Citation: Long-Fei MA, Zhao-Hui ZHU, Xiao-Bo HUANG. Synthesis and Crystal Structure of Arylthiotetrathiafulvalenes and Cupric Bromide Charge Transfer Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 821-828. doi: 10.11862/CJIC.2022.086 shu

Synthesis and Crystal Structure of Arylthiotetrathiafulvalenes and Cupric Bromide Charge Transfer Complexes

Department of Criminal Science and Technology, Henan Police College, Zhengzhou 450046, China

Corresponding author: Long-Fei MA, malongfei@hnp.edu.cn
Received Date: 3 November 2021
Revised Date: 15 February 2022

Figures(6)

Four charge-transfer complexes, (1^+·)(Cu₂Br₆)_0.5, (2^+·)(Cu₂Br₆)_0.5, (3^+·)(Cu₂Br₆)_0.5 and (4^+·)(CuBr₂), have been prepared via diffusion methods comprising arylthio-substituted tetrathiafulvalene derivatives 1-4 and CuBr₂. Crystal-lographic studies indicate that the anions in the complexes, which are derived from CuBr₂, show diverse configura-tions including octahedral (CuⅡ₂Br ₆)^2-and linear (CuⅠBr₂)^-. The plane of the outer four Br atoms and the plane of the central quadrilateral on(CuⅡ₂Br₆)^2-have a different dihedral angle. Compounds 1-4 show radical cation and the cen-tral framework of compounds 1-4 are nearly planar in the complexes. The stacking structure and anionic configura-tion of the charge transfer complexes can be effectively regulated by regulating the substitution positions and sizes of halogen atoms on the aryl groups. CCDC: 2119456, (1^+·)(Cu₂Br₆)_0.5;2119457, (2^+·)(Cu₂Br₆)_0.5;2119458, (3^+·)(Cu₂Br₆)_0.5;2119459, (4^+·)(CuBr₂).
- tetrathiafulvalene,
- cupric bromide,
- crystal structure,
- charge transfer complexes
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