Citation: Shuang LIU, Ming-Fei HU, Lei-Lei LI, Wen-Zhen WANG. Structures, Photoluminescent and Magnetic Properties of Three 2D Lanthanide Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 716-724. doi: 10.11862/CJIC.2022.067 shu

Structures, Photoluminescent and Magnetic Properties of Three 2D Lanthanide Complexes

Shuang LIU ^{1, 2,,} ,
Ming-Fei HU ¹ ,
Lei-Lei LI ^{1, 2,,} ,
Wen-Zhen WANG ¹

1.
School of Chemistry and Chemical Engineering, Xi′an Shiyou University, Xi′an 710065, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: Shuang LIU, liush@xsyu.edu.cn Lei-Lei LI, lll@xsyu.edu.cn
Received Date: 18 June 2021
Revised Date: 20 November 2021

Figures(6)

Three new 2D lanthanide complexes with the formula [Ln₂(dmpa)₄]Cl₂, where Ln=Eu (1), Tb (2), Dy (3), have been prepared based on the ligand 2, 2-bis(hydroxymethyl)propionic acid (Hdmpa) under solvothermal conditions and characterized by IR spectrum, elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and single-crystal X-ray diffraction. These complexes are isostructural in which individual Ln(Ⅲ) ions are linked by carboxyl groups into 2D layers which are further assembled into 3D supramolecular structures by intermolecular interactions. Magnetic investigations on Dy complex indicate the presence of weak ferromagnetic interactions transmitted by carboxyl groups. And photoluminescence studies reveal that the Eu(Ⅲ) and Tb(Ⅲ) complexes exhibit charac- teristic red-light and green-light emissions, respectively.
- lanthanide complex,
- crystal structure,
- magnetic property,
- photoluminescent property
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