Citation: Zhi-Yong MO, Shi-Zhu SONG, Wen-Yu LI, Xue-Long HE, Lu SHEN, Xiao-Hong GAO, Qi LI. Pd Nanoparticles Anchored on Porous Carbon Nanofibers for Enhanced Electrocatalytic Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1037-1048. doi: 10.11862/CJIC.2022.110 shu

Pd Nanoparticles Anchored on Porous Carbon Nanofibers for Enhanced Electrocatalytic Oxygen Reduction Reaction

School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

Corresponding author: Xiao-Hong GAO, gao.xh@ntu.edu.cn Qi LI, zhuiqiuzhizhuo@163.com
Received Date: 3 December 2021
Revised Date: 14 April 2022

Figures(10)

Zirconium-based metal-organic frameworks (UiO-66) nanomaterials with 2-amino terephthalic acid as a ligand was synthesized by the solvothermal method. PAN/UiO-66 fibers with free-dispersed UiO-66 nanoparticles were prepared by electrospinning. Porous carbon nanofibers (PCNFs) were prepared by controllable pyrolysis. Pd nanoparticles were deposited on the surface of PCNFs by the wet-chemistry reduction method to obtain PCNFs@Pd composites. The morphologies, compositions, and structures of PCNFs@Pd were characterized by scanning electron microscope, transmission electron microscope, and X -ray diffraction. The performances of oxygen reduction reaction (ORR) of PCNFs@Pd were tested by electrochemical workstations in 0.1 mol·L^-1 KOH and 0.1 mol·L^-1 HClO₄ electrolytes, respectively. It was found that adding UiO-66 into PAN fibers significantly improved the ORR performance of PCNFs@Pd (0.34% of Pd loading) composites. Compared with 40%Pt/C, PCNFs@Pd composites in alkaline electrolytes showed lower Tafel slope, better cycle stability, and methanol toxicity resistance. Moreover, the catalytic activity and cycle stability of PCNFs@Pd were comparable to that of 20%Pt/C in acidic electrolytes.
- UIO-66,
- electrospinning,
- porous carbon nanofibers,
- Pd nanoparticles,
- oxygen reduction reaction
1. [1]
  Wang F X, Wu X W, Yuan X H, Liu Z C, Zhang Y, Fu L J, Zhu Y S, Zhou Q M, Wu Y P, Huang W. Latest Advances in Supercapacitors: From New Electrode Materials to Novel Device Designs[J]. Chem. Soc. Rev., 2017,46(22):6816-6854. doi: 10.1039/C7CS00205J
2. [2]
  Zhang Y, Liu J, Li S L, Su Z M, Lan Y Q. Polyoxometalate - Based Materials for Sustainable and Clean Energy Conversion and Storage[J]. EnergyChem, 2019,1(3):100021-100021. doi: 10.1016/j.enchem.2019.100021
3. [3]
  Guan X L, Ma J W, Li K, Liang J M, Li Z, Peng W C, Zhang G L, Fan X B, Zhang F B, Li Y. Multilevel N - Doped Carbon Nanotube/Graphene Supported Cobalt Phosphide Nanoparticles for Electrocatalytic Hydrogen Evolution Reaction[J]. Int. J. Hydrogen Energy, 2019,44(57):30053-30061. doi: 10.1016/j.ijhydene.2019.08.163
4. [4]
  Gao Y, Xie C, Zheng Z J. Textile Composite Electrodes for Flexible Batteries and Supercapacitors: Opportunities and Challenges[J]. Adv. Energy Mater., 2020,11(3)2002838.
5. [5]
  Xu T, Ding X T, Liang Y, Zhao Y, Chen N, Qu L T. Direct Spinning of Fiber Supercapacitor[J]. Nanoscale, 2016,8(24):12113-12117. doi: 10.1039/C6NR03116A
6. [6]
  Aa T C, Zhang W B, Zhu X H, Xiong Y, Sheng G Y, Fu J M. A Novel Photoelectrocatalytic Reactor and Photoelectrocatalytic Advanced Oxidation of Formic Acid[J]. Chin. J. Catal., 2003,24(5):338-342.
7. [7]
  Yang H C, Liang J, Wang Z X, An B G, Li F. Applications of Porous Carbon Materials in the Electrocatalysis of the Oxygen Reduction Reaction[J]. New Carbon Mater., 2016,31(3):243-263.
8. [8]
  Miao H, Xue Y J, Zhou X F, Liu Z P. Graphene-Based Oxygen Reduction Reaction Catalysts for Metal Air Batteries[J]. Prog. Chem., 2015,27(7):935-944.
9. [9]
  Song S Z, Qin T, Li Q, Wang Y Q, Tang Y F, Zhang L F, Liu X J. Single Co Atoms Implanted into N-Doped Hollow Carbon Nanoshells with Non-planar Co-N₄-1-O₂ Sites for Efficient Oxygen Electrochemistry[J]. Inorg. Chem., 2021,60(10):7498-7509. doi: 10.1021/acs.inorgchem.1c00824
10. [10]
  Primo A, Parvulescu V, Garcia H. Graphenes as Metal - Free Catalysts with Engineered Active Sites[J]. J. Phys. Chem. Lett., 2016,8(1):264-278.
11. [11]
  JI W J, WANG D, WANG G J, SUN X L, FU Y L. High Performance Supercapacitor Constructed by Isomorphic MOFs Composite Graphene Oxide Electrode Material[J]. Chinese J. Inorg. Chem., 2021,37(11):1931-1942. doi: 10.11862/CJIC.2021.241
12. [12]
  LI S J, ZHU J, ZHENG J M, GENG J Y, LI Y B. Preparation and Oxygen Reduction Properties of Cu-N Co-Doped Carbon-Based Catalysts[J]. Chinese J. Inorg. Chem., 2020,36(4):627-635.
13. [13]
  Liu J, Song P, Ruan M B, Xu W L. Catalytic Properties of Graphitic and Pyridinic Nitrogen Doped on Carbon Black for Oxygen Reduction Reaction[J]. Chin. J. Catal., 2016,37(7):1119-1126. doi: 10.1016/S1872-2067(16)62456-7
14. [14]
  Espallargas G M, Coronado E. Magnetic Functionalities in MOFs: From the Framework to the Pore[J]. Chem. Soc. Rev., 2018,47(2):533-557. doi: 10.1039/C7CS00653E
15. [15]
  CAO S J, CHEN F, CHEN Y F, WANG B. Thin Film Study of Metal-Organic Framework Materials[J]. Chemistry, 2017,80(1):3-9.
16. [16]
  He T, Xu X B, Ni B, Wang H Q, Long Y, Hu W P, Wang X. Fast and Scalable Synthesis of Uniform Zirconium -, Hafnium - Based Metal - Organic Framework Nanocrystals[J]. Nanoscale, 2017,9(48):19209-19215. doi: 10.1039/C7NR06274E
17. [17]
  Valenzano L, Civalleri B, Chavan S, Bordiga S, Nilsen M H, Jakobsen S, Lillerud K P, Lamberti C. Disclosing the Complex Structure of UiO - 66 Metal Organic Framework: A Synergic Combination of Experiment and Theory[J]. Chem. Mater., 2011,23(7):1700-1718. doi: 10.1021/cm1022882
18. [18]
  Bhadra M, Sasmal H S, Basu A, Midya S P, Kandambeth S, Pachfule P, Balaraman E, Banerjee R. Predesigned Metal-Anchored Building Block for In Situ Generation of Pd Nanoparticles in Porous Covalent Organic Framework: Application in Heterogeneous Tandem Catalysis[J]. ACS Appl. Mater. Interfaces, 2017,9(15):13785-13792. doi: 10.1021/acsami.7b02355
19. [19]
  Taylor-Pashow K M L, Della R J, Xie Z G, Tran S, Lin W B. Postsynthetic Modifications of Iron - Carboxylate Nanoscale Metal - Organic Frameworks for Imaging and Drug Delivery[J]. J. Am. Chem. Soc., 2009,131(40):14261-14263. doi: 10.1021/ja906198y
20. [20]
  Borges D D, Normand P, Permiakova A, Babarao R, Heymans N, Galvao D S, Serre C, De W G, Maurin G. Gas Adsorption and Separation by the Al-Based Metal-Organic Framework MIL - 160[J]. J. Phys. Chem. C, 2017,121(48):26822-26832. doi: 10.1021/acs.jpcc.7b08856
21. [21]
  Gu Z G, Zhang D X, Fu W Q, Fu Z H, Vohra M I, Zhang L, Woell C, Zhang J. Facile Synthesis of Metal - Loaded Porous Carbon Thin Films via Carbonization of Surface - Mounted Metal - Organic Frame-works[J]. Inorg. Chem., 2017,56(6):3526-3531. doi: 10.1021/acs.inorgchem.6b03140
22. [22]
  Zhang Y C, Mao Y L, Shi S L, Wan M M, Ma C, Wang S H, Chen C, Zhao D, Zhang N. Fabrication of Magnetic Pd/MOF Hollow Nanospheres with Double - Shell Structure: Toward Highly Efficient and Recyclable Nanocatalysts for Hydrogenation Reaction[J]. ACS Appl. Mater. Interfaces, 2019,11(35):32251-32260. doi: 10.1021/acsami.9b07864
23. [23]
  Cao M T, Yang F L, Zhang Q, Zhang J H, Zhang L, Li L F, Wang X H, Dai W L. Facile Construction of Highly Efficient MOF - Based Pd@UiO-66-NH₂@ZnIn₂S₄ Flower-like Nanocomposites for Visible-Light - Driven Photocatalytic Hydrogen Production[J]. J. Mater. Sci. Technol., 2021,76:189-199. doi: 10.1016/j.jmst.2020.11.028
24. [24]
  NIU Z D, ZHOU L L, GUAN Q Q, CHEN Q L, MIAO R R, JI W, HE L. Preparation and Application of Bimetallic MOF Materials[J]. New Chemical Materials, 2019,47(8):5-8.
25. [25]
  Shao M. Palladium - Based Electrocatalysts for Hydrogen Oxidation and Oxygen Reduction Reactions[J]. J. Power Sources, 2011,196(5):2433-2444. doi: 10.1016/j.jpowsour.2010.10.093
26. [26]
  Oh M Y, Lee J J, Park H S, Kim T Y, Lee Y S. Efficient Bifunctional Catalytic Activity of Nanoscopic Pd - Decorated La_0.6Sr_0.4CoO_3-_δ Perovskite toward Li - O₂ Battery, Oxygen Reduction, and Oxygen Evolution Reactions[J]. J. Ind. Eng. Chem., 2019,80(C):686-695.
27. [27]
  Torrero J, Montiel M, Pena M A, Ocon P, Rojas S. Insights on the Electrooxidation of Ethanol with Pd - Based Catalysts in Alkaline Electrolyte[J]. Int. J. Hydrogen Energy, 2019,44(60):31995-32002. doi: 10.1016/j.ijhydene.2019.10.124
28. [28]
  DENG H L, WANG J N, LI X Y, ZHANG J H. Preparation and Characterization of PAN/UIO-66 Composite Electrospun Nanofiber Membrane[J]. Journal of Beijing Institute of Fashion Technology (Natural Science Edition), 2020,40(3):1-8. doi: 10.3969/j.issn.1001-0564.2020.03.001
29. [29]
  Bentz K C, Ayala S, Kalaj M, Cohen S M. Polyacids as Modulators for the Synthesis of UiO-66[J]. Aust. J. Chem., 2019,72(10):848-851. doi: 10.1071/CH19271
30. [30]
  SHANG P M, JIA Y, DAI J H. Preparation of Metal - Organic Skeleton Material UIO - 66 and Its Adsorption of NO₃^- in Solution[J]. Environmental Protection of Chemical Industry, 2018,38(6):710-715. doi: 10.3969/j.issn.1006-1878.2018.06.015
31. [31]
  Cavka J H, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud K P. A New Zirconium Inorganic Building Brick forming Metal Organic Frameworks with Exceptional Stability[J]. J. Am. Chem. Soc., 2008,130(42):13850-13851. doi: 10.1021/ja8057953
32. [32]
  SUN J W, LIU Y Q, YU L Y, YANG K, XU Q. Preparation of Pd₀@UIO -66-NH₂ Catalyst and Study on Its Efficient Catalytic Suzuki Coupling Reaction[J]. New Chem. Mater., 2021,49(5):180-185.
33. [33]
  Tao L, Xia Z H, Zhang Q H, Sun Y J, Li M G, Yin K, Gu L, Guo S J. Spiny Pd/Pt Fe Core/Shell Nanotubes with Rich High - Index Facets for Efficient Electrocatalysis[J]. Sci. Bull., 2020,66(1):44-51.
34. [34]
  Kiguchi F, Nakamura M, Hoshi N. Cation Effects on ORR Activity on Low - Index Planes of Pd in Alkaline Solution[J]. Electrochemistry, 2021,89(2):145-147. doi: 10.5796/electrochemistry.21-00008
35. [35]
  Spendelow J S, Wieckowski A. Electrocatalysis of Oxygen Reduction and Small Alcohol Oxidation in Alkaline Media[J]. Phys. Chem. Chem. Phys., 2007,9(21):2654-2675. doi: 10.1039/b703315j
36. [36]
  Jiang Y Y, Ni P J, Chen C X, Lu Y Z, Yang P, Kong B, Fisher A, Wang X. Selective Electrochemical H₂O₂ Production through Two - Electron Oxygen Electrochemistry[J]. Adv. Energy Mater., 2018,8(31)1801909. doi: 10.1002/aenm.201801909
37. [37]
  Wang J J, Zhang Z, Ding J, Zhong C, Deng Y D, Han X P, Hu W B. Recent Progresses of Micro - nanostructured Transition Metal Compound - Based Electrocatalysts for Energy Conversion Technolo-gies[J]. Sci. China Mater., 2021,64(1):1-26. doi: 10.1007/s40843-020-1452-9
1. [1]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
4. [4]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
7. [7]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
8. [8]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
11. [11]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
16. [16]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1636)
HTML views(354)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142