Citation: Gui-Xiang ZHAN, Hong-Yu YANG, Jun-Ran ZHANG, Lin WANG. Structural Dimensions and Optoelectronic Properties of Chiral Perovskites[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1441-1450. doi: 10.11862/CJIC.2022.133 shu

Structural Dimensions and Optoelectronic Properties of Chiral Perovskites

Key Laboratory of Flexible Electronics and Institute of Advanced Materials, School of Physical and Mathematical Sciences, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Jun-Ran ZHANG, jrzhang@njtech.edu.cn Lin WANG, iamlwang@njtech.edu.cn
Received Date: 17 March 2022
Revised Date: 25 April 2022

Figures(7)

The past decade has witnessed an explosion of research into organic‐inorganic hybrid perovskites due to their outstanding optoelectronic properties, including high flexibility, high absorption/emission efficiency, large defect tolerance, and long‐distance carrier diffusion. Recently, chiral hybrid perovskites, combing the unique properties of perovskites and chiral materials, show promising potential in the applications of the three‐dimensional display, optical information processing, quantum optics, biological probe, and spintronics, etc. Particularly, chiral hybrid perovskites exhibit robust circularly polarized light emission and sensitive circularly polarized light detection, as the present chiral molecules can rotate the light polarization plane differently and/or absorb the left‐handed (σ^-) and right‐handed (σ⁺) circularly polarized light differently. Considering that circularly polarized light can create nonequilibrium spin polarization between the two Rashba‐split bands, chiral perovskites are promising for chiro‐spintronic and chiro‐optoelectronic applications. Chiral perovskites can be sorted as one‐dimensional, two‐dimensional, and three‐dimensional structures according to the space distributions of organic and inorganic components. This work demonstrates the crystal structure, and optical and optoelectronic properties of chiral perovskite of different dimensionalities, including the circular dichroism, the photoluminescence, and photodetection properties under the excitation of circularly polarized light. Considering the van der Waals coupling layered structure of two‐dimensional chiral perovskites, we also introduce the work on their two‐dimensional heterostructures combined with other two‐dimensional materials. Last, the important challenges and promising directions of chiral perovskites are summarized in aspects of material design and device exploration.
- chiral perovskite,
- structure dimensionality,
- heterostructures,
- optical behavior,
- photoelectric property
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沈阳化工大学材料科学与工程学院沈阳 110142