Citation: Xiao-Min HOU, Si-Fu TANG. Heterometallic uranyl sulfophosphonates: Synthesis, crystal structures, and fluorescence properties[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 746-752. doi: 10.11862/CJIC.2023.034 shu

Heterometallic uranyl sulfophosphonates: Synthesis, crystal structures, and fluorescence properties

Xiao-Min HOU ¹ ,
Si-Fu TANG ^2,,

1.
College of Life Science, Qingdao Agricultural University, Qingdao, Shandong 266109, China
2.
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, Shandong 266109, China

Corresponding author: Si-Fu TANG, tangsf@qau.edu.cn
Received Date: 2 October 2022
Revised Date: 17 January 2023

Figures(5)

It is still a great challenge to construct heterometallic uranyl phosphonates. In this work, a series of isostructural heterometallic uranyl sulfophosphonates, namely [UO₂M(L)₂(H₂O)₄], where M=Mn (1), Co (2), Ni (3), Zn (4), Cd (5) and Et₂L=diethyl ((phenylsulfonyl)methyl)phosphonate, have been successfully synthesized and systematically characterized. The sulfonyl group is not involved in coordination with the metal centers, whereas the phosphonate group is fully deprotonated and connects with two uranyl cations and one transition metal ion, affording a 2D layered crystal structure. It was found that the luminescent emission was almost totally quenched in the presence of Mn(Ⅱ), Co(Ⅱ), and Ni(Ⅱ), whereas showed strong emissions in the presence of Zn(Ⅱ) and Cd(Ⅱ).
- uranyl,
- phosphonates,
- crystal structures,
- fluorescence
1. [1]
  Loiseau T, Mihalcea I, Henry N, Volkringer C. The crystal chemistry of uranium carboxylates[J]. Coord. Chem. Rev., 2014,266-267:69-109. doi: 10.1016/j.ccr.2013.08.038
2. [2]
  Andrews M B, Cahill C L. Uranyl bearing hybrid materials: Synthesis, speciation, and solid-state structures[J]. Chem. Rev., 2013,113:1121-1136. doi: 10.1021/cr300202a
3. [3]
  Wu D, Mo X F, He P, Li H R, Yi X Y, Liu C. 3D uranyl organic frameworks supported by rigid octadentate carboxylate ligand: Synthesis, structure diversity, and luminescence properties[J]. Chem.-Eur. J., 2021,27:10313-10322. doi: 10.1002/chem.202100099
4. [4]
  Li F Z, Geng J S, Hu K Q, Yu J P, Liu N, Chai Z F, Mei L, Shi W Q. Proximity effect in uranyl coordination of the cucurbit[6]uril-bipyridinium pseudorotaxane ligand for promoting host-guest synergistic chelating[J]. Inorg. Chem., 2021,60:10522-10534. doi: 10.1021/acs.inorgchem.1c01177
5. [5]
  Thuéry P, Harrowfield J. Ni(2,2':6',2″-terpyridine-4'-carboxylate)₂ zwitterions and carboxylate polyanions in mixed-ligand uranyl ion complexes with a wide range of topologies[J]. Inorg. Chem., 2022,61:9725-9745. doi: 10.1021/acs.inorgchem.2c01220
6. [6]
  Wang Y L, Liu Z Y, Li Y X, Bai Z L, Liu W, Wang Y X, Xu X M, Xiao C L, Sheng D P, Diwu J, Su J, Chai Z F, Albrecht-Schmitt T E, Wang S A. Umbellate distortions of the uranyl coordination environment result in a stable and porous polycatenated framework that can effectively remove cesium from aqueous solutions[J]. J. Am. Chem. Soc., 2015,137:6144-6147. doi: 10.1021/jacs.5b02480
7. [7]
  Xie J, Wang Y X, Liu W, Yin X M, Chen L H, Zou Y M, Diwu J, Chai Z F, Albrecht-Schmitt T E, Liu G K, Wang S A. Highly sensitive detection of ionizing radiations by a photoluminescent uranyl organic framework[J]. Angew. Chem. Int. Ed., 2017,56:7500-7504. doi: 10.1002/anie.201700919
8. [8]
  Hu K Q, Jiang X, Wang C Z, Mei L, Xie Z N, Tao W Q, Zhang X L, Chai Z F, Shi W Q. Solvent-dependent synthesis of porous anionic uranyl-organic frameworks featuring a highly symmetrical (3, 4)-connected ctn or bor topology for selective dye adsorption[J]. Chem.-Eur. J., 2017,23:529-532. doi: 10.1002/chem.201604225
9. [9]
  Xu M M, Lu H J, Wang C H, Qiu J, Zheng Z F, Guo X F, Zhang Z H, He M Y, Qian J F, Lin J. Enhancing photosensitivity via the assembly of a uranyl coordination polymer[J]. Chem. Commun., 2022,58:9389-9392. doi: 10.1039/D2CC02985E
10. [10]
  Li Y X, Yang Z X, Wang Y L, Bai Z L, Zheng T, Dai X, Liu S T, Gui D X, Liu W, Chen M, Chen L H, Diwu J, Zhu L Y, Zhou R H, Chai Z F, Albrecht-Schmitt T E, Wang S A. A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants[J]. Nat. Commun., 2017,8:1354-1364. doi: 10.1038/s41467-017-01208-w
11. [11]
  Liu D D, Wang Y L, Luo F, Liu Q Y. Rare three-dimensional uranyl-biphenyl-3, 3'-disulfonyl-4, 4'-dicarboxylate frameworks: Crystal structures, proton conductivity, and luminescence[J]. Inorg. Chem., 2020,59:2952-2960. doi: 10.1021/acs.inorgchem.9b03323
12. [12]
  Gui D X, Duan W C, Shu J, Zhai F W, Wang N, Wang X X, Xie J, Li H, Chen LH, Diwu J, Chai Z F, Wang S A. Persistent superprotonic conductivity in the order of 10^-1 S·cm^-1 achieved through thermally induced structural transformation of a uranyl coordination polymer[J]. CCS Chem., 2019,1:197-206. doi: 10.31635/ccschem.019.20190004
13. [13]
  Yang W T, Parker G, Sun Z M. Structural chemistry of uranium phosphonates[J]. Coord. Chem. Rev., 2015,303:86-109. doi: 10.1016/j.ccr.2015.05.010
14. [14]
  Liu C, Yang W T, Qu N, Li L J, Pan Q J, Sun Z M. Construction of uranyl organic hybrids by phosphonate and in situ generated carboxyphosphonate ligands[J]. Inorg. Chem., 2017,56:1669-1678. doi: 10.1021/acs.inorgchem.6b02765
15. [15]
  Adelani P O, Martinez N A, Cook N D, Burns P C. Uranyl-organic hybrids designed from hydroxyphosphonate[J]. Eur. J. Inorg. Chem., 2015:340-347.
16. [16]
  Adelani P O, Soriano J S, Galeas B E, Sigmon G E, Szymanowski J E S, Burns P C. Hybrid uranyl-phosphonate coordination nanocage[J]. Inorg. Chem., 2019,58(19):12662-12668. doi: 10.1021/acs.inorgchem.9b01448
17. [17]
  Tang S F, Hou X M. Structural tuning and sensitization of uranyl phosphonates by incorporation of countercations into the framework[J]. Inorg. Chem., 2019,58:1382-1390. doi: 10.1021/acs.inorgchem.8b02904
18. [18]
  Wen G H, Zou Q, Huang X D, Zhang K, Bao S S, Zheng L M. Heterometallic uranyl-organic frameworks incorporating manganese and copper: Structures, ammonia sorption and magnetic properties[J]. Polyhedron, 2021,205115327. doi: 10.1016/j.poly.2021.115327
19. [19]
  Wen G H, Zou Q, Xu K, Huang X D, Bao S S, Chen X T, Ouyang Z, Wang Z, Zheng L M. Layered uranyl phosphonates encapsulating Co(Ⅱ)/Mn(Ⅱ)/Zn(Ⅱ) ions: Exfoliation into nanosheets and its impact on magnetic and luminescent properties[J]. Chem.-Eur. J., 2022,28(42)e202200721.
20. [20]
  Diwu J, Wang S A, Good J J, DiStefano V H, Albrecht-Schmitt T E. Deviation between the chemistry of Ce(Ⅳ) and Pu(Ⅳ) and routes to ordered and disordered heterobimetallic 4f/5f and 5f/5f phosphonates[J]. Inorg. Chem., 2011,50(11):4842-4850. doi: 10.1021/ic200006m
21. [21]
  Thuéry P, Atoini Y, Harrowfield J. Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: Influences of transition metal ion coordination and differential U^Ⅵ chelation[J]. Dalton Trans., 2020,49:817-828. doi: 10.1039/C9DT04126E
22. [22]
  Kumar S, Maji S, Sundararajan K. Enhanced luminescence of tris (carboxylato)uranyl (Ⅵ) complexes and energy transfer to Eu(Ⅲ): A combined spectroscopic and theoretical investigation[J]. Dalton Trans., 2022,51:9803-9817. doi: 10.1039/D2DT00849A
23. [23]
  Hou J J, Zhang X M. Structures and magnetic properties of a series of metal phosphonoacetates synthesized from in situ hydrolysis of triethyl phosphonoacetate[J]. Cryst. Growth Des., 2006,6(6):1445-1452. doi: 10.1021/cg0600750
24. [24]
  Hix G B, Turner A, Kariuki B M, Tremayne M, MacLean E J. Strategies for the synthesis of porous metal phosphonate materials[J]. J. Mater. Chem., 2002,12(11):3220-3227. doi: 10.1039/B204131F
25. [25]
  Hou X M, Tang S F. Lanthanide-uranyl phosphonates constructed from diethyl ((phenylsulfonyl)methyl)phosphonate[J]. Dalton Trans., 2022,51:1041-1047. doi: 10.1039/D1DT03596G
26. [26]
  QU Z R. Uranium(Ⅵ) metal-organic framework with atropisomeric dicarboxylic ligand[J]. Chinese J. Inorg. Chem., 2007,23(12):2126-2127. doi: 10.3321/j.issn:1001-4861.2007.12.024
27. [27]
  JIANG W J, LI A D, TANG M H, NAN X L, TAN Y L, TAN Y X. Solvothermal self-assembly syntheses, crystal structures and property of two uranyl complexes with organic ligand containing N and O atoms[J]. Chinese J. Inorg. Chem., 2021,37(12):2209-2218.
28. [28]
  WANG J, LÜ X, LI Z Y, ZHANG Y Y, CHENG S Y. Synthesis, crystal structure of uranium-potassium heteronuclear coordination polymer[J]. Chinese J. Inorg. Chem., 2011,27(3):580-584.
29. [29]
  Zheng T, Gao Y, Chen L H, Liu Z Y, Diwu J, Chai Z F, Albrecht-Schmitt T E, Wang S A. A new chiral uranyl phosphonate framework consisting of achiral building units generated from ionothermal reaction: Structure and spectroscopy characterizations[J]. Dalton Trans., 2015,44:18158-18166. doi: 10.1039/C5DT02667A
30. [30]
  Su J, Zhang K, Schwarz W H E, Li J. Uranyl-glycine-water complexes in solution: Comprehensive computational modeling of coordination geometries, stabilization energies, and luminescence properties[J]. Inorg. Chem., 2011,50:2082-2093. doi: 10.1021/ic200204p
31. [31]
  Zheng T, Wu Q Y, Gao Y, Gui D X, Qiu S W, Chen L H, Sheng D P, Diwu J, Shi W Q, Chai Z F, Albrecht-Schmitt T E, Wang S A. Probing the influence of phosphonate bonding modes to uranium(Ⅵ) on structural topology and stability: A complementary experimental and computational investigation[J]. Inorg. Chem., 2015,54:3864-3874. doi: 10.1021/acs.inorgchem.5b00024
32. [32]
  Denning R G. Electronic structure and bonding in actinyl ions and their analogs[J]. J. Phys. Chem. A, 2007,111:4125-4143. doi: 10.1021/jp071061n
33. [33]
  Thuéry P, Harrowfield J. Uranyl ion complexes with 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid: Structural and spectroscopic studies of one- to three-dimensional assemblies[J]. Inorg. Chem., 2015,54:6296-6305. doi: 10.1021/acs.inorgchem.5b00596
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
3. [3]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
4. [4]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
5. [5]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
6. [6]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
7. [7]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
8. [8]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
9. [9]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
10. [10]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
11. [11]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
12. [12]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
13. [13]
  Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739
14. [14]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
15. [15]
  Jingqi Ma , Huangjie Lu , Junpu Yang , Liangwei Yang , Jian-Qiang Wang , Xianlong Du , Jian Lin . Rational design and synthesis of a uranyl-organic hybrid for X-ray scintillation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100275-100275. doi: 10.1016/j.cjsc.2024.100275
16. [16]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
20. [20]
  Gongcheng Ma , Qihang Ding , Yuding Zhang , Yue Wang , Jingjing Xiang , Mingle Li , Qi Zhao , Saipeng Huang , Ping Gong , Jong Seung Kim . Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide. Chinese Chemical Letters, 2024, 35(9): 109293-. doi: 10.1016/j.cclet.2023.109293

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1014)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142