Citation: Xiu-Dong CHEN, Jia-Qin JIAN, Ping YAN, Pei-Fang LIU, Xiao-Hua CAO, Jin-Hang LIU. Preparation and Lithium Storage Properties of Fe-CrSe/C Anode Material Derived from Bimetallic Organic Framework[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1752-1758. doi: 10.11862/CJIC.2022.198 shu

Preparation and Lithium Storage Properties of Fe-CrSe/C Anode Material Derived from Bimetallic Organic Framework

Xiu-Dong CHEN ^{1, 2} ,
Jia-Qin JIAN ¹ ,
Ping YAN ¹ ,
Pei-Fang LIU ^3,, ,
Xiao-Hua CAO ⁴ ,
Jin-Hang LIU ^1,,

1.
School of Chemistry and Chemical Engineering, Jiujiang University, Jiujiang, Jiangxi 332005, China
2.
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
3.
Analysis & Testing Center of Xinyang Normal University, Xinyang, Henan 464000, China
4.
Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang, Jiangxi 332005, China

Corresponding author: Pei-Fang LIU, peifangliu@xynu.edu.cn Jin-Hang LIU, 429162235@qq.com
Received Date: 26 March 2022
Revised Date: 28 July 2022

Figures(6)

To develop novel metal-organic framework-based derivatives with excellent electrochemical properties, a bimetal-organic framework (Fe-Cr-MOF) was synthesized by microwave method using terephthalic acid, and chromium trichloride, and ferric nitrate nonahydrate as raw materials. Under nitrogen protection, Fe -Cr -MOF was selenized at high temperatures to obtain nanoparticulate Fe - CrSe/C composites, which were used as anode materials for lithium -ion batteries. The results showed that the reversible specific capacity of the Fe -CrSe/C electrode reached 958.4 mAh·g^-1 in the first cycle, and the specific capacity can maintain 891.6 mAh·g^-1 after 150 cycles at the current density of 100 mA·g^-1.
- bimetallic organic framework,
- anode material,
- lithium-ion batteries,
- electrochemical performance
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