Citation: Alamgir, Yan-Long ZHAO, Talha Khalid, Ya-Bo XIE, Lu WANG, Lin-Hua XIE, Xin ZHANG, Jian-Rong LI. An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1817-1824. doi: 10.11862/CJIC.2022.174 shu

An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water

Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing 100124, China

Corresponding author: Xin ZHANG, zhang.xin@bjut.edu.cn
Received Date: 9 January 2022
Revised Date: 19 May 2022

Figures(6)

As an emerging type of porous material, metal-organic frameworks (MOFs) have been developed as sensors for monitoring environmental pollutants in water. It is of high significance to develop fluorescent MOFs with simple precursors for selective detection of toxic Fe³⁺ ions. In this work, we present a water-stable two-fold interpenetrated indium-based metal-organic framework (NH₂Me₂)[In(fdc)₂]·2H₂O named BUT-205 (BUT stands for Beijing University of Technology, H₂fdc=furan -2, 5-dicarboxylic acid) constructed from a biomass-derived ligand. BUT-205 has been structurally characterized by single-crystal X-ray diffraction. BUT-205 was an efficient sensor for Fe³⁺ ions in water with high sensitivity and selectivity. The limit of detection (LOD) was calculated to be 1.3 μmol·L^-1 being lower than the US-EPA (U. S. Environmental Protection Agency) standard (15.7 μmol·L^-1) in drinking water. Furthermore, BUT-205 could be recycled and used for at least four cycles.
- metal-organic frameworks,
- anionic framework,
- fluorescent sensing,
- metal cations,
- water safety
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通讯作者: 陈斌, bchen63@163.com

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An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe3+ in Water

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通讯作者: 陈斌, bchen63@163.com

An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water