Citation: Xiu-Dong CHEN, Jiang-Nan KE, Ping YAN, Jin-Hang LIU, Ya-Wei WANG, Chang-Chao ZHAN, Xiao-Duo JIANG. Core-Shell Nanosphere Cobalt-Based Metal-Organic Polymer: Preparation and Lithium Storage Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 836-842. doi: 10.11862/CJIC.2022.089 shu

Core-Shell Nanosphere Cobalt-Based Metal-Organic Polymer: Preparation and Lithium Storage Performance

Xiu-Dong CHEN ¹ ,
Jiang-Nan KE ¹ ,
Ping YAN ^{1, 2,,} ,
Jin-Hang LIU ^{1, 3} ,
Ya-Wei WANG ¹ ,
Chang-Chao ZHAN ^{1, 3} ,
Xiao-Duo JIANG ^2,,

1.
School of Chemistry and Chemical Engineering, Jiujiang University, Jiujiang, Jiangxi 332005, China
2.
Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang, Jiangxi 332005, China
3.
Jiujiang Key Laboratory of Organosilicon Chemistry and Application, Jiujiang, Jiangxi 332005, China

Corresponding author: Ping YAN, ypjjtu@126.com Xiao-Duo JIANG, 568666967@qq.com
Received Date: 29 November 2021
Revised Date: 3 March 2022

Figures(8)

Using trimellitic acid and cobalt nitrate hexahydrate as raw materials, two cobalt-based metal-organic polymers (Co-MOP) with different reaction times were synthesized by the hydrothermal method. The structure and morphology of Co-MOP were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and N₂ adsorption-desorption test. Two cobalt-based metal-organic polymer materials were used as anode materials for lithium-ion batteries, and the electrochemical performance tests were carried out. The results showed that Co-MOP-12 (hydrothermal reaction for 12 h) exhibited excellent electrochemical performance. The first-cycle reversible specific capacity the of Co-MOP-12 electrode reached 979 mAh·g^-1 at a current density of 100 mA·g^-1. The specific capacity was as high as 1 345 mAh·g^-1 after 100 cycles.
- metal-organic polymers,
- anode material,
- lithium-ion batteries,
- electrochemical properties
1. [1]
  Zhang C, Wei Y L, Cao P F, Lin M C. Energy Storage System: Current Studies on Batteries and Power Condition System[J]. Renewable Sustainable Energy Rev., 2018,82(3):3091-3106.
2. [2]
  Tang W, Yin X S, Kang S J, Zhan Z X, Tian B B, Teo S L, Wang X W, Chi X, Loh K L, Lee H W, Zheng G W. Lithium Silicide Surface Enrichment: A Solution to Lithium Metal Battery[J]. Adv. Mater., 2018,30(34)1801745. doi: 10.1002/adma.201801745
3. [3]
  Choi J W, Aurbach D. Promise and Reality of Post-Lithium-Ion Batteries with High Energy Densities[J]. Nat. Rev. Mater., 2016,1(4)16013. doi: 10.1038/natrevmats.2016.13
4. [4]
  Schon T B, Mcallister B T, Li P F, Seferos D S.. The Rise of Organic Electrode Materials for Energy Storage.[J]. Chem. Soc. Rev., 2016,45(22):6345-6404. doi: 10.1039/C6CS00173D
5. [5]
  Weng Y Q, Xu S M, Huang G Y, Jiang C Y. Synthesis And Performance of Li[(Ni_1/3Co_1/3Mn_1/3)_(1-x)Mg_x]O₂ Prepared from Spent Lithium Ion Batteries[J]. J. Hazard. Mater., 2013,246:163-172.
6. [6]
  Kim T, Song W T, Son D Y, Ono L K, Qi Y B. Lithium-Ion Batteries: Outlook on Present, Future, and Hybridized Technologies[J]. J. Mater. Chem. A, 2019,7(7):2942-2964. doi: 10.1039/C8TA10513H
7. [7]
  Armand M, Tarascon J M. Building Better Batteries[J]. Nature, 2008,451:652-657. doi: 10.1038/451652a
8. [8]
  Zhang H L, Zhao H B, Khan M A, Zou W W, Xu J Q, Zhang L, Zhang J J. Recent Progress in Advanced Electrode Materials, Separators and Electrolytes for Lithium Batteries[J]. J. Mater. Chem. A, 2018,6(42):20564-20620. doi: 10.1039/C8TA05336G
9. [9]
  Goodenough J B, Park K S. The Li-Ion Rechargeable Battery: A Perspective[J]. J. Am. Chem. Soc., 2013,135(4):1167-1176. doi: 10.1021/ja3091438
10. [10]
  Chen X D, Sun W W, Wang Y. Covalent Organic Frameworks for Next-Generation Batteries[J]. ChemElectroChem, 2020,7(19):3905-3926. doi: 10.1002/celc.202000963
11. [11]
  Yao S W, Shi Z Q, Zhang X X. Synthesis and Electrochemical Properties of α-Fe₂O₃ Porous Microrods as Anode for Lithium-Ion Batteries[J]. J. Alloys Compd., 2019,794:333-340. doi: 10.1016/j.jallcom.2019.04.298
12. [12]
  Ye J C, Baumgaertel A C, Wang M Y, Biener J, Biener M M. Structural Optimization of 3D Porous Electrodes for High-Rate Performancelithium Ion Batteries[J]. ACS Nano, 2015,9(2):2194-2202. doi: 10.1021/nn505490u
13. [13]
  Li C, Zhang C, Xie J, Wang K B, Li J Z, Zhang Q C. Ferrocene-Based Metal-Organic Framework as a Promising Cathode in Lithium-Ion Battery[J]. Chem. Eng. J., 2021,404126463. doi: 10.1016/j.cej.2020.126463
14. [14]
  Wang K B, Wang S E, Liu J D, Guo Y X, Mao F F, Wu H, Zhang Q C. Fe-Based Coordination Polymers as Battery-Type Electrodes in Semi-Solid-State Battery-Supercapacitor Hybrid Devices[J]. ACS Appl. Mater. Interfaces, 2020,12(29):32719-32725. doi: 10.1021/acsami.0c07729
15. [15]
  Li C, Yang H Y, Xie J, Wang K B, Li J Z, Zhang Q C. Ferrocene-Based Mixed-Valence Metal-Organic Framework as an Efficient and Stable Cathode for Lithium-Ion-Based Dual-Ion Battery[J]. ACS Appl. Mater. Interfaces, 2021,13(13):15315-15323. doi: 10.1021/acsami.1c01339
16. [16]
  Yin X J, Zhi C W, Sun W W, Lv L P, Wang Y. Multilayer NiO@Co₃O₄@Graphene Quantum Dots Hollow Spheres for High-Performance Lithium-Ion Batteries and Supercapacitors[J]. J. Mater. Chem. A, 2019,7(13):7800-7814. doi: 10.1039/C8TA11982A
17. [17]
  Zhu S H, Li Q D, Wei Q L, Sun R M, Liu X Q, An Q Y, Mai L Q. NiSe₂ Nanooctahedra as an Anode Material for High-Rate and Long-Life Sodium-Ion Battery[J]. ACS Appl. Mater. Interfaces, 2017,9(1):311-316. doi: 10.1021/acsami.6b10143
18. [18]
  Chao D L, Liang P, Chen Z, Bai L Y, Shen H, Liu X X, Xia X H, Zhao Y L, Savilov S V, Lin J Y, Shen Z X. Pseudocapacitive Na-Ion Storage Boosts High Rate and Areal Capacity of Self-Branched 2D Layered Metal Chalcogenide Nanoarrays[J]. ACS Nano, 2016,10(11):10211-10219. doi: 10.1021/acsnano.6b05566
19. [19]
  Chen Z L, Wu R B, Wang H, Jiang Y K, Jin L, Guo Y H, Song Y, Fang F, Sun D L. Construction of Hybrid Hollow Architectures by In‑Situ Rooting Ultrafine ZnS Nanorods within Porous Carbon Polyhedra for Enhanced Lithium Storage Properties[J]. Chem. Eng. J., 2017,326:680-690. doi: 10.1016/j.cej.2017.06.009
20. [20]
  Wu Z Z, Xie J, Xu J Z, Zhang S Q, Zhang Q C. Recent Progress in Metal-Organic Polymers as Promising Electrodes for Lithium/Sodium Rechargeable Batteries[J]. J. Mater. Chem. A, 2019,7(9):4259-4290. doi: 10.1039/C8TA11994E
1. [1]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
2. [2]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
3. [3]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
4. [4]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
5. [5]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
8. [8]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
9. [9]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
10. [10]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
11. [11]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
12. [12]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
13. [13]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
14. [14]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
15. [15]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
18. [18]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
19. [19]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
20. [20]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(784)
HTML views(159)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142