luminescence spectra.The results show that all these Ln-MOFs are monoclinic C2/m space group crystals and have 3D mesoporous structures with double cores as inorganic building units.Among them, 2 could selectively fluorescently detect Fe³⁺ ion and ciprofloxacin hydrochloride drug molecule and the limits of detection were 4.59 and 0.77 μmol·L^-1, respectively.
- lanthanide metal-organic frameworks,
- fluorescence sensing,
- Fe³⁺,
- ciprofloxacin hydrochloride
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沈阳化工大学材料科学与工程学院沈阳 110142

Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe3+ and ciprofloxacin hydrochloride

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通讯作者: 陈斌, bchen63@163.com

Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe³⁺ and ciprofloxacin hydrochloride