Citation: Xue-Zhi GAO, Huan SONG, Bing LI, Rui WANG, Xiao-Shuang ZHU, Xiao-Yan TIAN. Synthesis, Crystal Structure, and Catalytic Performance of a Cd(Ⅱ) Complex Based on 3-Carboxyl-5-ammino-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1808-1816. doi: 10.11862/CJIC.2022.193 shu

Synthesis, Crystal Structure, and Catalytic Performance of a Cd(Ⅱ) Complex Based on 3-Carboxyl-5-ammino-1, 2, 4-triazole

Xue-Zhi GAO ^{1, 2} ,
Huan SONG ^{1, 2} ,
Bing LI ^{1, 2,,} ,
Rui WANG ^{1, 2} ,
Xiao-Shuang ZHU ^{1, 2} ,
Xiao-Yan TIAN ^{1, 2}

1.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
2.
Department of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: Bing LI, nxdaxue@126.com
Received Date: 23 December 2021
Revised Date: 28 June 2022

Figures(6)

Triazole -derived energetic complexes have paid significant attention in the field of energetic materials. An energetic complex [Cd(Hatzc)₂(H₂O)] (LH1) (H₂atzc=3-carboxyl-5-amino-1, 2, 4-triazole) was synthesized and fully characterized by single crystal X-ray diffraction, elemental analysis, infrared spectral analysis, and thermogravimetric analysis. LH1 belongs to the monoclinic system, space group P2₁/n. The structural analyses illustrate that LH1 exhibits a 1D chain, which is linked by hydrogen-bonding interactions to give a 3D supramolecular architecture. Complex LH1 had high detonation velocity (D=10.4 km·s^-1), detonation pressure (p =55.2 GPa), energy of detonation (16.51 kJ·g^-1), and density (2.363 g·cm^-3), which were superior to most of the energetic compounds. The impact sensitivity (> 40 J) and friction sensitivity (> 360 N) reveal that LH1 is less sensitive to impact and friction. The results of the catalytic thermal decomposition of ammonium perchlorate (AP) show that LH1 decreased the higher thermal decomposition temperature of AP by 38 ℃ and increased the exothermic quantity of decomposition by 0.46 kJ·g^-1 in a short time, which showed a good catalytic effect on the thermal decomposition of AP.
- energetic complex,
- 3-carboxyl-5-amino-1, 2, 4-triazole,
- thermal decomposition,
- ammonium perchlorate
1. [1]
  Bennion J C, Matzger A J. Development and Evolution of Energetic Cocrystals[J]. Acc. Chem. Res., 2021,54(7):1699-1710. doi: 10.1021/acs.accounts.0c00830
2. [2]
  Ma X H, Cai C, Sun W J, Song W M, Ma Y L, Liu X Y, Xie G, Chen S P, Gao S L. Enhancing Energetic Performance of Multinuclear Ag(Ⅰ)-Cluster MOF -Based High-Energy-Density Materials by Thermal Dehy-dration[J]. ACS Appl. Mater. Interfaces, 2019,11(9):9233-9238. doi: 10.1021/acsami.9b00834
3. [3]
  ZHENG H, JIAO Y, FENG S S. Synthesis, Structure, Luminescence, Photocatalytic and Magnetic Properties of a Neodymium Complex Constructed from Biphenyl-3, 4', 5-tricarboxylic Acid[J]. Chinese J. Inorg. Chem., 2021,37(9):1691-1699.
4. [4]
  Li Y N, Wang B, Chang P, Hu J J, Chen T, Wang Y L, Wang B Z. Novel Catenated N₆ Energetic Compounds Based on Substituted 1, 2, 4-Triazoles: Synthesis, Structures and Properties[J]. RSC Adv., 2018,8(25):13755-13763. doi: 10.1039/C8RA02491J
5. [5]
  Yin P, Zhang J H, He C L, Parrish D A, Shreeve J M. Polynitro-Substituted Pyrazoles and Triazoles as Potential Energetic Materials and Oxidizers[J]. J. Mater. Chem. A, 2014,2(9):3200-3208. doi: 10.1039/c3ta15057g
6. [6]
  Jiao F B, Xiong Y, Li H Z, Zhang C Y. Alleviating the Energy & Safety Contradiction to Construct New Low Sensitivity and Highly Energetic Materials through Crystal Engineering[J]. CrystEngComm, 2018,20(13):1757-1768. doi: 10.1039/C7CE01993A
7. [7]
  Klapötke T M, Krumm B, Unger C C. Energetic Metal and Nitrogen-Rich Salts of the Pentaerythritol Tetranitrate Analogue Pentaerythritol Tetranitrocarbamate[J]. Inorg. Chem., 2019,58(4):2881-2887. doi: 10.1021/acs.inorgchem.8b03540
8. [8]
  Tang Y X, He C L, Imler G H, Parrish D A, Shreeve J M. Aminonitro Groups Surrounding a Fused Pyrazolotriazine Ring: A Superior Thermally Stable and Insensitive Energetic Material[J]. ACS Appl. Energy Mater., 2019,2(3):2263-2267. doi: 10.1021/acsaem.9b00049
9. [9]
  Shang Y, Yu Z H, Huang R K, Chen S L, Liu D X, Chen X X, Zhang W X, Chen X M. Metal-Free Hexagonal Perovskite High-Energetic Materials with NH₃OH⁺/NH₂NH₃⁺ as B-Site Cations[J]. Engineering, 2020,6(9):1013-1018. doi: 10.1016/j.eng.2020.05.018
10. [10]
  Wang S, Wang Q Y, Feng X, Wang B, Yang L. Explosives in the Cage: Metal-Organic Frameworks for High-Energy Materials Sensing and Desensitization[J]. Adv. Mater., 2017,29(36)1701898. doi: 10.1002/adma.201701898
11. [11]
  LI Y, ZHUANG Y F, ZHANG Y L, FENG A S, ZOU X C. Syntheses, Crystal Structures, Luminescence and Catalytic Activity of Manganese and Cadmium Coordination Polymers Based on 2, 3-Dihydroxy-terephthalic Acid[J]. Chinese J. Inorg. Chem., 2021,37(6):1135-1142. doi: 10.11862/CJIC.2021.132
12. [12]
  Li B, Wei Q, Yang Q, Chen S P, Gao S L. Synthesis, Structure, and Thermophysical Properties of an Energetic Complex Co(3-(2-pyridyl)-5-(3'-pyridyl)-1H-1, 2, 4-triazole)₃·H₂O[J]. J. Chem. Eng. Data, 2011,56(7):3043-3046. doi: 10.1021/je2000364
13. [13]
  Gao H, Li B, Jin X D, Bi S X, Tian X Y, Liu W Y. Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3, 5-Bis(3-pyridyl)-1H-1, 2, 4-triazole[J]. Chin. J. Struct. Chem., 2016,35(12):1902-1911.
14. [14]
  Li B, Song H, Wu H P, Wang J K, Tian X Y, Ma X X. A New Oxygen-Rich and Poly-Nitrogen Energetic Complex: Synthesis, Properties of High Energy Materials and Catalytic Decomposition of Ammonium Perchlorate[J]. J. Coord. Chem., 2021,74(7):1159-1167. doi: 10.1080/00958972.2021.1892663
15. [15]
  Li B, Han J, Yang Q F, Tian X Y, Chen X Y. A New Energetic Complex [Co(2, 4, 3-tpt)₂(H₂O)₂]·2NO₃: Synthesis, Structure, and Catalytic Thermal Decomposition for Ammonium Perchlorate[J]. Z. Anorg. Allg. Chem., 2015,641(14):2371-2375. doi: 10.1002/zaac.201500249
16. [16]
  Liu L L, Li J, Zhang L Y, Tian S Y. Effects of Magnesium-Based Hydrogen Storage Materials on the Thermal Decomposition, Burning Rate, and Explosive Heat of Ammonium Perchlorate-Based Composite Solid Propellant[J]. J. Hazard. Mater., 2018,342:477-481. doi: 10.1016/j.jhazmat.2017.08.055
17. [17]
  Wei T T, Zhang Y, Xu K Z, Ren Z Y, Gao H X, Zhao F Q. Catalytic Action of Nano Bi₂WO₆ on Thermal Decompositions of AP, RDX, HMX and Combustion of NG/NC Propellant[J]. RSC Adv., 2015,5(86):70323-70328. doi: 10.1039/C5RA13257F
18. [18]
  Yaman H, Çelik V, Değirmenci E. Experimental Investigation of the Factors Affecting the Burning Rate of Solid Rocket Propellants[J]. Fuel, 2014,115:794-803. doi: 10.1016/j.fuel.2013.05.033
19. [19]
  Li B, Shen D, Chen X Y, Li T, Ren J L, Hu Q L, Liu W Y. A New 1-D Energetic Complex [Cu(2, 3'-bpt)₂·H₂O]_n: Synthesis, Structure, and Catalytic Thermal Decomposition for Ammonium Perchlorate[J]. J. Coord. Chem., 2014,67(11):2028-2038. doi: 10.1080/00958972.2014.934230
20. [20]
  Sheldrick G M. SHELXTL/PC, Version 6.12 for Windows XP. Bruker AXS Inc., Madison, Wisconsin, USA, 2001.
21. [21]
  Sheldrick G M. SHELXL-2014, Program for the Refinement of Crystal Structures. University of Göttingen, Germany, 2014.
22. [22]
  Yang Q, Ge J, Gong Q B, Song X X, Zhao J W, Wei Q, Xie G, Chen S P, Gao S L. Two Energetic Complexes Incorporating 3, 5-Dinitro-benzoic Acid and Azole Ligands: Microwave-Assisted Synthesis, Favorable Detonation Properties, Insensitivity and Effects on the Thermal Decomposition of RDX[J]. New J. Chem., 2016,40(9):7779-7786. doi: 10.1039/C6NJ00197A
23. [23]
  Mohamadnia Z, Zohuriaan-Mehr M J, Kabiri K, Razavi-Nouri M. Tragacanth Gum-Graft-Polyacrylonitrile: Synthesis, Characterization and Hydrolysis[J]. J. Polym. Res., 2008,15(3):173-180. doi: 10.1007/s10965-007-9156-0
24. [24]
  ZHANG L, GUO L F, HUANG S, KANG J, SUN W M. Synthesis, Characterization and Biological Activity of Pr(Ⅲ) Complex Constructed by Pyridine-2, 6-dicarboxylate[J]. Chinese J. Inorg. Chem., 2021,37(7):1269-1276. doi: 10.11862/CJIC.2021.139
25. [25]
  Kahali P, Montazer M, Dolatabadi M K. Attachment of Tragacanth Gum on Polyester Fabric through the Synthesis of Iron Oxide Gaining Novel Biological, Physical, and Thermal Features[J]. Int. J. Biol. Macromol., 2022,207:193-204. doi: 10.1016/j.ijbiomac.2022.02.194
26. [26]
  Marrazzini G, Giovannini T, Scavino M, Egidi F, Cappelli C, Koch H. Multilevel Density Functional Theory[J]. J. Chem. Theory Comput., 2021,17(2):791-803. doi: 10.1021/acs.jctc.0c00940
27. [27]
  Bushuyev O S, Brown P, Maiti A, Gee R H, Peterson G R, Weeks B L, Hope-Weeks L J. Ionic Polymers as a New Structural Motif for High-Energy-Density Materials[J]. J. Am. Chem. Soc., 2012,134(3):1422-1425. doi: 10.1021/ja209640k
28. [28]
  Li S H, Wang Y, Qi C, Zhao X X, Zhang J C, Zhang S W, Pang S P. 3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials[J]. Angew. Chem. Int. Ed., 2013,52(52):14031-14035. doi: 10.1002/anie.201307118
29. [29]
  Song H, Li B, Gao X Z, Shan F L, Ma X X, Tian X Y, Chen X Y. Thermodynamics and Catalytic Properties of Two Novel Energetic Complexes Based on 3-Amino-1, 2, 4-triazole-5-carboxylic Acid[J]. ACS Omega, 2022,7:3024-3029. doi: 10.1021/acsomega.1c06052
30. [30]
  Xu J G, Wang S H, Zhang M J, Sun C, Xiao Y, Li R, Zheng F K, Guo G C, Huang J S. Nitrogen-Rich Tetranuclear Metal Complex as a New Structural Motif for Energetic Materials[J]. ACS Omega, 2017,2(1):346-352. doi: 10.1021/acsomega.6b00431
31. [31]
  Zhang Q, Shreeve J M. Metal-Organic Frameworks as High Explosives: A New Concept for Energetic Materials[J]. Angew. Chem. Int. Ed., 2014,53(10):2540-2542. doi: 10.1002/anie.201310014
32. [32]
  Liu X L, Li J Z, Bi F Q, Zhang W Q, Zhang G F, Gao Z W. Ionic Ferrocene-Based Burning-Rate Catalysts with Polycyano Anions: Synthesis, Structural Characterization, Migration, and Catalytic Effects during Combustion[J]. Eur. J. Inorg. Chem., 2015(9):1496-1504.
33. [33]
  Kissinger H E. Reaction Kinetics in Differential Thermal Analysis[J]. Anal. Chem., 1957,29(11):1702-1706. doi: 10.1021/ac60131a045
34. [34]
  Soria-Verdugo A, Morgano M T, Mätzing H, Goos E, Leibold H, Merz D, Riedel U, Stapf D. Comparison of Wood Pyrolysis Kinetic Data Derived from Thermogravimetric Experiments by Model-Fitting and Model-Free Methods[J]. Energy Conv. Manag., 2020,212112818. doi: 10.1016/j.enconman.2020.112818
35. [35]
  Bu X R, Jackson C R, van Derveer D, You X Z, Meng Q J, Wang R X. New Copper(Ⅱ) Complexes Incorporating Unsymmetrical Tetradentate Ligands with cis-N₂O₂ Chromophores: Synthesis, Molecular Structure, Substituent Effect and Thermal Stability[J]. Polyhedron, 1997,16(17):2991-3001. doi: 10.1016/S0277-5387(97)00048-X
36. [36]
  Wang J, Wang Y, Zhang Z H, Zhang X D, Liu X Z, Gao G R, Liu X Y, Zhang Y. Syntheses and Structural Analyses of Nine-Coordinate Protonated (Py)₂[Gd^Ⅲ(HNta)(Nta)(H₂O)]·5H₂O and Eight-Coordinate (NH₄)₃[Ho^Ⅲ(Nta)₂] Complexes[J]. Russ. J. Coord. Chem., 2006,32(1):63-70. doi: 10.1134/S1070328406010118
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