Citation: Ren-Zheng JIANG, Jun-Hua CHANG, Ying GAO, Jin-Feng ZHANG, Meng-Jiang LI, Ying-Peng XIE. Surface Sulfuration and Phosphorization Boosting Hydrogen Evolution Performance of Nickel Molybdate[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1729-1738. doi: 10.11862/CJIC.2022.172 shu

Surface Sulfuration and Phosphorization Boosting Hydrogen Evolution Performance of Nickel Molybdate

1.
College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
2.
College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Ying-Peng XIE, ypxie@syuct.edu.cn
Received Date: 21 March 2022
Revised Date: 26 June 2022

Figures(8)

Herein, the nickel molybdate nanorods arrays supported on Ni foam (NMO/NF) precursor were firstly fabricated by hydrothermal method. Then the surface sulfidation and phosphating for NMO/NF were conducted in turn, to obtain a three-dimensional self-supported electrode (PS-NMO/NF). The sulfidation induces the formation of amorphous sulfides with significantly enhanced electrochemical active area on the surface of nickel molybdate (S- NMO/ NF), as well as a coral-like sphere structure. Phosphates were induced on the surface of sulfides by subsequent phosphating. The formed sulfides/phosphates heterogeneous interfaces can promote the electron transfer and improve the hydrogen evolution reaction (HER) performance of NMO. In 1 mol·L^-1 KOH electrolyte, when the current density was 10 and 100 mA·cm^-2, the corresponding HER overpotential of PS-NMO/NF was 93 and 180 mV, respectively. The Tafel slope of PS-NMO/NF was 67 mV·dec^-1, and it had good stability within 20 h of running.
- nickel molybdate,
- sulfidation,
- phosphating,
- hydrogen evolution reaction
1. [1]
  Braff W A, Mueller J M, Trancik J E. Value of Storage Technologies for Wind and Solar Energy[J]. Nat. Clim. Chang., 2016,6(10):964-969. doi: 10.1038/nclimate3045
2. [2]
  Dincer I. Green Methods for Hydrogen Production[J]. Int. J. Hydrog. Energy, 2012,37(2):1954-1971. doi: 10.1016/j.ijhydene.2011.03.173
3. [3]
  Nikolaidis P, Poullikkas A. A Comparative Overview of Hydrogen Production Processes[J]. Renew. Sust. Energ. Rev., 2017,67:597-611. doi: 10.1016/j.rser.2016.09.044
4. [4]
  Zhang D D, Soo J Z, Tan H H, Jagadish C, Catchpole K, Karuturi S K. Earth-Abundant Amorphous Electrocatalysts for Electrochemical Hydrogen Production: A Review[J]. Adv. Energy Sustainability Res., 2021,2(3)2000071. doi: 10.1002/aesr.202000071
5. [5]
  Hu C L, Zhang L, Gong J L. Recent Progress Made in the Mechanism Comprehension and Design of Electrocatalysts for Alkaline Water Splitting[J]. Energy Environ. Sci., 2019,12:2620-2645. doi: 10.1039/C9EE01202H
6. [6]
  Xiao P, Chen W, Wang X. A Review of Phosphide - Based Materials for Electrocatalytic Hydrogen Evolution[J]. Adv. Energy Mater., 2015,5(24)1500985. doi: 10.1002/aenm.201500985
7. [7]
  WANG Z M, LU Y N, TANG M, ZHANG S, WANG Y C, ZHANG Z B, LIU Y H, LIU Y H. Preparation by Molten Salt Method of Cu/MoS₂ for Enhancement of Hydrogen Evolution Reaction Performance under Alkaline Condition[J]. Chinese J. Inorg. Chem., 2021,37(9):1589-1596.
8. [8]
  Luo X, Ji P X, Wang P Y, Cheng R L, Chen D, Lin C, Zhang J A, He J W, Shi Z H, Li N, Xiao S Q, Mu S C. Interface Engineering of Hierarchical Branched Mo-Doped Ni₃ S ₂/Ni_xP_y Hollow Heterostructure Nanorods for Efficient Overall Water Splitting[J]. Adv. Energy Mater., 2020,10(17)1903891. doi: 10.1002/aenm.201903891
9. [9]
  Yang Y Q, Zhang K, Lin H, Li X, Chan H C, Yang L C, Gao Q S. MoS₂-Ni₃S₂ Heteronanorods as Efficient and Stable Bifunctional Electrocata-lysts for Overall Water Splitting[J]. ACS Catal., 2017,7(4):2357-2366. doi: 10.1021/acscatal.6b03192
10. [10]
  Chen Z J, Zhong H F, Hu W J, Yin H, Cao G X, Wen H, Wang J J, Wang P. Highly Dispersed Ni_2-xMo_xP Nanoparticles on Oxygen - Defect - Rich NiMoO_4-y Nanosheets as an Active Electrocatalyst for Alkaline Hydrogen Evolution Reaction[J]. J. Power Sources, 2019,444227311. doi: 10.1016/j.jpowsour.2019.227311
11. [11]
  Du C C, Shang M X, Mao J X, Song W B. Hierarchical MoP/Ni₂P Heterostructures on Nickel Foam for Efficient Water Splitting[J]. J. Mater. Chem. A, 2017,515940. doi: 10.1039/C7TA03669H
12. [12]
  Li Y J, Zhang H C, Jiang M, Kuang Y, Wang H, Sun X M. Amorphous Co-Mo-S Ultrathin Films with Low-Temperature Sulfurization as High - Performance Electrocatalysts for the Hydrogen Evolution Reaction[J]. J. Mater. Chem. A, 2016,4:13731-13735. doi: 10.1039/C6TA05742J
13. [13]
  Jiang R Z, Zhao D Q, Fan H N, Xie Y P, Li M J, Lin H, Wu Z S. Phosphorus Doping and Phosphates Coating for Nickel Molybdate/ Nickel Molybdate Hydrate Enabling Efficient Overall Water Splitting[J]. J. Colloid Interface Sci., 2022,606:384-392. doi: 10.1016/j.jcis.2021.08.035
14. [14]
  Ghosh D, Giria S, Das C K. Synthesis, Characterization and Electrochemical Performance of Graphene Decorated with 1D NiMoO₄· nH₂O Nanorods[J]. Nanoscale, 2013,5(21):10428-10437. doi: 10.1039/c3nr02444j
15. [15]
  Liu X, Meng J S, Ni K, Guo R T, Xia F J, Xie J J, Li X, Wen B, Wu P J, Li M, Wu J S, Wu X J, Mai L Q, Zhao D Y. Complete Reconstruction of Hydrate Pre-catalysts for Ultrastable Water Electrolysis in Industrial-Concentration Alkali Media[J]. Cell Rep. Phys. Sci., 2020,1100241. doi: 10.1016/j.xcrp.2020.100241
16. [16]
  Li D J, Kang J, Lee H J, Choi D S, Koo S H, Han B, Kim S O. High Activity Hydrogen Evolution Catalysis by Uniquely Designed Amorphous/Metal Interface of Core-Shell Phosphosulfide/N-Doped CNTs[J]. Adv. Energy Mater., 2018,8(13)1702806. doi: 10.1002/aenm.201702806
17. [17]
  Zhang W Z Z, Ding L C, Sun W P, Sheng T, Wu Z C, Gao F. Ultrasmall Pt Nanoparticles - Loaded Crystalline MoO₂/Amorphous Ni(OH)₂ Hybrid Nanofilms with Enhanced Water Dissociation and Sufficient Hydrogen Spillover for Hydrogen Generation[J]. ACS Sustain. Chem. Eng., 2021,9:8257-8269. doi: 10.1021/acssuschemeng.1c02421
18. [18]
  You B, Tang M T, Tsai C, Abild - Pedersen F, Zheng X L, Li H. Enhancing Electrocatalytic Water Splitting by Strain Engineering[J]. Adv. Mater., 2019,31(17)1807001. doi: 10.1002/adma.201807001
19. [19]
  Kwon J, Han H, Jo S, Choi S, Chung K Y, Ali G, Park K, Paik U, Song T. Amorphous Nickel - Iron Borophosphate for a Robust and Efficient Oxygen Evolution Reaction[J]. Adv. Energy Mater., 2021,11(25)2100624. doi: 10.1002/aenm.202100624
20. [20]
  Lu X F, Zhang S L, Sim W L, Gao S Y, Lou X W. Phosphorized CoNi₂S₄ Yolk - Shell Spheres for Highly Efficient Hydrogen Production via Water and Urea Electrolysis[J]. Angew. Chem. Int. Ed., 2021,60(42):22885-22891. doi: 10.1002/anie.202108563
21. [21]
  Xu Q C, Liu Y, Jiang H, Hu Y, Liu H L, Li C Z. Unsaturated Sulfur Edge Engineering of Strongly Coupled MoS₂ Nanosheet-Carbon Macroporous Hybrid Catalyst for Enhanced Hydrogen Generation[J]. Adv. Energy Mater., 2019,9(2)1802553. doi: 10.1002/aenm.201802553
22. [22]
  Sarma P V, Vineesh T V, Kumar R, Sreepal V, Prasannachandran R, Singh A K, Shaijumon M M. Nanostructured Tungsten Oxysulfide as an Efficient Electrocatalyst for Hydrogen Evolution Reaction[J]. ACS Catal., 2020,10(12):6753-6762. doi: 10.1021/acscatal.9b04177
23. [23]
  Duan Y, Yu Z Y, Hu S J, Zheng X S, Zhang C T, Ding H H, Hu B C, Fu Q Q, Yu Z L, Zheng X, Zhu J F, Gao M R, Yu S H. Scale - Up Synthesis of Amorphous NiFeMo Oxides and Their Rapid Surface Reconstruction for Superior Oxygen Evolution Catalysis[J]. Angew. Chem. Int. Ed., 2019,58(44):15772-15777. doi: 10.1002/anie.201909939
24. [24]
  Xiao Z, Wang Y, Huang Y C, Wei Z, Dong C L, Ma J, Shen S, Li Y, Wang S. Filling the Oxygen Vacancies in Co₃O₄ with Phosphorus: An Ultra-Efficient Electrocatalyst for Overall Water Splitting[J]. Energy Environ. Sci., 2017,10:2563-2569. doi: 10.1039/C7EE01917C
25. [25]
  Ai L H, Niu Z G, Jiang J. Mechanistic Insight into Oxygen Evolution Electrocatalysis of Surface Phosphate Modified Cobalt Phosphide Nanorod Bundles and Their Superior Performance for Overall Water Splitting[J]. Electrochim. Acta, 2017,242:355-363. doi: 10.1016/j.electacta.2017.05.032
26. [26]
  Peng L S, Shen J J, Zheng X Q, Xiang R, Deng M M, Mao Z X, Feng Z P, Zhang L, Li L, Wei Z D. Rationally Design Of Monometallic NiO-Ni₃ S₂/NF Heteronanosheets as Bifunctional Electrocatalysts for Overall Water Splitting[J]. J. Catal., 2019,369:345-351. doi: 10.1016/j.jcat.2018.11.023
27. [27]
  Gu H H, Fan W, Liu T X. Phosphorus Doped NiCo₂S₄ Nanocrystals Grown on Electrospun Carbon Nanofibers as Ultra-efficient Electrocatalysts for Hydrogen Evolution Reaction[J]. Nanoscale Horiz., 2017,2:277-283. doi: 10.1039/C7NH00066A
28. [28]
  ZHOU Q, LI X B, LI Z Y. Composite Electrodes of Nano - Porous Ni-Mo Modified by RuO₂ and Electrocatalytic Property for Hydrogen Evolution[J]. Chinese J. Inorg. Chem., 2020,36(9):1649-1658.
29. [29]
  Jin Y S, Yue X, Shu C, Huang S L, Shen P K. Three - Dimensional Porous MoNi₄ Networks Constructed by Nanosheets as Bifunctional Electrocatalysts for Overall Water Splitting[J]. J. Mater. Chem. A, 2017,5:2508-2513. doi: 10.1039/C6TA10802D
30. [30]
  Patil R B, House S D, Mantri A, Yang J C, Mc Kone J R. Direct Observation of Ni - Mo Bimetallic Catalyst Formation via Thermal Reduction of Nickel Molybdate Nanorods[J]. ACS Catal., 2020,10(18):10390-10398. doi: 10.1021/acscatal.0c02264
31. [31]
  Gong M, Wang D Y, Chen C C, Hwang B J, Dai H. A Mini Review on Nickel - Based Electrocatalysts for Alkaline Hydrogen Evolution Reaction[J]. Nano Res., 2016,9:28-46. doi: 10.1007/s12274-015-0965-x
32. [32]
  Kim H S, Cook J B, Lin H, Ko J S, Tolbert S H, Ozolins V, Dunn B. Oxygen Vacancies Enhance Pseudocapacitive Charge Storage Prop-erties of MoO_3-x[J]. Nat. Mater., 2017,16:454-460. doi: 10.1038/nmat4810
33. [33]
  Cobo S, Heidkamp J, Jacques P A, Fize J, Fourmond V, Guetaz L, Jousselme B, Ivanova V, Dau H, Palacin S, Fontecave M, Artero V. A Janus Cobalt - Based Catalytic Material for Electrosplitting of Water[J]. Nat. Mater., 2012,11(9):802-807. doi: 10.1038/nmat3385
34. [34]
  Du F, Zhang Y T, He H C, Li T, Wen G H, Zhou Y, Zou Z G. Elec-trodeposited Amorphous Cobalt Phosphosulfide on Ni Foams for Highly Efficient Overall Water Splitting[J]. J. Power Sources, 2019,431:182-188. doi: 10.1016/j.jpowsour.2019.05.063
35. [35]
  Ge Y C, Dong P, Craig S R, Ajayan P M, Ye M X, Shen J F. Trans-forming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni₂P/Fe ₂P for Efficient Hydrogen Evolution Reaction[J]. Adv. Energy Mater., 2018,8(21)1800484. doi: 10.1002/aenm.201800484
36. [36]
  Liu X L, Guo Y H, Wang P, Wu Q, Zhang Q Q, Rozhkova E A, Wang Z Y, Liu Y Y, Zheng Z K, Dai Y, Huang B B. Synthesis of Syn-ergistic Nitrogen-Doped NiMoO ₄/Ni₃N Heterostructure for Implemen-tation of an Efficient Alkaline Electrocatalytic Hydrogen Evolution Reaction[J]. ACS Appl. Energy Mater., 2020,3(3):2440-2449. doi: 10.1021/acsaem.9b02130
37. [37]
  Jiang Y, Huang J B, Mao B G, An T Y, Wang J, Cao M H. Inside Solid-Liquid Interfaces: Understanding the Influence of the Electri-cal Double Layer on Alkaline Hydrogen Evolution Reaction[J]. Appl. Catal. B-Environ., 2021,293120220. doi: 10.1016/j.apcatb.2021.120220
38. [38]
  Wang H Y, Hung S F, Chen H Y, Chan T S, Chen H M, Liu B. In Operando Identification of Geometrical - Site - Dependent Water Oxi-dation Activity of Spinel Co₃O₄[J]. J. Am. Chem. Soc., 2016,138(1):36-39. doi: 10.1021/jacs.5b10525
39. [39]
  ZHOU Q, LI X B, JIAO S Z. Mesoporous Regulated Co₉S ₈/Ni₃S₂ Composite Electrode Materials and Electrocatalytic Hydrogen Evolu-tion Performance[J]. Chinese J. Inorg. Chem., 2021,37(11):1970-1980.
1. [1]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
2. [2]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
3. [3]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
4. [4]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
7. [7]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
8. [8]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
9. [9]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
10. [10]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
11. [11]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
12. [12]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
13. [13]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
14. [14]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
15. [15]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
16. [16]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
17. [17]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
18. [18]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051
19. [19]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
20. [20]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

Get Citation

PDF

XML

Metrics

PDF Downloads(20)
Abstract views(1801)
HTML views(400)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142