Citation: Ya-Ping LI, Xiao-Xia ZHANG, Cheng-Qiang QIU, Sui-Jun LIU. A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 1948-1958. doi: 10.11862/CJIC.2022.213 shu

A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-

1.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China
2.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: Ya-Ping LI, yapingli2007@163.com Sui-Jun LIU, sjliu@jxust.edu.cn
Received Date: 1 February 2022
Revised Date: 23 July 2022

Figures(13)

A 3D Cd^Ⅱ -based coordination polymer with the formula of [Cd₂(DDBD)(NDC)₂]_n (JXUST-16) has been solvothermally synthesized by using 4, 7-bis(1H-1, 2, 4-triazol-1-yl)-2, 1, 3-benzothiadiazole (DDBD) as the primary ligand and 1, 4-naphthalenedicarboxylic acid (H₂NDC) as the auxiliary ligand, and structurally characterized through single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, etc. JXUST-16 belongs to the monoclinic I 2/a space group and the adjacent CdⅡ ions are bridged through the carboxylate ligand NDC^2- to form a symmetrical trinuclear CdⅡ cluster, which extends to obtain a 1D chain. The neighboring 1D chains are further linked by DDBD to form a 3D structure. JXUST-16 could keep stable in organic solvents and aqueous solutions with different pH values, and be used as a dual -function fluorescence sensor to identify MnO₄^- and H₂PO₄^- with obvious naked-eye recognition under a 365 nm UV lamp. In addition, MnO₄^- showed a turn-off effect on the fluorescence of JXUST-16 due to the competitive absorption mechanism; while H₂PO₄^- had a certain redshift and turn-on effect on the fluorescence of JXUST-16, which can be explained by the absorbance-caused enhancement mechanism.
- bistriazolyl benzothiadiazole,
- coordination polymer,
- crystal structure,
- anions fluorescence sensing
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A Dual-Function Fluorescence Sensor Based on CdⅡ Coordination Polymer for Selective Recognition of MnO4- and H2PO4-

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通讯作者: 陈斌, bchen63@163.com

A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-