Citation: Zeng-Xue WANG, Yan LIU, Pan ZHAO, Xun-Di ZHANG, Yi-Ming YANG, Peng SUN, Xiu-Yun ZHANG, Yu FENG, Ting-Ting ZHENG, Chen CHEN, Wei LI. Near-Infrared Photothermal Conversion Agent Oxygen-Deficient Molybdenum Dioxide: Preparation and Application in Photothermal Therapy[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1739-1751. doi: 10.11862/CJIC.2022.195 shu

Near-Infrared Photothermal Conversion Agent Oxygen-Deficient Molybdenum Dioxide: Preparation and Application in Photothermal Therapy

Zeng-Xue WANG ¹ ,
Yan LIU ¹ ,
Pan ZHAO ¹ ,
Xun-Di ZHANG ¹ ,
Yi-Ming YANG ¹ ,
Peng SUN ² ,
Xiu-Yun ZHANG ¹ ,
Yu FENG ¹ ,
Ting-Ting ZHENG ^1,, ,
Chen CHEN ^3,, ,
Wei LI ^1,,

1.
College of Pharmacy, Shandong University of Traditional Chinese Medicine, Jinan 250355, China
2.
Innovative Institute of Chinese Medicine and Pharmacy, Shandong University of Traditional Chinese Medicine, Jinan 250355, China
3.
Key Laboratory of New Material Research Institute, Department of Acupuncture-Moxibustion and Tuina, Shandong University of Traditional Chinese Medicine, Jinan 250355, China

Corresponding author: Ting-Ting ZHENG, ttz10_10@163.com Chen CHEN, 21129008@zju.edu.cn Wei LI, liwei6911@163.com
Received Date: 20 March 2022
Revised Date: 26 July 2022

Figures(11)

In this paper, molybdenum dioxide (MoO₂) nanoparticles were prepared by hydrothermal synthesis method using molybdenum pentachloride (MoCl₅) as molybdenum source and polyvinylpyrrolidone (PVP) as a structural guiding agent as well as reducing agent. The results from X - ray powder diffraction (XRD), transmission electron microscopy (TEM), UV-Vis-near-infrared (UV-Vis-NIR) absorption spectroscopy, X-ray photoelectron spectroscopy (XPS), and electron spin resonance spectroscopy (EPR) illustrated that the diameter of the prepared MoO₂ nanoparticles were about 18 nm. The particle size was uniform with abundant oxygen defects, and had good light absorption ability in the near-infrared region of 650-1 100 nm. The photothermal test demonstrated that the 100 μg·mL^-1 aqueous solution of the material heated up 31.5 ℃ within 10 min, the photothermal conversion rate was up to 67.9% with excellent photothermal stability. Cytotoxicity test showed that the nanomaterial had no toxicity to cells, meanwhile possessing an obvious photothermal killing effect on hepatoma cells.
- oxygen vacancy,
- molybdenum dioxide,
- hydrothermal synthesis method,
- photothermal therapy
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