Citation: Rui-Qin HUANG, Zheng LIU, Sheng WANG, Cai-Li YU, Run-Zhi WEI, Qun TANG. Synthesis, crystal structure, and properties of manganese/cobalt complexes based on 2,5-dibromoterephthalic acid ligands[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 159-167. doi: 10.11862/CJIC.2022.277 shu

Synthesis, crystal structure, and properties of manganese/cobalt complexes based on 2,5-dibromoterephthalic acid ligands

College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin, Guangxi 541006, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 8 August 2022
Revised Date: 3 November 2022

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The organic substance 2,5-dibromoterephthalic acid (H₂L₁) was used as the primary ligand and 2,2'-bipyridine (L₂) and 1,10-phenanthroline (L₃) as the secondary ligands, respectively, and reacted with manganese sulphate monohydrate and cobalt nitrate hexahydrate by the solvothermal method to give complexes [Mn₂(L₁)₂(L₂)₂ (H₂O)₂]_n (1) and [Co₂(L₁)₂(L₃)₂(H₂O)₂]_n (2). The two complexes were investigated analytically by such as single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis, etc. The results show that complex 1 is composed of Mn²⁺ coordination linking L₁^2- and L₂ to form an infinitely extended 2D network-like structure, with the layers forming a 3D network-like structure under intermolecular hydrogen bonding and π-π stacking. Complex 2 consists of Co²⁺ ligated to L₁^2- and L₃ to form an infinitely extended 2D network, with the layers stacked in a 3D network by intermolecular hydrogen bonding and π -π stacking. Both complexes had good fluorescence property and thermal stability, and the maximum emission wavelengths of complexes 1 and 2 were 355 and 365 nm, respectively.
- complex,
- 2,5-dibromoterephthalic acid,
- crystal structure,
- fluorescence property,
- thermal stability
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