Citation: Wen-Sen SONG, Saulat Hammad, Tao YAN, Jin-Yin LÜ, Jian-Hua YANG, Jin-Ming LU, Yan ZHANG. Preparation of MFI Zeolite Nanosheets and b-Oriented MFI Zeolite Film[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1781-1789. doi: 10.11862/CJIC.2022.159 shu

Preparation of MFI Zeolite Nanosheets and b-Oriented MFI Zeolite Film

State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membrane, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Jian-Hua YANG, yjianhua@dlut.edu.cn
Received Date: 28 March 2022
Revised Date: 4 June 2022

Figures(6)

Herein, the bottom - up method was utilized for the synthesis of MFI nanosheet with a high aspect ratio and crystallinity by using homemade dC5 (bis-1, 5(tripropyl ammonium). b-Oriented MFI nanosheets seed layer was coated on glass supports by slip coating method with an average thickness of about 100 nm. The SDA (structure - directing agent) free secondary growth of the MFI nanosheet layer was conducted to effectively seal the interlayer and nanoscale gap among the nanosheet layer. The SDA-free secondary growth effectively preserves the b- orientation of the MFI film while maintaining the minimal thickness. A continuous and dense b-oriented MFI zeolite film with a thickness of about 200 nm was prepared under n_SiO₂∶n_Na₂O∶n_C₂H₅OH∶n_H₂O=1∶0.03∶1.3∶0.89 with a crystallization time and temperature of 48 h and 180 ℃, respectively. A significant decrease was observed in the thickness (approxi-mately 90%) of the synthesized film by the SDA-free secondary growth method as compared to MFI zeolite film pre-pared by the conventional secondary growth method containing tetrapropylammonium hydroxide (TPAOH) as SDA that fails to preserve the desired b-orientation of the film.
- two-dimensional material,
- MFI zeolite nanosheet,
- b-oriented MFI zeolite film
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of MFI Zeolite Nanosheets and b-Oriented MFI Zeolite Film

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com